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Issue Date: 25-Aug-2004 CHEMWATCH 4598-18
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Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
0893 100 023 - UNIVERSAL GLUE - EXTRA
STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New
Zealand Hazardous Substances New Organisms legislation.
OTHER NAMES
PROPER SHIPPING NAME
ADHESIVES containing flammable liquid
PRODUCT USE
Contact glue for most surfaces.
The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing.
Before starting consider control of exposure by mechanical ventilation.
SUPPLIER
Company: Wurth New Zealand Limited
Address:
42 Hobill Avenue
Manukau City
Auckland
NZL
Telephone: 0800 683 040
Fax: 0800 100 104
Section 2 - HAZARDS IDENTIFICATION
GHS Classification
Chronic Aquatic Hazard Category 3
Eye Irritation Category 2A
Flammable Liquid Category 2
Respiratory Irritation Category 3
EMERGENCY OVERVIEW
HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
3.1B 6.4A 9.1C
May cause respiratory irritation
Highly flammable liquid and vapour
Causes serious eye irritation
Harmful to aquatic life with long lasting effects
PRECAUTIONARY STATEMENTS
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Section 2 - HAZARDS IDENTIFICATION
Prevention
Take precautionary measures against static discharge
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools.
Wash hands thoroughly after handling.
Ground/bond container and receiving equipment.
Keep away from heat/sparks/open flame - No smoking.
Keep container tightly closed.
Wear protective gloves and eye/face protection.
Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Wear eye/face protection.
If eye irritation persists, get medical advice/attention.
If on skin or hair: remove/take off immediately all contaminated clothing. Rinse with
water/shower.
In case of fire, use foam for extinction.
Disposal
Dispose of contents and container in accordance with relevant legislation.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
ethyl acetate 141-78-6 40-60
naphthenic distillate, light, hydrotreated (severe) 64742-53-6. 15-24
zinc oxide 1314-13-2 0.25-2.4
p- tert- butylphenol 98-54-4 0.1-0.4
Section 4 - FIRST AID MEASURES
NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
SWALLOWED
If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than
their hips to help avoid possible aspiration of vomitus.
路 Immediately give a glass of water.
路 First aid is not generally required. If in doubt, contact a Poisons Information Centre
or a doctor.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear.
路 Flush skin and hair with running water (and soap if available).
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Section 4 - FIRST AID MEASURES
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Alcohol stable foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
路 Water spray or fog - Large fires only.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Consider evacuation (or protect in place).
路 Fight fire from a safe distance, with adequate cover.
路 If safe, switch off electrical equipment until vapour fire hazard removed.
路 Use water delivered as a fine spray to control the fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 Do not approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,
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Section 5 - FIRE FIGHTING MEASURES
consider evacuation by 500 metres in all directions.
FIRE/EXPLOSION HAZARD
路 Liquid and vapour are highly flammable.
路 Severe fire hazard when exposed to heat, flame and/or oxidisers.
路 Vapour may travel a considerable distance to source of ignition.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include:.
carbon dioxide (CO2).
other pyrolysis products typical of burning organic material.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
Personal Protective Equipment
Gloves, boots (chemical resistant).
Breathing apparatus.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb small quantities with vermiculite or other absorbent material.
路 Wipe up.
路 Collect residues in a flammable waste container.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 May be violently or explosively reactive.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Consider evacuation (or protect in place).
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Water spray or fog may be used to disperse /absorb vapour.
路 Contain spill with sand, earth or vermiculite.
路 Use only spark-free shovels and explosion proof equipment.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.
PROTECTIVE ACTIONS FOR SPILL
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Issue Date: 25-Aug-2004 CHEMWATCH 4598-18
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Section 6 - ACCIDENTAL RELEASE MEASURES
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance 25 metres
Downwind Protection Distance 300 metres
IERG Number 14
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 128 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
ethyl acetate 2000 ppm
naphthenic distillate, light, hydrotreated (severe) 500 mg/m鲁
zinc oxide 500 mg/m鲁
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
ethyl acetate 400 ppm
naphthenic distillate, light, hydrotreated (severe) 500 mg/m鲁
zinc oxide 15 mg/m鲁
other than mild, transient adverse effects without perceiving a clearly defined odour is:
ethyl acetate 400 ppm
naphthenic distillate, light, hydrotreated (severe) 100 mg/m鲁
zinc oxide 15 mg/m鲁
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Section 6 - ACCIDENTAL RELEASE MEASURES
The threshold concentration below which most people will experience no appreciable risk of health effects:
ethyl acetate 400 ppm
naphthenic distillate, light, hydrotreated (severe) 35 mg/m鲁
zinc oxide 15 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
Contains low boiling substance:
Storage in sealed containers may result in pressure buildup causing violent rupture of
containers not rated appropriately.
