Page 1 of 7
MATERIAL SAFETY DATA SHEET MSDS-059
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
1. PRODUCT IDENTIFICATION
1.1 Product Name:
TRADITIONAL POWDERS
1.2 Chemical Name:
POLY ETHYLMETHACRYLATE POWDER
1.3 Synonyms:
TRADITIONAL PINK POWDER, TRADITIONAL CLEAR POWDER, TRADITIONAL NATURAL POWDER, TRADITIONAL WHITE POWDER
1.4 Trade Names:
NP-100, NP-200, NP-300, NP-400
1.5 Product Use:
PROFESSIONAL OR SUNDRY USE ONLY
1.6 Manufacturer鈥檚 Name:
OPI PRODUCTS, INC.
1.7 Manufacturer鈥檚 Address:
13034 SATICOY STREET, NO. HOLLYWOOD, CA 91605 USA
1.8 Emergency Phone:
CHEMTREC: (703) 527-3887
1.9 Business Phone:
(818) 759-2400
2. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH - ppm OSHA - ppm OTHER
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. % TLV STEL PEL STEL IDLH
POLY ETHYL/METHYL
NA NA NA 鈮? 98.0 (10) NE (10) NE NE
METHACRYLATE COPOLYMER
BENZOYL PEROXIDE 94-36-0 DM8575000 202-327-6 鈮? 2.0 (5) NE (5) NE NE
MAY ALSO CONTAIN:
CI 77891 (TITANIUM DIOXIDE) 13463-67-7 XR2275000 236-675-5 鈮? 2.0 (15) NE (15) NE NE
CI 45410 (RED 27) 18472-87-2 LM5900000 242-355-6 鈮? 2.0 NE NE NE NE NE
CI 16035 (RED 40) 25956-17-6 QK2260000 247-368-0 鈮? 2.0 NE NE NE NE NE
CI 47005 (YELLOW 10) 8003-22-3 NA 232-318-2 鈮? 2.0 NE NE NE NE NE
CI 45380 (RED 21) 548-26-5 KQ6300000 241-409-6 鈮? 2.0 NE NE NE NE NE
NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2003 format.
Page 2 of 7
MATERIAL SAFETY DATA SHEET MSDS-059
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
3. HAZARD IDENTIFICATION
3.1 Hazard Identification:
Allergic contact dermatitis is possible with prolonged or repeated contact. The product is a fine powder, and may cause a slipping
and falling hazard if spilled.
3.2 Routes of Entry: Inhalation: YES Absorption: NO Ingestion: YES
3.3 Effects of Exposure:
EYES: Possible irritation from dust.
SKIN: Irritation. Allergic contact dermatitis is possible with prolonged or repeated contact.
INGESTION: No exposure effects are reported.
INHALATION: Considered a nuisance dust. May cause irritation of the mouth, nose, throat, and lungs.
3.4 Symptoms of Overexposure:
Symptoms of skin overexposure may include redness, itching, and irritation of affected areas. Overexposure in eyes may cause
redness, itching and watering. The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) upon prolonged or
repeated exposure.
3.5 Acute Health Effects:
Moderate irritation to eyes and skin near affected areas. Additionally, high concentrations of vapors can cause drowsiness, dizziness,
headaches and nausea.
3.6 Chronic Health Effects:
No long-term health effects are known.
3.7 Target Organs:
Eyes, skin & respiratory system.
4. FIRST AID MEASURES
4.1 First Aid:
INGESTION: If ingested, do not induce vomiting! If product has been swallowed, drink plenty of water or milk IMMEDIATELY. If the
patient is vomiting, continue to offer water or milk. Never give water or milk to an unconscious person. Contact the
nearest Poison Control Center or local emergency number. Provide an estimate of the time at which the material was
ingested and the amount of the substance that was swallowed.
SKIN: If irritation occurs & product is on the skin, rinse thoroughly with lukewarm water, followed by a thorough washing of the
affected area with plenty of soap and water. Remove contaminated clothing and wash thoroughly before reuse. If
irritation, redness or swelling persists, consult a physician immediately.
EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at least 15 minutes. Open and close
eyelid(s) to ensure thorough irrigation. If irritation persists seek immediate medical attention.
INHALATION: Remove victim to fresh air at once. If breathing stops, perform artificial respiration. Seek immediate medical attention.
