Material Safety Data Sheet
THINSOL 160
1 Chemical product and company identification
: 7780
Common name : THINSOL 160 Code
Supplier : Sasol Solvents MSDS# :
Private Bag X55
Saxonwold
2132
South Africa
TEL: +27 11 280-0000
Synonym : Not available. Validation date : 12/8/2003.
Trade name : Thinsol 160 Print date : 12/8/2003.
Material uses : Not available. Prepared by : Aneshia Ambaram
Manufacturer : Sasol Chemical Industries In case of : SOUTH AFRICA: 0800 11
P.O. Box 1 emergency 28 90
Sasolburg INTERNATIONAL: +27 17
1947 610 4444
Republic of South Africa
TEL: +27 16 960-9111
2 Composition / information on ingredients
CAS #
Name % by Exposure limits
weight
n-Propanol 71-23-8 26 ACGIH TLV (United States, 2003)
STEL: 250 ppm 15 minute(s).
TWA: 200 ppm 8 hour(s).
OSHA PEL Z1 (United States, 1993).
TWA: 200 ppm 8 hour(s).
TWA: 500 mg/m 3 8 hour(s).
Toluene 108-88-3 19-26 ACGIH TLV (United States, 2003)
TWA: 50 ppm 8 hour(s).
OSHA PEL Z2 (United States, 2003).
TWA: 200 ppm 8 hour(s).
CEIL: 300 ppm
NIOSH (United States, 1997).
STEL: 150 ppm 15 minute(s).
NIOSH (United States, 1997).
STEL: 560 mg/m 3 15 minute(s).
Acetone 17 ACGIH TLV (United States, 2002)
TWA: 500 ppm 8 hour(s).
TWA: 1188 mg/m 3 8 hour(s).
STEL: 750 ppm 15 minute(s).
STEL: 1782 mg/m 3 15 minute(s).
OSHA (United States, 2002).
TWA: 750 ppm 8 hour(s).
TWA: 1800 mg/m 3 8 hour(s).
STEL: 1000 ppm 15 minute(s).
STEL: 2400 mg/m 3 15 minute(s).
Xylenes 1330-20-7 7-12 ACGIH TLV (United States, 2003)
TWA: 100 ppm 8 hour(s).
STEL: 150 ppm 15 minute(s).
OSHA PEL Z1 (United States, 1993).
: 100 ppm
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THINSOL 160
3
: 435 mg/m
NIOSH (United States, 1997).
STEL: 150 ppm 15 minute(s).
STEL: 655 mg/m 3 15 minute(s).
Glycol ether 6 ACGIH TLV (United States, 2003)
TWA: 20 ppm 8 hour(s).
OSHA PEL Z1 (United States, 1993).
: 50 ppm
: 240 mg/m3
NIOSH REL (United States, 1997). Skin
REL: 5 ppm 40 hour(s).
REL: 24 mg/m 3 40 hour(s).
Ethyl methyl benzene 611-14-3 1-4 Not available.
Butan-2-ol 78-92-2 3 OSHA PEL Z1 (United States, 2002).
TWA: 150 ppm 8 hour(s).
TWA: 450 mg/m 3 8 hour(s).
3 Hazards identification
Physical state and : Liquid.
appearance
Emergency overview : WARNING!
HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
RISK OF SERIOUS DAMAGE TO EYES.
HARMFUL BY INHALATION.
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS AND CRACKING.
Keep away from heat, sparks and flame. Avoid contact with eyes, skin and clothing. Do not
ingest. Avoid breathing vapor or mist. Keep container closed. Use only with adequate
ventilation. Wash thoroughly after handling.
Routes of entry : Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eyes : Risk of serious damage to eyes.
Skin : Repeated exposure may cause skin dryness or cracking.
Inhalation : Harmful by inhalation.
Ingestion : Hazardous in case of ingestion.
Potential chronic health : CARCINOGENIC EFFECTS Classified A4 (Not classifiable for human or animal.) by ACGIH,
:
effects 3 (Not classifiable for human.) by IARC [Toluene]. Classified A4 (Not classifiable for human
or animal.) by ACGIH, 3 (Not classifiable for human.) by IARC [Xylenes]. Classified None. by
OSHA, None. by NIOSH [Acetone]. Classified A4 (Not classifiable for human or animal.) by
ACGIH, D (Not classifiable for human or animal.) by EPA [Acetone]. Classified A3 (Proven
for animal.) by ACGIH [Propyl alcohol]. Classified None. by OSHA, None. by NIOSH [Propyl
alcohol]. Classified 4 (Probably not for human.) by IARC, None. by NIOSH [Butan-2-ol].
