Part No.: 19-0712-04
MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand WASP-FREEZE庐 Wasp & Hornet Killer Formula 1
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (Prosar) TRANSPORTATION: 800-424-9300 (Chemtrec)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION SECTION 5. FIRE FIGHTING MEASURES
Product Name: Prescription Treatment庐 brand WASP-FREEZE庐 FIRE AND EXPLOSION
Wasp & Hornet Killer Formula 1 Flash Point (TCC): 144掳F
EPA Reg. No.: 499-362 Flame Projection: NE
Product Code(s): 02-0518 (12 x 17.5 oz) Explodibility Limits of Propellant in Air (% by volume):
EPA Signal Word: CAUTION Lower (LEL) = NE Upper (UEL) = NE
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc. NFPA 30B Flammability: Level III Aerosol
3568 Tree Court Industrial Blvd. UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
St. Louis MO 63122-6682 Contents under pressure. Exposure to temperatures above 130掳F may cause bursting.
IN CASE OF FIRE
SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS Extinguisher Media: CO2, Dry Chemical, Foam
Special Fire Fighting Procedures: None required
COMPOSITION INFORMATION
ACTIVE INGREDIENTS (0.249%) % CAS NO.
SECTION 6. ACCIDENTAL RELEASE MEASURES
d-trans Allethrin 0.129 28057-48-9
Phenothrin 0.120 26002-80-2 IN CASE OF SPILL OR LEAK
If container begins to leak (through puncture, etc.), eliminate all ignition sources and
OTHER INGREDIENTS* (99.751%)
allow to discharge completely in well ventilated area, then dispose of as directed below.
Petroleum Distillate > 10.0 64742-47-8 This product contains no Comprehensive Environmental Response, Compensation and
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the Liability Act (CERCLA) listed chemicals. Releases of this product are NOT reportable to
OSHA Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200. the National Response Center.
Emergency Telephone Number of Chemtrec: 800-424-9300 (for transportation spills)
EXPOSURE INFORMATION
PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
OSHA PEL ACGIH TLV
Eyes: Use proper protection 鈥? safety glasses are recommended.
MATERIAL STEL TWA STEL TWA
Skin: Wear chemical-resistant gloves. (Good practice requires that gross amounts of any
d-trans Allethrin NE NE NE NE
chemical be removed from the skin as soon as practical, especially before eating
Phenothrin NE NE NE NE
or smoking.)
Petroleum Distillate* NE 500 ppm NE NE
Inhalation: Use of a respirator may be appropriate when working with spills in enclosed
* TWA recommended by ingredient supplier = 166 ppm
or confined spaces, or when prolonged exposure to product vapor or spray mist may
occur. When using a respirator, wear a NIOSH approved respirator with an organic vapor
SECTION 3. HAZARDS IDENTIFICATION (OV) cartridge or canister with any R or P prefilter. See 29 CFR 1910.134 for respiratory
NOTES TO PHYSICIAN protection, training and testing requirements.
Contains petroleum distillate 鈥? vomiting may cause aspiration pneumonia. WASTE DISPOSAL METHOD
SIGNS/SYMPTOMS OF EXPOSURE Do not contaminate water, food or feed by storage or disposal of wastes. Take full or leak-
May cause eye irritation. Prolonged exposure may cause skin irritation and dermatitis. ing containers to a local disposal company for biological treatment or incineration.
High concentrations of the petroleum distillate (> 1,000 ppm) may cause headache and Review all local, state and federal regulations concerning health and pollution to deter-
dizziness, are anesthetic, and may have other central nervous system effects. When used mine approved disposal procedures. NEVER PLACE WASTES DOWN ANY INDOOR OR
according to label directions, this level will not be attained. OUTDOOR DRAIN OR SEWER.
ROUTES OF ENTRY
Primary: Skin Secondary: Inhalation Tertiary: Ingestion SECTION 7. HANDLING AND STORAGE
HAZARDOUS DECOMPOSITION PRODUCTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Thermal decomposition in open flame may result in carbon dioxide. Keep out of reach of children. CAUTION 鈥? Harmful if swallowed, inhaled or absorbed
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS through skin. Avoid breathing vapors or spray mist. Avoid contact with skin, eyes or
Contents under pressure. Exposure to temperatures above 130掳F may cause bursting. clothing. Wash thoroughly with soap and water after handling. Remove contaminated
clothing and wash clothing before reuse.
SECTION 4. FIRST AID MEASURES PHYSICAL OR CHEMICAL HAZARDS
Flammable. Contents under pressure. Keep away from heat, sparks and open flame.
Have the product container or label with you when calling a poison control center or doctor
Do not puncture or incinerate container. Exposure to temperatures above 130掳F may
or going for treatment. Describe any symptoms and follow the advice given.
cause bursting. May cause staining (darkening) of asphalt surfaces and shingles.
Ingestion: Immediately call a poison control center or doctor. Do not induce vomiting
STORAGE
unless told to do so by a poison control center or doctor. Do not give ANY liquid to the
Do not contaminate water, food or feed. Store in a cool, dry area away from heat or open
person. Do not give anything by mouth to an unconscious person.
flame and inaccessible to children.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of
water for 15 - 20 min. Call a poison control center or doctor for treatment advice.
Eye Contact: Hold eyes open and rinse slowly and gently with water for 15 - 20 min. SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION
Remove contact lenses, if present, after the first 5 min, then continue rinsing eyes. Call
PERSONAL PROTECTIVE EQUIPMENT (PPE)
a poison control center or doctor for treatment advice.