HEALTH 1
4.2 Medical Conditions Aggravated by Exposure:
Pre-existing dermatitis, other skin conditions, and disorders of the target organs (eyes,
FLAMMABILITY 1
skin, respiratory system). Preclude from exposure those individuals that are
susceptible to dermatitis, asthma or bronchitis.
REACTIVITY 1
PROTECTIVE EQUIPMENT B
EYES SKIN
Page 3 of 7
MATERIAL SAFETY DATA SHEET MSDS-059
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
264 掳C (508 掳F), TCC
5.2 Autoignition Temperature:
NA
5.3 Flammability Limits: Lower Explosive Limit (LEL): NA Upper Explosive Limit (UEL): NA
5.4 Fire & Explosion Hazards:
Keep away from excessive heat, open flames, sparks, and other possible sources of ignition.
5.5 Extinguishing Methods:
Carbon dioxide, dry chemical & water spray.
5.6 Firefighting Procedures:
Keep containers cool until well after the fire is out. Prevent runoff from fire control or dilution from
entering sewers, drains, drinking water supply, or any natural waterway. Firefighters should wear full
face, self-contained breathing apparatus (MSHA/NIOSH approved or the equivalent) and impervious
protective clothing.
6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., < 5 lbs) wear appropriate personal protective equipment (e.g., goggles, gloves). Maximize ventilation (open
doors and windows) and secure all sources of ignition. Carefully sweep up spilled material and place into appropriate closed
container(s) for disposal. Dispose of properly in accordance with local, state and federal regulations. Wash all affected areas and
outside of container with plenty of warm water and soap. Remove any contaminated clothing and wash thoroughly before reuse.
For spills 鈮? 5 lbs, deny entry to all unprotected individuals. Contain spill with inert material (e.g., sand or earth). Carefully sweep up
spilled material and place into appropriate closed container(s) for disposal. Remove contaminated clothing promptly and wash
affected skin areas with soap and water. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water.
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Avoid prolonged contact with this material. Limit inhalation of the vapors generated by this product. Use in a well-ventilated location
(e.g., local exhaust ventilation, fans). Wash exposed skin thoroughly with plenty of soap & water after using this product. Do not eat,
drink, or smoke while handling this product.
7.2 Storage & Handling:
Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans). Keep away from excessive heat, open
flames, sparks, and other possible sources of ignition. Keep away from incompatible materials listed in Section 10. Do not store in
damaged or unmarked containers or storage devices. Keep containers securely closed when not in use. Open slowly on a level,
stable surface. Empty containers may contain residual amounts of this product; therefore, empty containers should be handled with
care. Keep away from children at all times!
7.3 Special Precautions:
Local exhaust ventilation is recommended.
Page 4 of 7
MATERIAL SAFETY DATA SHEET MSDS-059
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
Use with adequate ventilation (e.g., local exhaust ventilation, fans). Ensure appropriate decontamination equipment is available
(e.g., sink, safety shower, eye-wash station).
8.2 Respiratory Protection:
No special respiratory protection is required under typical circumstances of use or handling. In instances where vapors or sprays of
this product are generated, and respiratory protection is needed, use only protection authorized by 29 CFR 搂1910.134, applicable U.S.
State regulations, or the Canadian CAS Standard Z94.4-93 and applicable standards of Canadian Provinces, EC member States, or
Australia.
8.3 Eye Protection:
Avoid eye contact. None required under normal conditions of use. However, may cause irritation in some sensitive individuals.
When handling large quantities (e.g., 鈮? 1 gallon), safety glasses with side shields should be used.
8.4 Hand Protection:
No apron required when handling small quantities.
When handling large quantities (e.g., 鈮? 1 gallon), eye wash stations and deluge showers should be available. Upon completion of
work activities involving large quantities of this product, wash any exposed areas thoroughly with soap and water.
8.5 Body Protection:
No apron required when handling small quantities.
When handling large quantities (e.g., 鈮? 1 gallon), eye wash stations and deluge showers should be available. Upon completion of
work activities involving large quantities of this product, wash any exposed areas thoroughly with soap and water.
