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MSDS Material Safety Data Sheet
CAS

67-63-0
111-76-2

File Name: thisoldgrout_com---clearguardwb.asp
Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).


Material Safety Data Sheet
Clear Guard WB


1 . Product and company identification
Common name : Clear Guard WB
Material uses : Water and oil based stain protection for natural stone, grout and porous masonry
surfaces.
Supplier/Manufacturer : This Old Grout Mfg, Inc.
2225 W. Pecos Rd. Suite 12
Chandler, Az. 85224
Toll free : 1-866-OLD-GROUT
info@thisoldgrout.com
Fax : (480) 969-1978
In case of emergency : CHEMTREC International: (703) 527-3887
1-866-OLD-GROUT
MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 08/15/2006

2 . Hazards identification
Physical state : Liquid.
Hazard status : This material is classified hazardous under OSHA regulations in the United States, the
WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 in
Mexico.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eyes : Irritating to eyes.
Skin : No known significant effects or critical hazards.
Irritating to respiratory system. May be harmful by inhalation.
Inhalation :
: May be harmful if swallowed.
Ingestion
Potential chronic health : Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
effects Mutagenic effects: Not available.
Teratogenic effects: Not available.
Medical conditions : Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or
aggravated by over- prolonged contact with spray or mist may produce chronic eye irritation and severe skin
exposure irritation.

3 . Composition/information on ingredients
United States
Name CAS number %
Isopropyl alcohol 67-63-0 >1
2-Butoxyethanol 111-76-2 >1

Canada
Name CAS number %
Isopropyl alcohol 67-63-0 >1
2-Butoxyethanol 111-76-2 >1




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Mexico
Classification
Name UN number IDLH H F R Special CAS number %
Isopropyl alcohol UN1219 2000 ppm 1 2 0 67-63-0 >1
2-Butoxyethanol UN2810 700 ppm 3 2 0 111-76-2 >1


4 . First aid measures
Eye contact : Check for and remove any contact lenses. In case of contact with eyes, rinse
immediately with plenty of water. Seek medical attention if symptoms occur.
Skin contact : Wash with soap and water. Seek medical attention if symptoms occur.

Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. Seek medical
attention if symptoms occur.
Ingestion : Do not induce vomiting. Never give anything by mouth to an unconscious person. Seek
medical attention if symptoms occur.
Notes to physician : No specific antidote. Medical staff must contact Poison Control Center.

5 . Fire-fighting measures
Flammability of the product : Non-flammable.
Products of combustion : These products are carbon oxides.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : No specific hazard.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6 . Accidental release measures
Personal precautions : Use suitable protective equipment.
Environmental precautions : Wash small spills to sanitary sewer. Large spills-confine spill, soak up with approved
and clean-up methods absorbent, shovel product into approved container for disposal.

7 . Handling and storage
Handling : Do not breathe vapor or mist. Wash thoroughly after handling.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.

8 . Exposure controls/personal protection
United States
Product name Exposure limits
Isopropyl alcohol ACGIH TLV (United States, 1/2005).
STEL: 400 ppm 15 minute(s). Form: All forms.
TWA: 200 ppm 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001).
STEL: 1225 mg/m3 15 minute(s). Form: All forms.
STEL: 500 ppm 15 minute(s). Form: All forms.
TWA: 980 mg/m3 10 hour(s). Form: All forms.
TWA: 400 ppm 10 hour(s). Form: All forms.

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Clear Guard WB


OSHA PEL (United States, 8/1997).
TWA: 980 mg/m3 8 hour(s). Form: All forms.
TWA: 400 ppm 8 hour(s). Form: All forms.
2-Butoxyethanol ACGIH TLV (United States, 1/2005).
TWA: 20 ppm 8 hour(s). Form: All forms.
NIOSH REL (United States, 12/2001). Skin
TWA: 24 mg/m3 10 hour(s). Form: All forms.
TWA: 5 ppm 10 hour(s). Form: All forms
OSHA PEL (United States, 8/1997). Skin
TWA: 240 mg/m3 8 hour(s). Form: All forms.
TWA: 50 ppm 8 hour(s). Form: All forms.

Canada
Product name Exposure limits
Isopropyl alcohol ACGIH TLV (United States, 1/2005).
STEL: 400 ppm 15 minute(s). Form: All forms.
TWA: 200 ppm 8 hour(s). Form: All forms.
2-Butoxyethanol ACGIH TLV (United States, 1/2005).
TWA: 20 ppm 8 hour(s). Form: All forms.