Classified None. by NIOSH [2-Methylpropan-1-ol]. Classified A3 (Proven for animal.) by
ACGIH [Glycol ether].
MUTAGENIC EFFECTS Non-mutagenic for bacteria and/or yeast. [Xylenes].
:
TERATOGENIC EFFECTS Classified None. for human [Acetone].
:
Medical conditions : No data available
aggravated by
overexposure:
Overexposure : No data available.
/signs/symptoms
See toxicological information (section 11)
4 First aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water for at
least 15 minutes, keeping eyelids open. Get medical attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention if symptoms appear.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
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THINSOL 160
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie,
belt or waistband. If large quantities of this material are swallowed, call a physician
immediately.
Notes to physician : Support respiratory and cardiovascular function.
5 Fire fighting measures
Flammability of the product : Flammable.
Autoignition temperature : The lowest known value is 238掳C (460.4掳F) (Glycol ether).
Flash points : Closed cup: <0掳C (32掳F).
Flammable limits : The greatest known range is LOWER: 1.1% UPPER: 12.7% (Glycol ether)
Products of combustion : These products are carbon oxides (CO, CO2).
Fire hazards in presence of : Flammable in presence of open flames, sparks and static discharge, of heat, of oxidizing
various substances materials, of combustible materials, of reducing materials, of alkalis.
Explosion hazards in : No data available.
presence of various
substances
Fire fighting media : SMALL FIRE: Use DRY chemical powder.
and instructions LARGE FIRE: Use water spray or fog. Cool containing vessels with water jet in order to
prevent pressure build-up, autoignition or explosion.
Protective clothing (fire) : Be sure to use an approved/certified respirator or equivalent.
Special remarks on fire : Explosive in the form of vapor when exposed to heat or flame. Vapor may travel
hazards considerable distance to source of ignition and flash back. When heated to decomposition
it emits acrid smoke and irritating fumes.
Special remarks on : No additional remark.
explosion hazards
6 Accidental release measures
Small spill and leak : Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large spill and leak : Keep away from heat. Keep away from sources of ignition. Stop leak if without risk.
Absorb with DRY earth, sand or other non-combustible material. Do not get water inside
container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry
into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
7 Handling and storage
Handling : Keep away from heat, sparks and flame. Keep container closed. Use only with adequate
ventilation. To avoid fire or explosion, dissipate static electricity during transfer by
grounding and bonding containers and equipment before transferring material. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment.
Storage : Store in a segregated and approved area. Keep container in a cool, well-ventilated area.
Keep container tightly closed and sealed until ready for use. Avoid all possible sources of
ignition (spark or flame).
8 Exposure controls, personal protection
Engineering controls : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapors below their respective occupational exposure limits. Ensure that
eyewash stations and safety showers are proximal to the work-station location.
Personal protection
Eyes : Splash goggles.
Body : Chemical resistant protective suit.
Respiratory : Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate.
Hands : Chemical resistant gloves.
Feet : Chemical resistant safety boots.
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THINSOL 160
Protective clothing :
(pictograms)
: Splash goggles. Full suit. Boots. Gloves. A self contained breathing apparatus should be used to avoid
Personal protection in case
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
of a large spill
BEFORE handling this product.
Product name Exposure limits
Propyl alcohol ACGIH TLV (United States, 2003)
STEL: 250 ppm 15 minute(s).
TWA: 200 ppm 8 hour(s).
OSHA PEL Z1 (United States, 1993).
TWA: 200 ppm 8 hour(s).
TWA: 500 mg/m 3 8 hour(s).
Toluene ACGIH TLV (United States, 2003)
TWA: 50 ppm 8 hour(s).
OSHA PEL Z2 (United States, 2003).
TWA: 200 ppm 8 hour(s).
CEIL: 300 ppm
NIOSH (United States, 1997).
STEL: 150 ppm 15 minute(s).
NIOSH (United States, 1997).
STEL: 560 mg/m 3 15 minute(s).
Acetone ACGIH TLV (United States, 2002)
TWA: 500 ppm 8 hour(s).
TWA: 1188 mg/m 3 8 hour(s).
STEL: 750 ppm 15 minute(s).
STEL: 1782 mg/m 3 15 minute(s).
OSHA (United States, 2002).
TWA: 750 ppm 8 hour(s).
TWA: 1800 mg/m 3 8 hour(s).
