Brammer and Strachan Rd, Germiston, Gauteng, South Africa
P.O.Box 14075, Wadeville 1422
Tel: +27 (11) 873 0157; Fax: +27 (11) 873 8480
e-mail: triangle@global.co.za; www.trianglesolvents.co.za
SAFETY DATA SHEET
PARAFFIN
TRADE NAME:
C9-C11 n-PARAFFIN
SYNONYM:
ODOURLESS KEROSENE
COMMON NAME:
New Heights 390 (Pty) Ltd registration no 2000/023987/07 trading as Triangle Solvents
Material Safety Data Sheet
C9-C11 n-Paraffin
1 Chemical product and company identification
: 1443
Common name : C9-C11 n-Paraffin Code
Supplier : Sasol Wax MSDS# :
P.O. Box 1
Sasolburg
1947
Republic of South Africa
TEL: +27 16 960 3002
Synonym : Kersol 150/200 (Sasolchem), Hydrocarbon Validation date : 11/21/2003.
blend C9-C11, Solvent C9-C11, Normal
alkane C9-C11
Trade name : C9-C11 n-Paraffin Print date : 11/21/2003.
Material uses : Paints and coatings; detergents; adhesives; Prepared by : Aneshia Ambaram
aerosols; lacquers; carrier for insecticides;
polishes; catalyst carrier.
Manufacturer : Sasol Chemical Industries In case of : SOUTH AFRICA: 0800 11
P.O. Box 1 emergency 28 90
Sasolburg INTERNATIONAL: +27 17
1947 610 4444
Republic of South Africa
TEL: +27 16 960-9111
2 Composition / information on ingredients
CAS #
Name % by Exposure limits
weight
Hydrocarbon blend, may contain:
Nonane 111-84-2 30-50 ACGIH TLV (United States, 2003)
TWA: 200 ppm 8 hour(s).
Decane 124-18-5 30-50 AIHA WEEL (United States)
TWA: 45 ppm 8 hour(s).
TWA: 250 mg/m 3 8 hour(s).
Undecane 1120-21-4 20-30 Not available.
Octane 111-65-9 5 ACGIH TLV (United States, 2002)
TWA: 300 ppm 8 hour(s).
TWA: 1401 mg/m 3 8 hour(s).
OSHA PEL Z1 (United States, 2002).
: 500 ppm
: 2350 mg/m 3
Dodecane 112-40-3 1 Not available.
3 Hazards identification
: Clear liquid.
Physical state and
appearance
Emergency overview : WARNING!
FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
HARMFUL, MAY CAUSE LUNG DAMAGE IF SWALLOWED.
VAPORS MAY CAUSE DROWSINESS AND DIZZINESS.
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS AND CRACKING.
TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS.
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C9-C11 n-Paraffin
Keep away from heat, sparks and flame. Keep container closed. Use only with adequate
ventilation. If swallowed, seek medical advice immediately and show this container or label.
Routes of entry : Absorbed through skin. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eyes : Hazardous in case of eye contact.
Skin : Repeated exposure may cause skin dryness or cracking.
Inhalation : Vapors may cause drowsiness and dizziness.
Ingestion : Harmful if swallowed. Aspiration hazard if swallowed- can enter lungs and cause damage.
Potential chronic health : CARCINOGENIC EFFECTS Not listed.
:
effects MUTAGENIC EFFECTS Not listed.
:
TERATOGENIC EFFECTS Not listed.
:
Medical conditions : Repeated or prolonged exposure is not known to aggravate medical condition.
aggravated by
overexposure:
Overexposure : Inhalation of vapour can produce headache, drowsiness, dizziness, anaesthetic effect and
/signs/symptoms central nervous system depression, which can lead to loss of coordination, numbness,
impaired judgement, inability to concentrate and, if exposure is prolonged, unconsciousness.
See toxicological information (section 11)
4 First aid measures
Eye contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get medical attention.
Skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Get medical attention.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie,
belt or waistband. If large quantities of this material are swallowed, call a physician
immediately.
Notes to physician : Support respiratory and cardiovascular function.
5 Fire fighting measures
Flammability of the product : Flammable.
Autoignition temperature : No data available.
Flash points : Closed cup: 42掳C (107.6掳F).
Flammable limits : No data available.
Products of combustion : These are carbon oxides (CO, CO2).
