REVISION DATE:
11220 - PERMABLAK
SAFETY DATA SHEET
PERMABLAK
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY:
PERMABLAK
PRODUCT NAME:
17314
PART No.:
- for industrial use only.
APPLICATIONS:
MacDermid plc
SUPPLIER:
Palmer Steet
Birmingham B9 4EU
Tel: 44 (0) 121-606 8100
2. COMPOSITION/INFORMATION ON INGREDIENTS:
NAME CAS No.: CONTENT SYMBOL: RISK:
SELENIUM DIOXIDE 7446-08-4 1-5 % T R-23/25, 33
3. HAZARDS IDENTIFICATION:
Possible risk of irreversible effects. May cause sensitisation by inhalation and skin
contact. Danger of cumulative effects.
4. FIRST AID MEASURES:
Move the exposed person to fresh air at once. Perform artificial respiration if breathing
INHALATION:
has stopped. Keep the affected person warm and at rest. Get prompt medical
attention.
NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! DO NOT
INGESTION:
INDUCE VOMITING! Get medical attention.
Remove affected person from source of contamination. Promptly wash contaminated
SKIN:
skin with soap or mild detergent and water. Promptly remove clothing if soaked through
and wash as above. Get medical attention promptly if symptoms occur after washing.
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for
EYES:
at least 15 minutes and get medical attention.
5. FIRE FIGHTING MEASURES:
Water spray, fog or mist. Powder, foam or CO2.
EXTINGUISHING MEDIA:
Keep run-off water out of sewers and water sources. Dike for water control. Move
SPECIAL FIRE FIGHTING
container from fire area if it can be done without risk. If risk of water pollution occurs,
PROCEDURES:
notify appropriate authorities. NOTE! Use air-supplied respirators to protect against
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REVISION DATE:
11220 - PERMABLAK
gases\fumes.
May develop highly toxic or corrosive fumes if heated.
UNUSUAL FIRE & EXPLOSION
HAZARDS:
Self contained breathing apparatus. Full protective clothing.
PROTECTIVE MEASURES IN FIRE:
6. ACCIDENTAL RELEASE MEASURES:
Use protection as listed in section 8.
PERSONAL PRECAUTION IN SPILL:
Drains must be covered to avoid sewer/river contamination. In case of major spillage
PRECAUTIONS TO PROTECT
alert the emergency services and local water authority
ENVIRONMENT:
Provide ventilation and confine spill. Do not allow runoff to sewer. Clean-up personnel
SPILL CLEANUP METHODS:
should use respiratory and/or liquid contact protection. Absorb in vermiculite, dry sand
or earth and place into containers. Flush with plenty of water to clean spillage area.
7. HANDLING AND STORAGE:
Avoid spilling, skin and eye contact. Preferably use a mechanically operated pump to
USAGE PRECAUTIONS:
transfer the liquid. Ventilate well, avoid breathing vapours. Use approved respirator if
air contamination is above accepted level.
Keep in cool, dry, ventilated storage and closed containers.
STORAGE PRECAUTIONS:
Chemical storage.
STORAGE CRITERIA:
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION:
INGREDIENT NAME: CAS No.: STD: LT EXP. 8HRS: ST EXP. 15 MIN:
SELENIUM DIOXIDE 7446-08-4 OES. 0.1 mg/m3 No std.
PROTECTIVE EQUIPMENT:
Use engineering controls to reduce air contamination to permissible exposure level.
PROCESS CONDITIONS:
Provide adequate general and local exhaust ventilation.
VENTILATION:
Respiratory protection must be used if air concentration exceeds acceptable level.
RESPIRATORS:
Use protective gloves made of: Rubber or plastic.
PROTECTIVE GLOVES:
Wear approved chemical safety goggles where eye exposure is reasonably probable.
EYE PROTECTION:
Wear appropriate clothing to prevent repeated or prolonged skin contact.
OTHER PROTECTION:
Wash at the end of each work shift and before eating, smoking and using the toilet.
HYGIENIC WORK PRACTICES:
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REVISION DATE:
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9. PHYSICAL AND CHEMICAL PROPERTIES:
Clear. Liquid.
APPEARANCE:
Blue.
COLOUR:
Odourless or no characteristic odour.
ODOUR/TASTE:
1.27 - 1.30 20
DENSITY/SPECIFIC GRAVITY (g/ml): Temperature (掳C):
Miscible with water.