Mexico
Product name Exposure limits
Isopropyl alcohol NOM-010-STPS (Mexico, 9/2000). Skin
CCT: 1225 mg/m3 15 minute(s). Form: All forms.
CCT: 500 ppm 15 minute(s). Form: All forms.
CPT: 980 mg/m3 8 hour(s). Form: All forms.
CPT: 400 ppm 8 hour(s). Form: All forms.
2-Butoxyethanol NOM-010-STPS (Mexico, 9/2000). Skin
CCT: 360 mg/m3 15 minute(s). Form: All forms.
CCT: 75 ppm 15 minute(s). Form: All forms.
CPT: 120 mg/m3 8 hour(s). Form: All forms.
CPT: 26 ppm 8 hour(s). Form: All forms

Engineering measures : Use only with adequate ventilation.
Personal protection
Eyes :Safety glasses.
Skin :Lab coat.
Respiratory :A respirator is not needed under normal and intended conditions of use.
Hands :Natural rubber (latex).
Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in
general.
HMIS Code/Personal :B
protective equipment


Hygiene measures : Wash hands, forearms and face thoroughly after handling compounds and before eating,
smoking and using the lavatory and at the end of the day. Follow good industrial hygiene
practice.




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Clear Guard WB



9 . Physical and chemical properties
Physical state : Liquid.
pH : Neutral.
Boiling/condensation point : Weighted average: 101.56掳C (214.8掳F)
Melting/freezing point : Weighted average: -6.14掳C (20.9掳F)
Critical temperature : The lowest known value is 367.9掳C (694.2掳F) (2-Butoxyethanol).
Relative density : Weighted average: 1 (Water = 1)
Vapor pressure : Weighted average: 2.38 kPa (17.85 mm Hg) (at 20掳C)
Vapor density : Weighted average: 0.8 (Air = 1)
Evaporation rate : Weighted average: 0.4 compared with Butyl acetate.
Solubility : Miscible in water.

10 . Stability and reactivity
Stability and reactivity : The product is stable.
Incompatibility with various : Reactive with oxidizing materials, acids and alkalis.
substances
Hazardous polymerization : Will not occur.
Conditions of reactivity : Not applicable.

11 . Disposal considerations
Waste disposal : Dispose material in accordance with all local, state, and federal regulations.

12 . Transport information
Regulatory information
UN/ IMDG/ IATA DOT/ TDG : Not regulated.

13 . Regulatory information
United States
HCS Classification : Irritating material
U.S. Federal regulations : TSCA : All components listed.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Isopropyl alcohol; 2-Butoxyethanol
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Isopropyl
alcohol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard;
2-Butoxyethanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health
hazard
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: Sodium hydroxide
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
SARA 313
Product name CAS number Concentration
Form R - Reporting : Isopropyl alcohol 67-63-0 >1
2-Butoxyethanol 111-76-2 >1
requirements


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Clear Guard WB


Supplier notification : Isopropyl alcohol 67-63-0 >1
2-Butoxyethanol 111-76-2 >1
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations : Pennsylvania RTK: Isopropyl alcohol: (environmental hazard, generic environmental
hazard); 2-Butoxyethanol: (environmental hazard, generic environmental hazard);
Sodium hydroxide: (environmental hazard, generic environmental hazard)
Massachusetts RTK: Isopropyl alcohol; 2-Butoxyethanol; Sodium hydroxide; Glycine, n,n-
bis(carboxymethyl)-, trisodium salt
New Jersey: Isopropyl alcohol; 2-Butoxyethanol; Sodium hydroxide

California prop. 65: No products were found.
Canada
WHMIS (Canada) : Class D-2B: Material causing other toxic effects (Toxic).




CEPA DSL: All components listed.

CEPA NDSL: Glycine, n,n'-1,2-ethanediylbis-, disodium salt
This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United States
OSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA
and NOM -018-STPS-2000.
Mexico
HAZARD RATINGS
Classification :
0 Flammability 4- Extreme
Health 1 0 Reactivity 3- Serious
2- Moderate
Special 1- Slight
0- Minimal



International lists : This product, (and its ingredients) is (are) listed on national inventories, or is (are)
exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea
(TCCL), in Japan (METI), in the Philippines (RA6969).

14 . Other information
References : - Manufacturer's Material Safety Data Sheet. - 29CFR Part1910.1200 OSHA MSDS
Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping
Names, PG. - Canada Gazette Part II, Vol. 122, No. 2. Registration SOR/88-64, 31
December 1987. Hazardous Products Act "Ingredient Disclosure List" - Canadian
Transport of Dangerous Goods, Regulations and Schedules, Clear Language version
2005. - Official Mexican Standards NOM-018-STPS-2000 and NOM-004-SCT2-1994.
Date of issue : 08/15/2006
Version :1
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the user.
All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist.




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