9. PHYSICAL & CHEMICAL PROPERTIES
9.1 Density: NA
9.2 Boiling Point: NE
9.3 Melting Point: NE
9.4 Evaporation Rate: NA
9.5 Vapor Pressure: NA
9.6 Molecular Weight: NA
9.7 Appearance & Color: Clear powder with an mild acrylic odor, in bulk.
9.8 Odor Threshold: NA
9.9 Solubility: Insoluble in water.
9.10 pH NA
9.11 Viscosity: NE
9.12 Other Information: NA
10. STABILITY & REACTIVITY
10.1 Stability:
Relatively stable under ambient conditions when stored properly.
10.2 Hazardous Decomposition Products:
If exposed to extremely high temperatures, products of thermal decomposition may include irritating vapors and toxic gases (e.g.,
oxides of carbon & nitrogen).
10.3 Hazardous Polymerization:
Will not occur.
10.4 Conditions to Avoid:
Exposure or contact to extreme temperatures, incompatible chemicals, strong light sources, sparks, flame.
10.5 Incompatible Substances:
Strong oxides, peroxides or strong acids.
Page 5 of 7
MATERIAL SAFETY DATA SHEET MSDS-059
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
11. TOXICOLOGICAL INFORMATION
11.1 Toxicity Data:
This product has not been tested on animals to obtain toxicological data. There are toxicology data for the components of this
product, which are found in the scientific literature. These data have not been presented in this document.
11.2 Acute Toxicity:
See Section 3.5
11.3 Chronic Toxicity:
No long-term health effects are known.
11.4 Suspected Carcinogen:
No
11.5 Reproductive Toxicity:
This product is not reported to produce reproductive toxicity in humans.
Mutagenicity:
This product is not reported to produce mutagenic effects in humans. However, animal mutation data are available for the
components of this product were obtained during clinical studies on specific animal tissues exposed to high doses of these
components.
Embryotoxicity:
This product is not reported to produce embryotoxic effects in humans.
Teratogenicity:
This product is not reported to produce teratogenic effects in humans.
Reproductive Toxicity:
This product is not reported to produce reproductive effects in humans.
11.6 Irritancy of Product:
See Section 3.3
11.7 Biological Exposure Indices:
NE
11.8 Physician Recommendations:
Treat symptomatically.
12. ECOLOGICAL INFORMATION
12.1 Environmental Stability:
This product will slowly volatile from soil. Components of this product will slowly decompose into organic compounds.
12.2 Effects on Plants & Animals:
There is no specific data available for this product.
12.3 Effects on Aquatic Life:
There is no specific data available for this product. However, releases of large volumes may be harmful or fatal to overexposed
aquatic life. Aquatic toxicity data for components of this product are available, but are not presented in this MSDS.
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose in accordance with local, state and Federal hazardous waste laws. U.S. EPA Characteristic Waste: D001 (flammable)
13.2 Special Considerations:
NA
14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
NOT REGULATED
14.2 IATA (AIR):
NOT REGULATED
14.3 IMDG (OCN):
NOT REGULATED
14.4 TDGR (Canadian GND):
NOT REGULATED
14.5 ADR/RID (EU):
NOT REGULATED
14.6 MEXICO (SCT):
NOT REGULATED
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MATERIAL SAFETY DATA SHEET MSDS-059
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
NA
15.2 SARA Threshold Planning Quantity:
NA
15.3 TSCA Inventory Status:
All components of this product are listed in the TSCA Inventory or are exempt.
15.4 CERCLA Reportable Quantity (RQ):
NA
15.5 Other Federal Requirements:
This product complies with the appropriate sections of the Food and Drug Administration's 21 CFR subchapter G (Cosmetics).
15.6 Other Canadian Regulations
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR. The components of this product are listed on the DSL/NDSL. None
of the components of this product are listed on the Priorities Substances List. Class B2 Flammable Liquid.
15.7 State Regulatory Information:
Benzoyl Peroxide is covered under specific state criteria. No components of this mixture are listed in the California Proposition 65 Lists.
15.8 67/548/EEC (European Union) Requirements:
The primary component of this product is not listed in Annex I of EU Directive 67/548/EEC.
16. OTHER INFORMATION
16.1 Other Information:
Precisely follow directions and MSDS (available through your supplier) for use. Avoid skin contact. If redness or other signs of adverse
reaction occur, discontinue use immediately. Use only in a well ventilated area. A ventilation system that expels vapors to the
outdoors is recommended. Keep out of reach of children. In case of emergency, contact your physician or local Poison Control
Center immediately. FOR PROFESSIONAL USE ONLY!