路 Check for bulging containers.
路 Vent periodically
路 Always release caps or seals slowly to ensure slow dissipation of vapours.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights, heat or ignition sources.
路 When handling, DO NOT eat, drink or smoke.
路 Vapour may ignite on pumping or pouring due to static electricity.
路 DO NOT use plastic buckets.
路 Earth and secure metal containers when dispensing or pouring product.
路 Use spark-free tools when handling.
路 Avoid contact with incompatible materials.
路 Keep containers securely sealed.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to
ensure safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin.
SUITABLE CONTAINER
路 Metal can or drum
路 Packaging as recommended by manufacturer.
路 Check all containers are clearly labelled and free from leaks.
路 Packing as supplied by manufacturer.
路 Plastic containers may only be used if approved for flammable liquid.
路 Check that containers are clearly labelled and free from leaks.
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Section 7 - HANDLING AND STORAGE
STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
路 Store in original containers in approved flame-proof area.
路 No smoking, naked lights, heat or ignition sources.
路 DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
路 Keep containers securely sealed.
路 Store away from incompatible materials in a cool, dry well ventilated area.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New ethyl 200 720
Zealand acetate
Workplace (Ethyl
Exposure acetate)
Standards
(WES)
New naphthenic 5 10
Zealand
Workplace distillate
Exposure , light,
Standards hydrotreat
(WES) ed
(severe)
(Oil mist,
mineral)
New zinc oxide 10
Zealand (Zinc
Workplace oxide
Exposure Dust)
Standards
(WES)
New zinc oxide 5 10
Zealand (Zinc
Workplace oxide
Exposure fume)
Standards
(WES)
The following materials had no OELs on our records
鈥? p- tert- butylphenol: CAS:98- 54- 4
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
ethyl acetate 2, 000 [LEL]
zinc oxide 500
NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
irreversible health effects or impairment of escape existed only at higher
concentrations.
ODOUR SAFETY FACTOR (OSF)
OSF=51 (ETHYL ACETATE)
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
ETHYL ACETATE:
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
Odour Threshold Value: 6.4-50 ppm (detection), 13.3-75 ppm (recognition)
The TLV-TWA provides a significant margin of safety from the standpoint of
adverse health effects. Unacclimated subjects found the odour
objectionably strong at 200 ppm. Mild nose, eye and throat irritation was
experienced at 400 ppm. Workers exposed regularly at concentrations
ranging from 375 ppm to 1500 ppm for several months showed no unusual
signs or symptoms.
NAPHTHENIC DISTILLATE, LIGHT, HYDROTREATED (SEVERE):
Human exposure to oil mist alone has not been demonstrated to cause health effects
except at levels above 5 mg/m3 (this applies to particulates sampled by a method that
does not collect vapour). It is not advisable to apply this standard to oils containing
unknown concentrations and types of additive.
ZINC OXIDE:
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their
equivalent) for all substances for which there is evidence of health effects at airborne
concentrations encountered in the workplace.
At this time no TLV has been established, even though this material may produce
adverse health effects (as evidenced in animal experiments or clinical experience).
Airborne concentrations must be maintained as low as is practically possible and
occupational exposure must be kept to a minimum.
NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified
(P.N.O.S) does NOT apply.
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
The concentration of respirable dust for application of this limit is to be determined
from the fraction that penetrates a separator whose size collection efficiency is
described by a cumulative lognormal function with a median aerodynamic diameter of 4.0 碌m
(+-) 0.3 碌m and with a geometric standard deviation of 1.5 碌m (+-) 0.1 碌m, i.e..generally
less than 5 碌m.
P-TERT-BUTYLPHENOL:
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
MAK value: 0.08 ppm, 0.08 mg/m3
MAK Category II Peak Limitation: For substances with systemic effects and with a half
-life in humans ranging from two hours to shift-length.
Allows excursions of 5 times the MAK value, for 30 minutes (on average), twice per
shift.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany.
PERSONAL PROTECTION
EYE
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
路 Overalls.
路 PVC Apron.