Fire hazards in presence of : Flammable in presence of open flames, sparks, static discharge and oxidizing materials.
various substances
Explosion hazards in : Acids, alkalis and strong oxidisers.
presence of various
substances
Fire fighting media : SMALL FIRE: Use DRY chemical powder.
and instructions LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective clothing (fire) : Be sure to use an approved/certified respirator or equivalent.
Special remarks on fire : No additional remark.
hazards
Special remarks on : No additional remark.
explosion hazards
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C9-C11 n-Paraffin
6 Accidental release measures
Small spill and leak : Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large spill and leak : Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Avoid
inhalation of vapours. Prevent run off into drains and waterways. Use absorbent (soil,
sand or other inert material).
7 Handling and storage
Handling : Keep away from heat, sparks and flame. Keep container closed. Use only with adequate
ventilation. To avoid fire, minimize ignition sources. Do not ingest.
Storage : Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed
until ready for use. Avoid all possible sources of ignition (spark or flame).
8 Exposure controls, personal protection
Engineering controls : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapors below their respective occupational exposure limits. Ensure that
eyewash stations and safety showers are proximal to the work-station location.
Personal protection
Eyes : Splash goggles.
Body : Chemical resistant protective suit.
Respiratory : Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate.
Hands : Impervious gloves.
Feet : Chemical resistant safety boots.
Protective clothing :
(pictograms)
: Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a
Personal protection in case
specialist BEFORE handling this product.
of a large spill
Product name Exposure limits
Hydrocarbon blend, may contain:
Nonane ACGIH TLV (United States, 2003)
TWA: 200 ppm 8 hour(s).
Decane AIHA WEEL (United States)
TWA: 45 ppm 8 hour(s).
TWA: 250 mg/m 3 8 hour(s).
Undecane Not available.
n-Octane ACGIH TLV (United States, 2002)
TWA: 300 ppm 8 hour(s).
TWA: 1401 mg/m 3 8 hour(s).
OSHA PEL Z1 (United States, 2002).
: 500 ppm
: 2350 mg/m 3
Dodecane Not available.
9 Physical and chemical properties
Physical state and : Clear liquid.
appearance
Color : Colourless.
Odor : Slight odour.
Taste : No data available.
Molecular weight : Not applicable.
Molecular formula : Not applicable.
pH (1% soln/water) : Not applicable.
Boiling/condensation point : 150-200掳C
Melting/freezing point : No data available.
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C9-C11 n-Paraffin
Critical temperature : No data available.
Specific gravity : 0.73 (Water = 1) @ 20掳C
Vapor pressure : 7kPa @ 20掳C
Vapor density : No data available.
Volatility : 100% w/w
Odor threshold : No data available.
Evaporation rate : No data available.
VOC : No data available.
Viscosity : Kinetic: 0.93 cSt @ 40掳C
LogKow : No data available.
Ionicity (in water) : No data available.
Dispersion properties : No data available.
Solubility : Insoluble in water.
Physical chemical comments : No additional remark.
10 Stability and reactivity
Stability and reactivity : The product is stable.
Conditions of instability : Heat. Prolonged storage at elevated temperatures may interfere with quality.
Incompatibility with various : Avoid contact with strong oxidizing agents.
substances
Hazardous decomposition : Flue gas, carbon monoxide.
products
Hazardous polymerization : Will not occur.
11 Toxicological information
: Acute toxicity of the vapor (LC50): 118 mg/m 3 4 hour(s) [Rat]. (n-Octane).
Toxicity to Animals
Chronic effects on humans : No data available.
Other toxic effects on : No known effects.
humans
Special remarks on toxicity to : No additional remark.
animals
Special remarks on chronic : No additional remark.
effects on humans
Special remarks on other : No additional remark.
toxic effects on humans
12 Ecological information
: No data available.
Ecotoxicity
BOD and COD : No data available.
Biodegradable/OECD : Paraffins are biodegradable.
Mobility : No data available.
Products of degradation : No data available.
Toxicity of the products of : No data available.
biodegradation
Special remarks on the : No additional remark.
products of biodegradation
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C9-C11 n-Paraffin
13 Disposal considerations
Waste information : Waste must be disposed of in accordance with federal, state and local environmental control
regulations.
Waste stream : No data available.
Consult your local or regional authorities.