16.2 Terms & Definitions:
See page 7 of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA鈥檚 Hazard Communication Standard, 29 CFR 搂1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & OPI Products鈥? knowledge, the
information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness are not
guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein relates only
to the specific product(s). If this product(s) is combined with other materials, all component properties must be considered. Data
may be changed from time to time. Be sure to consult the latest edition.
16.4 Prepared for:
OPI Products, Inc.
13034 Saticoy Street
No. Hollywood, CA 91605 USA
(818) 759-2400 phone
(818) 759-5770 fax
http://www.opi.com/
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Boulevard, Suite 201
Torrance, CA 90504 USA
310-360-3700 phone
310-360-5700 fax
http://www.shipmate.com/
Page 7 of 7
MATERIAL SAFETY DATA SHEET MSDS-059
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 01/01/2005
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION: NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
CAS No. Chemical Abstract Service Number FLAMMABILITY LIMITS IN AIR:
EXPOSURE LIMITS IN AIR:
Autoignition Minimum temperature required to initiate combustion
Temperature in air with no other source of ignition
ACGIH American Conference on Governmental Industrial Hygienists
LEL Lower Explosive Limit - lowest percent of vapor in air, by
TLV Threshold Limit Value
volume, that will explode or ignite in the presence of
OSHA U.S. Occupational Safety and Health Administration
an ignition source
PEL Permissible Exposure Limit
UEL Upper Explosive Limit - highest percent of vapor in air,
IDLH Immediately Dangerous to Life and Health
by volume, that will explode or ignite in the presence of
an ignition source
FIRST AID MEASURES:
CPR Cardiopulmonary resuscitation - method in which a person HAZARD RATINGS:
whose heart has stopped receives manual chest
compressions and breathing to circulate blood and provide
0 Minimal Hazard
oxygen to the body.
1 Slight Hazard
2 Moderate Hazard
HMIS庐
HAZARDOUS MATERIALS IDENTIFICATION FLAMMABILITY
REACTIVITY
3 Severe Hazard
SYSTEM: HMIS
4 Extreme Hazard
HEALTH
HEALTH, FLAMMABILITY & REACTIVITY RATINGS: ACD Acidic
ALK Alkaline
0 Minimal Hazard
FLAMMABILITY COR Corrosive
1 Slight Hazard
W Use No Water
2 Moderate Hazard SPECIAL
REACTIVITY HEALTH
OX Oxidizer PRECAUTIONS
3 Severe Hazard
4 Extreme Hazard PERSONAL PROTECTION
TOXICOLOGICAL INFORMATION:
NCCHL44T 漏 NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808
PERSONAL PROTECTION RATINGS:
LD50 Lethal Dose (solids & liquids) which kills 50% of the
exposed animals s
A G
LC50 Lethal concentration (gases) which kills 50% of the
exposed animal
B H ppm Concentration expressed in parts of material per
million parts
C I TDlo Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or
D J TC, TCo, LClo, & LCo toxic effects
IARC International Agency for Research on Cancer
E K NTP National Toxicology Program
RTECS Registry of Toxic Effects of Chemical Substances
Consult your supervisor or S.O.P. for BCF Bioconcentration Factor
F X special handling directions. TLm Median threshold limit
log KOW or log KOC Coefficient of Oil/Water Distribution
REGULATORY INFORMATION:
Face Shield &
Safety Glasses Splash Goggles Gloves
Eye Protection
WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
TC Transport Canada
Boots Synthetic Apron Full Suit Dust Respirator EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
NDSL Canadian Non-Domestic Substance List
Dust & Vapor Full Face Airline Hood/Mask
PSL Canadian Priority Substances List
Vapor Respirator Respirator
Respirator or SCBA
TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
Note: the dotted circle indicates that this respiratory protective
equipment is required for high concentrations or for large
volume spills or releases of product.
EC INFORMATION:
OTHER STANDARD ABBREVIATIONS:
NA Not Available
NR No Results
NE Not Established
ND Not Determined C E F N O T+ Xi Xn
ML Maximum Limit
SCBA Self-Contained Breathing Apparatus Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
|