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Material Safety Data Sheet

TREMSEAL HP CURATIVE 12 OZ CANS
Version 1. Print Date 08/16/2008
REVISION DATE: 08/14/2008


SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION

Product Information
Trade name : TREMSEAL HP CURATIVE 12 OZ CANS
Product code : 150607 009

Supplier : Tremco Canada division
220 Wicksteed Avenue
Toronto, ON M4H 1G7
Telephone : (416) 421-3300
Emergency Phone: : (613) 996-6666

Product use : Curative

Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 08/14/2008
Telephone : (416) 421-3300

SECTION 2 - HAZARDS IDENTIFICATION

Emergency Overview
Clear. Liquid solution. May cause slight irritation to the respiratory system. Leave area to breathe fresh air.
Avoid further overexposure. If symptoms persist, get medical attention.

Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system.
:
Eyes Vapors or liquid may cause tearing, blurred vision, severe irritation, and possible chemical
:
burns.
Ingestion May cause irritation to the mouth, throat and stomach. May cause chemical burns to
:
stomach, mouth, nose, and throat.
Skin May cause moderate irritation. May cause sensitization resulting in irritation, itching and
:
redness.

Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.

Chronic Health Effects
Prolonged and repeated overexposure to amines may cause liver and kidney damage based on animal studies.
Prolonged or repeated exposure to xylene may cause defatting, drying, and irritation of the skin, dermatitis,
central nervous system (CNS) effects, heart muscle sensitization and arrhythmia, hearing loss, and brain, liver,
kidney damage. Xylene overexposure may affect fetal development. The International Agency for Research on
Cancer (IARC) has evaluated ethylbenzene and classified it as a possible human carcinogen (Group 2B) based
on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in
exposed humans. Fillers are encapsulated and not expected to be released from product under normal
conditions of use. Prolonged or repeated exposure to mineral spirits (petroleum naphtha or stoddard solvent)
may cause defatting, drying, and irritation of the skin, dermatitis, central nervous system (CNS) effects, and
adverse liver, kidney, and lung effects.
Target Organs: Skin, Eye, Lung




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Material Safety Data Sheet

TREMSEAL HP CURATIVE 12 OZ CANS
Version 1. Print Date 08/16/2008
REVISION DATE: 08/14/2008



SECTION 3 : HAZARDOUS INGREDIENTS


Chemical Name CAS-No. Weight % Range
Aliphatic naphtha 64742-88-7 7.0 - 13.0
Xylene 1330-20-7 0.5 - 1.5
Ethylbenzene 100-41-4 0.1 - 1.0
1,2,4-Trimethylbenzene 95-63-6 0.1 - 1.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).

SECTION 4 - FIRST AID MEASURES

Get immediate medical attention for any significant overexposure.

Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.
Eye contact : Flush with water for 15 minutes. If irritation persists, get medical attention.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.


SECTION 5: FIRE / EXPLOSION HAZARDS

Flash point : 50 掳 122 掳
C, F
Method : Pensky-Martens Closed Cup
Lower explosion limit : 1.00 %(V) Solvent
Upper explosion limit : 5 %(V) Solvent
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide, carbon dioxide, and nitrogen oxides.
products
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.


SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES

Stop flow. Contain spill. Keep out of water courses. Absorb spill in sand, earth or other suitable material.
Transfer to appropriate container for disposal.

SECTION 7 - HANDLING AND STORAGE

Store under normal warehouse conditions in sealed containers. Keep container closed when not in use. Vapor
may migrate to sources of ignition. Do not smoke, weld, generate sparks, or use flame near container. Change
soiled work clothes frequently. Clean hands thoroughly after handling. Prevent inhalation of vapor, ingestion,


2/5 150607 009
Material Safety Data Sheet

TREMSEAL HP CURATIVE 12 OZ CANS
Version 1. Print Date 08/16/2008
REVISION DATE: 08/14/2008

and contact with skin eyes and clothing. Keep container closed when not in use. Precautions also apply to
emptied containers. Handle in compliance with common hygienic practices. Clean hands thoroughly after
handling.

SECTION 8 - PREVENTIVE MEASURES/EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protection equipment
Respiratory protection : Use full engineering controls before relying on personal protective
equipment.Wear NIOSH/MSHA approved vapor respirator with appropriate
cartridge when the vapor concentration is expected to exceed exposure limits
indicated on the MSDS. Follow manufacturer's directions for respirator use.
Hand protection : Protect hands with impervious gloves.
Eye protection : Wear chemical safety goggles and/or face shield to prevent eye contact. Do
not wear contact lenses. Do not touch eyes with contaminated body parts or
materials. Have eye washing facilities readily available.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use local exhaust when the general ventilation is inadequate.

Exposure Limits

Chemical Name CAS Number Regulation Limit Form
Xylene 1330-20-7 Ontario TWA: 435 mg/m3
Ontario STEL: 650 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm

Ethylbenzene 100-41-4 Ontario TWA: 435 mg/m3
Ontario STEL: 540 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 125 ppm

1,2,4-Trimethylbenzene 95-63-6 Ontario TWA: 123 mg/m3
ACGIH TWA: 25 ppm



SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State : Liquid
Form : Liquid solution
Color : Clear
Odor : Naptha
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : 400 掳C, 752 掳
F
Water solubility : Partially soluble

3/5 150607 009
Material Safety Data Sheet

TREMSEAL HP CURATIVE 12 OZ CANS
Version 1. Print Date 08/16/2008
REVISION DATE: 08/14/2008

Evaporation Rate: : Not available.
Specific Gravity : 0.935
% Volatile Weight : 11 %


SECTION 10 - REACTIVITY / STABILITY

Substances to avoid : Acids.
Stability : Stable under normal conditions. Avoid welding arcs, flames or other high
temperature sources.
Hazardous polymerization : Will not occur under normal conditions.


SECTION 11 - TOXICOLOGICAL INFORMATION

Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 4,300 mg/kg ( Rat ) 1,590 mg/kg ( Mouse ) 6,670 mg/kg (
Rat ) 3,523 - 8,600 mg/kg ( Rat ) 5,627 mg/kg ( Mouse )
Acute inhalation toxicity (LC-50) 6,350 mg/l for 4 h ( Rat ) 3,907 mg/l for 6 h ( Mouse ) 8,000
mg/l for 4 h ( Rat )

Ethylbenzene, CAS-No.: 100-41-4
Acute oral toxicity (LD-50 oral) 5,460 mg/kg ( Rat ) 3,500 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 17,800 mg/kg ( Rabbit )



SECTION 12 - ECOLOGICAL INFORMATION

No Data Available


SECTION 13 - WASTE DISPOSAL CONSIDERATIONS

RCRA Class : D001: Reportable Quantity = 100 lbs. (Characteristic of ignitability)
This classification applies only to the material as it was originally produced.

Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial
regulations.


SECTION 14 - TRANSPORTATION / SHIPPING DATA

TDG / DOT Shipping Description:
NOT REGULATED


SECTION 15 - REGULATORY INFORMATION

North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.




4/5 150607 009
Material Safety Data Sheet

TREMSEAL HP CURATIVE 12 OZ CANS
Version 1. Print Date 08/16/2008
REVISION DATE: 08/14/2008

Canadian Regulations:
WHMIS Classification : B3, D2A, D2B
This is a "controlled product" under the Canadian Workplace Hazardous Materials Information System
(WHMIS).

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.

Other Regulations:
Regulatory VOC (less water and : 105 g/l
exempt solvent)



SECTION 16 - OTHER INFORMATION

HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe

Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.

Prepared by: Sewnauth Raghunandan

Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System




5/5 150607 009

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