路 PVC protective suit may be required if exposure severe.
路 Eyewash unit.
路 Ensure there is ready access to a safety shower.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 A- AUS P -
1000 50 - A- AUS P
5000 50 Airline * -
5000 100 - A- 2 P
10000 100 - A- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
For flammable liquids and flammable gases, local exhaust ventilation or a process
enclosure ventilation system may be required. Ventilation equipment should be explosion
-resistant.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Red, brown highly flammable liquid with a characteristic odour;
does not mix with water.
Viscosity: 4000 mPas at 20 deg C.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.
Molecular Weight: Not applicable Boiling Range (掳 88 app rox.
C):
Melting Range (掳 Not available
C): Specific Gravity (water= 1): 0.88
Solubility in water (g/L): Immiscible pH (as supplied): Not applicable
pH (1% solution): Not applicable Vapour Pressure (kPa): 6 @ 20 degC.
Volatile Component (%vol): 73.7 Evaporation Rate: Not available
Relative Vapour Density (air=1): Not available Flash Point (掳 - 4
C):
Lower Explosive Limit (%): 0.8 Upper Explosive Limit (%): 11.5
Autoignition Temp (掳 215
C): Decomposition Temp (掳 Not av ailable
C):
State: Liquid Viscosity: Not available
log Kow: 0.66-0.73
log Kow: 3.31-3.65
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified by EC Directives or other classification systems as
"harmful by ingestion". This is because of the lack of corroborating animal or human
evidence. The material may still be damaging to the health of the individual, following
ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident.
Present definitions of harmful or toxic substances are generally based on doses producing
mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal
tract discomfort may produce nausea and vomiting. In an occupational setting however,
ingestion of insignificant quantities is not thought to be cause for concern.
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Section 11 - TOXICOLOGICAL INFORMATION
EYE
Evidence exists, or practical experience predicts, that the material may cause eye
irritation in a substantial number of individuals. Repeated or prolonged eye contact may
cause inflammation (similar to windburn) characterised by a temporary redness of the
conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
The liquid produces a high level of eye discomfort and is capable of causing pain and
severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of
vision, if not promptly and adequately treated.
SKIN
The material may accentuate any pre-existing dermatitis condition.
Repeated exposure may cause skin cracking, flaking or drying following normal handling
and use.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis. Histologically there may
be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the
epidermis.
INHALED
Inhalation hazard is increased at higher temperatures.
Acute effects from inhalation of high concentrations of vapour are pulmonary irritation,
including coughing, with nausea; central nervous system depression - characterised by
headache and dizziness, increased reaction time, fatigue and loss of co-ordination.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and by inhalation of
vapours especially at higher temperatures.
Prolonged or continuous skin contact with the liquid may cause defatting with drying,
cracking, irritation and dermatitis following.
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
As with any chemical product, contact with unprotected bare skin; inhalation of vapour,
mist or dust in work place atmosphere; or ingestion in any form, should be avoided by
observing good occupational work practice.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
ETHYL ACETATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 5620 mg/kg Eye (human): 400 ppm
Inhalation (rat) LC50: 1600 ppm/8h
Inhalation (human) TCLo: 400 ppm
Inhalation (Human) TCLo: 400 ppm/4h
Oral (Mouse) LD50: 4100 mg/kg
Intraperitoneal (Mouse) LD50: 709 mg/kg
Oral (Rabbit) LD50: 4935 mg/kg
Oral (Guinea) pig: LD50 5500 mg/kg
NAPHTHENIC DISTILLATE, LIGHT, HYDROTREATED (SEVERE):
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: > 5000 mg/kg *
Inhalation (rat) LC50: 2200 mg/m鲁/4h * *
[MORTON]
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Issue Date: 25-Aug-2004 CHEMWATCH 4598-18
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Section 11 - TOXICOLOGICAL INFORMATION
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
ZINC OXIDE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 500 mg/kg Skin : Mild
Inhalation (human) TCLo: 600 mg/m鲁 Eye : Mild
Oral (mouse) LD50: 7950 mg/kg
Oral (Rat) LD50: >8437 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling epidermis. Histologically there may
be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the
epidermis.