STEL: 1000 ppm 15 minute(s).
STEL: 2400 mg/m 3 15 minute(s).
Xylenes ACGIH TLV (United States, 2003)
TWA: 100 ppm 8 hour(s).
STEL: 150 ppm 15 minute(s).
OSHA PEL Z1 (United States, 1993).
: 100 ppm
: 435 mg/m3
NIOSH (United States, 1997).
STEL: 150 ppm 15 minute(s).
STEL: 655 mg/m 3 15 minute(s).
Ethylene glycol monobutyl ether ACGIH TLV (United States, 2003)
TWA: 20 ppm 8 hour(s).
OSHA PEL Z1 (United States, 1993).
: 50 ppm
: 240 mg/m3
NIOSH REL (United States, 1997). Skin
REL: 5 ppm 40 hour(s).
REL: 24 mg/m 3 40 hour(s).
Ethyl toluene Not available.
Butan-2-ol OSHA PEL Z1 (United States, 2002).
TWA: 150 ppm 8 hour(s).
TWA: 450 mg/m 3 8 hour(s).
9 Physical and chemical properties
Physical state and : Liquid.
appearance
Color : Clear, colourless. (Light.)
Odor : No data available.
Taste : No data available.
Molecular weight : Not applicable.
Molecular formula : Not applicable.
pH (1% soln/water) : Neutral.
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THINSOL 160
Boiling/condensation point : 82掳C (179.6掳F)
Melting/freezing point : May start to solidify at -70.4掳C (-94.7掳F) based on data for: Glycol ether. Weighted average:
-103.95掳C (-155.1掳F)
Critical temperature : No data available.
Specific gravity : 0.821 (Water = 1)
Vapor pressure : The highest known value is 24 kPa (180 mmHg) (at 20掳C) (Acetone). Weighted average:
6.28 kPa (47.1 mmHg) (at 20掳C)
Vapor density : The highest known value is 4.1 (Air = 1) (Glycol ether). Weighted average: 2.69 (Air = 1)
Volatility : 100% (v/v). (Propyl alcohol.) Weighted average: 100% (v/v) 100% (w/w). ( Propyl
alcohol.) Weighted average: 100% (w/w).
Odor threshold : The lowest known value is 0.1 ppm (Glycol ether) Weighted average: 15.97 ppm
Evaporation rate : 1.109 compared to Butyl acetate.
VOC : 100 (%)
Viscosity : Dynamic: The highest known value is 6.4 cP (Glycol ether) Weighted average: 1.52 cP
LogKow : No data available.
Ionicity (in water) : No data available.
Dispersion properties : Is not dispersed in cold water, hot water, methanol, diethyl ether, n-octanol.
See solubility in methanol, diethyl ether, n-octanol.
Solubility : Soluble in methanol, diethyl ether, n-octanol.
Physical chemical comments : No additional remark.
10 Stability and reactivity
Stability and reactivity : The product is stable.
Conditions of instability : Sparks, open flames, heat and other ignition sources.
Incompatibility with various : Reactive with oxidizing agents , reducing agents, organic materials, acids, alkalis and
substances metals.
Hazardous decomposition : No data available.
products
Hazardous polymerization : Will not occur.
11 Toxicological information
: Acute oral toxicity (LD50): 1441 mg/kg (Rat) (Calculated value for the mixture).
Toxicity to Animals
Acute dermal toxicity (LD50): 220 mg/kg [Rabbit]. (Glycol ether).
Acute toxicity of the vapor (LC50): 450 ppm 4 hour(s) [Rat]. (Glycol ether).
Chronic effects on humans : CARCINOGENIC EFFECTS Classified A4 (Not classifiable for human or animal.) by
:
ACGIH, 3 (Not classifiable for human.) by IARC [Toluene]. Classified A4 (Not classifiable
for human or animal.) by ACGIH, 3 (Not classifiable for human.) by IARC [Xylenes].
Classified None. by OSHA, None. by NIOSH [Acetone]. Classified A4 (Not classifiable for
human or animal.) by ACGIH, D (Not classifiable for human or animal.) by EPA [Acetone].
Classified A3 (Proven for animal.) by ACGIH [Propyl alcohol]. Classified None. by OSHA,
None. by NIOSH [Propyl alcohol]. Classified 4 (Probably not for human.) by IARC, None.
by NIOSH [Butan-2-ol]. Classified None. by NIOSH [2-Methylpropan-1-ol]. Classified A3
(Proven for animal.) by ACGIH [Glycol ether].