SOLUBILITY DESCRIPTION:
10. STABILITY AND REACTIVITY:
Normally stable.
STABILITY:
Avoid excessive heat for prolonged periods of time.
CONDITIONS TO AVOID:
No incompatible groups noted.
MATERIALS TO AVOID:
Fire or high temperatures create: Toxic gases/vapours/fumes of: Sulphurous gases
HAZARDOUS DECOMP.
(SOx). Oxides of: Selenium.
PRODUCTS:
11. TOXICOLOGICAL INFORMATION:
This chemical can be hazardous when inhaled and/or touched. Known or suspected
HEALTH WARNINGS:
carcinogen for humans. Repeated exposure may cause chronic eye irritation. May
cause chemical eye burns. Burning pain and severe corrosive skin damage. Swallowing
concentrated chemical may cause severe internal injury.
Carcinogen Category 3.
OTHER HEALTH EFFECTS:
Skin and/or eye contact.
ROUTE OF ENTRY:
Skin.
TARGET ORGANS:
Extreme irritation of eyes and mucous membranes, including burning and tearing. Skin
MEDICAL SYMPTOMS:
irritation. Gastrointestinal symptoms, including upset stomach.
12. ECOLOGICAL INFORMATION:
Dangerous for the environment: May cause long-term adverse effects in the aquatic
ECOLOGICAL INFORMATION:
environment.
13. DISPOSAL CONSIDERATIONS:
Use specialist disposal reference books for detail procedures. Refer to Croner麓s.
DISPOSAL METHODS:
Confirm disposal procedures with environmental engineer and local regulations.
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REVISION DATE:
11220 - PERMABLAK
14. TRANSPORT INFORMATION:
LABEL FOR CONVEYANCE:
3283
UN No. ROAD:
Division 6.1:Toxic substances.
ADR CLASS:
60 Toxic or slightly toxic substance.
HAZARD No. (ADR):
6.1
ADR LABEL No.:
SELENIUM COMPOUND, N.O.S. ( Selenium Dioxide )
PROPER SHIPPING NAME I:
6.1
RID ITEM No.:
6.1
IMDG CLASS:
III
IMDG PACK GR.:
6.1
ICAO CLASS:
III
AIR PACK GR.:
15. REGULATORY INFORMATION:
LABEL FOR SUPPLY:
R-33 Danger of cumulative effects.
RISK PHRASES:
R-40 Possible risk of irreversible effects.
R-42/43 May cause sensitisation by inhalation and skin contact.
S-20/21 When using do not eat, drink or smoke.
SAFETY PHRASES:
S-22 Do not breathe dust.
S-28 After contact with skin, wash immediately with plenty of water.
S-36/37 Wear suitable protective clothing and gloves.
S-45 In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
Health and Safety at Work Act 1974. The Control of Substances Hazardous to Health
UK REGULATORY REFERENCES:
Regulations 1988.
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REVISION DATE:
11220 - PERMABLAK
Dangerous Substance Directive 67\548. Dangerous Preparations Directive 88\379.
EU DIRECTIVES:
System of specific information relating to Dangerous Preparations. 91\155.
16. OTHER INFORMATION:
Hazardous Materials, Emergency Response Guidebook, DOT-P 5800.3, 1984.
INFORMATION SOURCES:
Chemical Hazards of the Workplace, Proctor & Hughes, Lippincott, 1978 Threshold
Limit Values and Biological Exposure Indices for 1985-86.
Mr P Moran BSc (Hons) MSc MIOSH
ISSUED BY:
A
REV. No./REPL. SDS GENERATED:
Approved.
SAFETY DATA SHEET STATUS:
26/6/97
DATE:
The information in this leaflet is believed to be correct but neither we nor our employees
DISCLAIMER:
or agents give any warranty or make any representation as to the accuracy thereof, and
accept no liability for any loss,injury or damage which may result from its use. The sole
purpose of this Data Sheet is to provide guidance on the safe handling and use of
products to which it relates.It does not form part of any product specification, nor of any
contract. It is not practical for the guidance and information in this Data Sheeet to cover
every conceivable application of the product as we may not be aware of the use to
which the products covered by this Data Sheet are to be put it remains the
responsibility of the user to conduct its own tests and to satisfy itself as to the suitability
of the product.
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