P-TERT-BUTYLPHENOL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 2951 mg/kg Skin (rabbit): 500 mg/4h - Mild
Dermal (rabbit) LD50: 2288 mg/kg Eye (rabbit): 10 mg - SEVERE
Eye (rabbit) 0.05 mg/24h - SEVERE
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
ETHYL ACETATE:
log Pow (Verschueren 1983): 0.66/0.73
ThOD: 50.4
log Pow (Verschueren 1983): 0.66/0.73
BOD5: 15%
COD: 1.54 (83%)
ThOD: 1.82
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 353
Half- life Air - Low (hours): 35.3
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 336
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
Aqueous biodegradation - Anaerobic - Low (hours): 96
Aqueous biodegradation - Removal secondary treatment - High (hours): 96%
Aqueous biodegradation - Removal secondary treatment - Low (hours): 99.90%
Photooxidation half- life water - High (hours): 9.60E+05
Photooxidation half- life water - Low (hours): 24090
Photooxidation half- life air - High (hours): 353
Photooxidation half- life air - Low (hours): 35.3
First order hydrolysis half- life (hours): 1.77E+04
Acid rate constant [M(H+)- HR]- 1: 3.05E- 08
Base rate constant [MOH)- HR]- 1: 2.99E- 05
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Issue Date: 25-Aug-2004 CHEMWATCH 4598-18
NA477ECP Version No:3
CD 2007/2 Page 14 of 16
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
log Kow: 0.66-0.73
Half-life (hr) air: 200
Half-life (hr) H2O surface water: 10
Henry's atm m鲁 /mol: 1.20E-04
BOD 5 if unstated: 0.1-1.24,16-36%
COD: 1.54,83%
ThOD: 1.82
NAPHTHENIC DISTILLATE, LIGHT, HYDROTREATED (SEVERE):
Not readily biodegradable
ZINC OXIDE:
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.
P-TERT-BUTYLPHENOL:
log Pow (Verschueren 1983): 3.31
log Kow: 3.31-3.65
Toxicity Fish: LC50(96)0.74-5.1mg/L
Toxicity invertebrate: LD0 >100
Bioacculmulation: not sig
Effects on algae and plankton: inhib degrad.glucose25mg/L.LD0 10mg/L
Degradation Biological: resist
Section 13 - DISPOSAL CONSIDERATIONS
路 Consult manufacturer for recycling options and recycle where possible .
路 Consult State Land Waste Management Authority for disposal.
路 Incinerate residue at an approved site.
路 Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE LIQUID
HAZCHEM: 3[Y]E
UNDG:
Dangerous Goods Class: 3 Subrisk: None
UN Number: 1133 Packing Group: II
Shipping Name:ADHESIVES containing flammable liquid
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Chemwatch Material Safety Data Sheet
Issue Date: 25-Aug-2004 CHEMWATCH 4598-18
NA477ECP Version No:3
CD 2007/2 Page 15 of 16
Section 14 - TRANSPORTATION INFORMATION
Air Transport IATA:
ICAO/IATA Class: 3 ICAO/IATA Subrisk: None
UN/ID Number: 1133 Packing Group: II
ERG Code: 3L
Shipping name:ADHESIVES containing flammable liquid
Maritime Transport IMDG:
IMDG Class: 3 IMDG Subrisk: None
UN Number: 1133 Packing Group: II
EMS Number: F- E, S- D Marine Pollutant: Not Determined
Shipping name:ADHESIVES containing flammable liquid
Section 15 - REGULATORY INFORMATION
REGULATIONS
0893 100 023 - Universal Glue - Extra (CAS No: None):
No regulations applicable
ethyl acetate (CAS: 141-78-6) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances (Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
naphthenic distillate, light, hydrotreated (severe) (CAS: 64742-53-6) is found on the following regulatory lists;
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
zinc oxide (CAS: 1314-13-2) is found on the following regulatory lists;
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
p-tert-butylphenol (CAS: 98-54-4) is found on the following regulatory lists;
OECD Representative List of High Production Volume (HPV) Chemicals
OSPAR List of Substances of Possible Concern
Specific advice on controls required for materials used in
New Zealand can be found at
http://www.ermanz.govt.nz/search/registers.html
Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
Denmark Advisory list for selfclassification of dangerous substances
Substance CAS Suggested codes
p- tert- butylphenol 98- 54- 4 R43
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
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Chemwatch Material Safety Data Sheet
Issue Date: 25-Aug-2004 CHEMWATCH 4598-18
NA477ECP Version No:3
CD 2007/2 Page 16 of 16
Section 16 - OTHER INFORMATION
Issue Date: 25-Aug-2004
Print Date: 20-Jul-2007
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