MUTAGENIC EFFECTS Non-mutagenic for bacteria and/or yeast. [Xylenes].
:
TERATOGENIC EFFECTS Classified None. for human [Acetone].
:
Other toxic effects on : No additional remark.
humans
Special remarks on toxicity to : No additional remark.
animals
Special remarks on chronic : Inhalation of vapors may cause dizziness, an irregular heartbeat, narcosis, nausea or
effects on humans asphyxiation. (Toluene)
Special remarks on other : No additional remark.
toxic effects on humans
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THINSOL 160
12 Ecological information
: No data available.
Ecotoxicity
BOD and COD : No data available.
Biodegradable/OECD : No data available.
Mobility : No data available.
Products of degradation : These products are Carbon oxides (CO, CO2) and water.
Toxicity of the products of : No data available
biodegradation
Special remarks on the : No food chain concentration potential. (Propyl alcohol)
products of biodegradation
13 Disposal considerations
Waste information : Waste must be disposed of in accordance with federal, state and local environmental control
regulations.
Waste stream : No data available.
Consult your local or regional authorities.
14 Transport information
Packing
Regulatory UN Proper shipping name Class Label Additional
group
information number information
II -
DOT UN1993 FLAMMABLE LIQUIDS, Class 3:
Classification N.O.S. Flammable liquid. FLAMMABLE LIQUID
3
II
TDG UN1993 FLAMMABLE LIQUIDS, Class 3: -
Classification N.O.S. Flammable liquid.
FLAMMABLE LIQUIDS, I M D G C l a s s 3 : II
IMDG Class UN1993 -
N.O.S. Flammable liquid.
3
FLAMMABLE LIQUIDS, I A T A C l a s s 3 : II -
IATA-DGR UN1993
Class N.O.S. Flammable liquid.
3
15 Regulatory information
HCS classification : Class: Flammable liquid having a flash point lower than 37.8掳C (100掳F).
Class: Irritating substance.
U.S. Federal regulations : TSCA 4(a) proposed test rules: Butan-2-ol
TSCA 5(e) substance consent order: Aliphatic ketone; 2-Methylpropan-1-ol
TSCA 8(a) PAIR: Trimethyl benzene (isomers); Butan-2-ol; 2-Methylpropan-1-ol
TSCA 8(a) IUR: Aliphatic ketone; 2-Methylpropan-1-ol
TSCA 8(b) inventory: Toluene; Xylenes; Ethyl toluene; Trimethyl benzene (isomers);
Aliphatic ketone; Propyl alcohol; Butan-2-ol; 2-Methylpropan-1-ol; Glycol ether
TSCA 8(d) H and S data reporting: Toluene; Xylenes; Butan-2-ol; Glycol ether
TSCA 12(b) one time export: Aliphatic ketone
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Butan-2-ol; 2-Methylpropan-1-ol
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Butan-2-ol:
Fire Hazard, Immediate (Acute) Health Hazard, Delayed (Chronic) Health Hazard;
2-Methylpropan-1-ol: Fire Hazard, Immediate (Acute) Health Hazard, Delayed (Chronic)
Health Hazard
SARA 313 toxic chemical notification and release reporting: Xylenes 9.996%; Butan-2-ol
3.1482%
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THINSOL 160
Clean Water Act (CWA) 307: Toluene
Clean Water Act (CWA) 311: Toluene; Xylenes
Clean air act (CAA) 112 accidental release prevention: Toluene; Xylenes
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
State regulations : Connecticut hazardous material survey.: Propyl alcohol
Illinois toxic substances disclosure to employee act: Glycol ether
Illinois chemical safety act: Propyl alcohol; Glycol ether
Rhode Island RTK hazardous substances: Toluene; Xylenes; Trimethyl benzene (isomers);
Aliphatic ketone; Propyl alcohol; Butan-2-ol; 2-Methylpropan-1-ol; Glycol ether
Pennsylvania RTK: Toluene; Xylenes: (environmental hazard); Trimethyl benzene
(isomers); Aliphatic ketone: (environmental hazard); Propyl alcohol; Butan-2-ol:
(environmental hazard, generic environmental hazard); 2-Methylpropan-1-ol:
(environmental hazard, generic environmental hazard); Glycol ether
Florida: Toluene; Xylenes; Trimethyl benzene (isomers); Aliphatic ketone; Propyl alcohol;
Butan-2-ol; 2-Methylpropan-1-ol
Minnesota: Toluene; Xylenes; Trimethyl benzene (isomers); Aliphatic ketone; Propyl
alcohol; Butan-2-ol; 2-Methylpropan-1-ol; Glycol ether
Michigan critical material: Toluene; Xylenes
Massachusetts RTK: Toluene; Xylenes; Trimethyl benzene (isomers); Aliphatic ketone;
Propyl alcohol; Butan-2-ol; 2-Methylpropan-1-ol; Glycol ether
Massachusetts spill list: Glycol ether