14 Transport information
Packing
Regulatory UN Proper shipping name Class Label Additional
group
information number information
D O T C l a s s 3 : III -
DOT UN 3295 HYDROCARBONS,
Classification LIQUID, N.O.S. Flammable liquid. FLAMMABLE LIQUID
3
T D G C l a s s 3 : III
TDG UN 3295 HYDROCARBONS,
Classification LIQUID, N.O.S. Flammable liquid.
3
I M D G C l a s s 3 : III
IMDG Class UN 3295 HYDROCARBONS, -
LIQUID, N.O.S. Flammable liquid.
3
I A T A C l a s s 3 : III -
IATA-DGR UN 3295 HYDROCARBONS,
Class LIQUID, N.O.S. Flammable liquid.
3
15 Regulatory information
HCS classification : Class: Combustible liquid having a flash point between 37.8掳C (100掳F) and 93.3掳C (200掳F).
U.S. Federal regulations : TSCA 4(a) proposed test rules: Nonane
TSCA 8(a) PAIR: Nonane
TSCA 8(b) inventory: n-Octane; Nonane; Decane; Undecane; Dodecane
TSCA 8(d) H and S data reporting: Nonane
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products
were found.
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
State regulations : Connecticut hazardous material survey.: n-Octane
Rhode Island RTK hazardous substances: n-Octane; Nonane; Decane
Pennsylvania RTK: n-Octane; Nonane; Decane
Minnesota: n-Octane; Nonane
Massachusetts RTK: n-Octane; Nonane
Massachusetts spill list: n-Octane; Nonane
New Jersey: n-Octane; Undecane
New Jersey spill list: Decane
California prop. 65: No products were found.
EU Regulations
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C9-C11 n-Paraffin
:
Hazard symbol(s)
: Dangerous for the environment, Harmful
Classification
: R10- Flammable.
Risk phrases
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapors may cause drowsiness and dizziness.
: S9- Keep container in a well-ventilated place.
Safety phrases
S16- Keep away from sources of ignition - No smoking.
S24/25- Avoid contact with skin and eyes.
S60- This material and its container must be disposed of as hazardous waste.
S61- Avoid release to the environment. Refer to special instructions/Safety data sheets.
S62- If swallowed, do not induce vomiting: seek medical advice immediately and show
this container or label.
: 203-892-1 (Octane), 203-913-4 (Nonane), 204-686-4 (Decane), 214-300-6 (Undecane),
EINECS Number
203-967-9 (Dodecane), 211-09-34 (Tridecane).
16 Other information
National Fire Fire Hazard
2
Protection
1 0
Association Health Reactivity
(U.S.A.) Specific hazard
References : - LOLI Database: The regulated Chemicals List of Lists.
- CHEMINFO: Canadian Centre for Occupational Health and Safety, Issue: 97-3 (August,
1997).- BDH; Hazard Data Disk, Version 3.- CESARS: Chemical Evaluation and Retrieval
System, Produced by: Ontario Ministry of Environment and Michigan Department of Natural
Resouces, Issue:97-3 (August, 1997).- TOMES Plus System: Toxicology, Occupational
Medicine & Environmental Series: incorporating:- MEDITEX, HAZARDTEXT, 1st Medical
Response Protocols, INFOTEXT, HSDB, CHRIS, OHM/TADS, IRIS, NIOSH Pocket Guide,
RTECS, NJ Fact Sheets, North American Emergency Response Guides, REPROTEXT,
REPROTOX, TERIS, Shepard's Catalog of Teratogenic Agents.
Other special : No additional remark.
considerations
Date of printing : 11/21/2003.
: 11/21/2003.
Date of issue
Date of previous issue : No Previous Validation.
Version :2
Derick Johannes.
Verified by :
Notice to reader
This MSDS summarises at the date of issue our best knowledge of the health, safety and environmental hazard information related to the product, and in
particular how to safely handle, use, store and transport the product in the workplace. Since SASOL and its subsidiaries cannot anticipate or contro
conditions under which the product may be handled, used, stored or transported, each user must, prior to usage, review this MSDS in the context of how
the user intends to handle, use, store or transport the product in the workplace and beyond, and communicate such information to all relevant parties.If
clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
We shall not assume any liability for the accuracy or completeness of the information contained herein or any advice given unless there has been gross
negligence on our part. In such event our liability shall be limited only to direct damages suffered. Our responsibility for product as sold is subject to our
standard terms and conditions, a copy of which is sent to our customers and is also available upon request. All risk associated with the possession and
application of the product passes on delivery.
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