Respiratory Protection: None required when used according to label directions.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambu-
Protective Gloves: Chemical-resistant gloves are recommended if prolonged or
lance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a poi-
repeated skin contact is likely. (Good practice requires that gross amounts of any chem-
son control center or doctor for further treatment advice.
ical be removed from the skin as soon as practical, especially before eating or smoking.)
Note to Physician: Contains petroleum distillate 鈥? vomiting may cause aspiration
Eye Protection: Use proper protection 鈥? safety glasses are recommended.
pneumonia.
Other Protective Equipment: None required
Medical Conditions Generally Aggravated by Exposure: None known
VENTILATION
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emergencies)
Local Exhaust: None required
Mechanical: None required
Special: None required
Other: None required
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MATERIAL SAFETY DATA SHEET
Prescription Treatment庐 brand WASP-FREEZE庐 Wasp & Hornet Killer Formula 1
SECTION 14. TRANSPORT INFORMATION
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Pale yellow color Odor: Solvent odor SHIPMENT BY GROUND WITHIN U.S. (DOT CLASSIFICATION)
Solubility in Water: Negligible Vapor Pressure: 100 psig @ 70掳F Proper Shipping Description: Consumer Commodity ORM-D
Viscosity: NE Vapor Density: NE Package Marking: Consumer Commodity ORM-D
Boiling Point: NE Freezing/Melting Point: NE Package Labeling: None required
pH: NE Density: 0.80 g/cm鲁 @ 68掳F (conc.) Certified Packaging: None required
Product in unopened original packaging is compliant with all regulations for ground ship-
ment within the U.S. WMG disclaims any liability for claims or damages that may result from
SECTION 10. STABILITY AND REACTIVITY
shipment by other means. Packages offered or intended for other modes of transportation are
REACTIVITY subject to additional requirements. Consult an appropriately trained shipping professional
Stability: Indefinite when used according to label directions. before offering for shipment by water or air.
Conditions to Avoid: Avoid excess heat (temperatures above 130掳F), open flame,
sparks and heated surfaces.
SECTION 15. REGULATORY INFORMATION
Incompatibility (Material to Avoid): None known
Hazardous Polymerization: Will not occur CERCLA
This product contains no CERCLA listed chemicals.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition in open flame may result in carbon dioxide. SARA TITLE III SECTION 311/312 HAZARD CLASS
This product has been reviewed according to the EPA 鈥淗azard Categories鈥? promulgated
under Section 311 and 312 of the Superfund Amendment and Reauthorization Act of
SECTION 11. TOXICOLOGICAL INFORMATION
1986 (SARA Title III) and is considered, under applicable definitions, to meet the follow-
ROUTES OF ENTRY ing categories:
Primary: Skin Secondary: Inhalation Tertiary: Ingestion Immediate (Acute) Health Hazard
ACUTE Fire Hazard
Eyes: Product produced slight irritation. Release of Pressure (Puncture) Hazard
Skin: Product produced moderate irritation clearing within 14 days. Acute dermal SARA TITLE III SECTION 313 CHEMICALS
LD50 > 2,000 mg/kg (rabbits). Primary skin irritation index = 4.46. Product is not a der- This product contains no substances subject to the reporting requirements of Section
mal sensitizer when tested on guinea pigs. 313 of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) or 40
Ingestion: Acute oral LD50 > 5,000 mg/kg (rats). CFR Part 372 in concentrations above the de minimis concentration level.
Inhalation: Unlikely due to product being pressurized and producing particles large
TSCA
enough not to be respirable.
All components of this product are listed or excluded from listing on the US Toxic
CHRONIC / CARCINOGENICITY Substance Control Act (TSCA) Chemical Substance Inventory.
Neither this product nor any of its ingredients are classified as carcinogens by the
National Toxicity Program (NTP), the International Agency for Research on Cancer (IARC)
SECTION 16. OTHER INFORMATION
or the Occupational Safety and Health Administration (OSHA).
NFPA HEALTH RATING INFORMATION KEY: 4 = Severe
HEALTH - 1 FLAMMABILITY - 1 REACTIVITY - 1 3 = High
SECTION 12. ECOLOGICAL INFORMATION
2 = Moderate
HMIS HAZARD RATING SYSTEM
This product is toxic to fish. Do not apply directly to water or to areas where surface water is 1 = Slight
HEALTH - 1 FLAMMABILITY - 1 REACTIVITY - 1
present or to intertidal areas below the mean high water mark. Do not contaminate water by 0 = Minimal
cleaning of equipment or disposal of equipment washwaters.
SECTION 13. DISPOSAL CONSIDERATION
Do not contaminate water, food or feed by disposal of container or waste. Dispose of con-
tainer and waste in accordance with all federal, state and local regulations.
Container Disposal: Do not puncture or incinerate! Empty container by using the prod-
uct according to the label directions. Offer empty container for recycling, if available, or
place in trash if allowed by state and local regulations. If container is partly full, contact
your local solid waste agency for disposal instructions.
Waste Disposal: Wastes resulting from the use of this product may be disposed of on
site or at an approved waste disposal facility.
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with
respect to the information contained herein. For automatic MSDS updates, register at www.wmmg.com.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Part No. 19-0712-04
NE - Not Established Effective Date: 05/15/07
WHITMIRE MICRO-GEN
PEL - Permissible Exposure Limit Review Date: 05/15/07
TLV - Threshold Limit Value Supersedes: 06/02/04
RESEARCH LABORATORIES, INC.
STEL - Short Term Exposure Limit (15 min) Text ID: 070625-4
TWA - Time Weighted Average (8 hr) Code #: 143-063
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