New Jersey: Toluene; Xylenes; Aliphatic ketone; Butan-2-ol; 2-Methylpropan-1-ol; Glycol
ether
New Jersey spill list: Toluene; Xylenes; Trimethyl benzene (isomers); Aliphatic ketone;
Propyl alcohol; Butan-2-ol; 2-Methylpropan-1-ol; Glycol ether
Louisiana spill reporting: Propyl alcohol; Glycol ether
California prop. 65: This product contains the following ingredients for which the State of
California has found to cause cancer, birth defects or other reproductive harm, which would
require a warning under the statute: Toluene
California prop. 65 (no significant risk level): Toluene: 7 mg/day (value), 13 mg/day
(inhalation)
California prop. 65: This product contains the following ingredients for which the State of
California has found to cause birth defects which would require a warning under the statute:
Toluene
EU Regulations
:
Hazard symbol(s)
: Highly flammable, Harmful
Classification
: R11- Highly flammable.
Risk phrases
R20- Harmful by inhalation.
R41- Risk of serious damage to eyes.
R66- Repeated exposure may cause skin dryness or cracking.
: S9- Keep container in a well-ventilated place.
Safety phrases
S16- Keep away from sources of ignition - No smoking.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S39- Wear eye/face protection.
S60- This material and its container must be disposed of as hazardous waste.
: 200-746-9 (Propyl alcohol), 200-662-2 (Acetone), 203-625-9 (Toluene), 215-535-7
EINECS Number
(Xylene), 203-905-0 (Ethylene glycol monobytyl ether), 210-255-1 (Ethyl methyl
benzene), 201-158-5 (Butan-2-ol).
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THINSOL 160
16 Other information
National Fire Fire Hazard
3
Protection
2 0
Association Health Reactivity
(U.S.A.) Specific hazard
References : -Manufacturer's Material Safety Data Sheet.
-BDH; Hazard Data disks, Version 3.
-R T E C H S: National Institute for Occupational Safety and Health, Issue: 97-3 (August,
1997).
-C E S A R S: Chemical Evaluation and Retrieval System, Produced by: Ontario Ministry of
Environment and Michigan Department of Natural Resources, Issue: 97-3 (August, 1997).
-C H R I S: Chemical Hazards Response Information System; United States Coast Guard,
Issue: 97-3 (August, 1997).
-CHEMINFO: Canadian Centre for Occupational Health and Safety, Issue: 97-3 (August,
1997).
-Hazardous Substances Data Bank (HSDB), Issue: 97-3 (August, 1997).
-TOMES Plus System: Toxicology, Occupational Medicine & Environmental Series:
incorporating MEDITEX, HAZARDTEXT, 1st Medical Response Protocols, INFOTEXT,
HSDB, CHRIS, OHM/TADS, IRIS, NIOSH Pocket Guide, RTECS, NJ Fact Sheets, North
American Emergency Response Guides, REPROTEXT, REPROTOX, TERIS, Shepard's
Catalog of Teratogenic Agents.
-LOLI Database: The regulated Chemicals List of Lists .
Other special : No additional remarks.
considerations
Date of printing : 12/8/2003.
: 12/8/2003.
Date of issue
Date of previous issue : No Previous Validation.
Version :1
Dr Thembakazi Mali.
Verified by :
Notice to reader
This MSDS summarises at the date of issue our best knowledge of the health, safety and environmental hazard information related to the product, and in
particular how to safely handle, use, store and transport the product in the workplace. Since SASOL and its subsidiaries cannot anticipate or contro
conditions under which the product may be handled, used, stored or transported, each user must, prior to usage, review this MSDS in the context of how
the user intends to handle, use, store or transport the product in the workplace and beyond, and communicate such information to all relevant parties.If
clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
We shall not assume any liability for the accuracy or completeness of the information contained herein or any advice given unless there has been gross
negligence on our part. In such event our liability shall be limited only to direct damages suffered. Our responsibility for product as sold is subject to our
standard terms and conditions, a copy of which is sent to our customers and is also available upon request. All risk associated with the possession and
application of the product passes on delivery.
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