zenox
zeno TM
LUBRICANTS
ABN: 97 106 933 582
Unit 2/ 10 Success Way Wangara, WA 6065 Phone/ Fax +61 8 9403 5119; Mob: 0421 840 351
PO Box 968 Hillarys WA 6923 Email: info@zenox.com.au; Website: www.zenox.com.au
ICE IN A CAN
PRODUCT NAME
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Supplier Name ZENOX INDUSTRIES GLOBAL PTY LTD
Address PO Box 968, Hillarys, WA, AUSTRALIA, 6923
Telephone (08) 9403 5119
Fax (08) 9403 5119
Emergency 0421 840 351
Email info@zenox.com.au
Web Site http://www.zenox.com.au
Synonym(s) PAIN RELIEF SPRAY 鈥? ZENOX ICE IN A CAN 鈥? PART NUMBER: Z098
Use(s) PAIN RELIEF
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO NOHSC CRITERIA
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
UN No. 1950 Hazchem Code Pkg Group
2Y None Allocated
DG Class 2.1 Subsidiary Risk(s) EPG 2D1
None Allocated
3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Formula Conc. CAS No.
DIBROMOCHLOROPROPANE C3-H5-Br2-Cl >70% 96-12-8
ISOPENTANE C5-H12 <20% 78-78-4
4. FIRST AID MEASURES
Eye Flush gently with running water for 15 minutes.
Inhalation If over exposure occurs leave exposure area immediately. If irritation persists, seek medical attention.
Skin Gently flush affected areas with water.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor. If swallowed, do not
induce vomiting. Ingestion is considered unlikely due to product form.
Advice to Treat symptomatically
Doctor
5. FIRE FIGHTING MEASURES
Flammability Highly flammable aerosol. May evolve toxic gases (eg: carbon oxides, hydrocarbons) when heated to
decomposition. Vapours may form explosive mixtures in air. Eliminate all ignition sources including cigarettes,
open flames, spark producing switches/tools, pilot lights, heaters, naked lights etc. when handling. Aerosol cans
may explode when heated above 50 C.
Fire and Highly flammable liquid/ aerosol. For large fires, evacuate area & contact emergency services. Toxic gases
(hydrocarbons, carbon oxides) may be evolved. Remain upwind and notify those downwind of hazard. Wear full
Explosion
protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to
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Printed: 05 Jan 2007
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PRODUCT NAME
cool intact containers and nearby storage areas.
Extinguishing Dry agent, carbon dioxide or foam. Prevent contamination of drains or waterways. Absorb runoff with sand or
similar.
Hazchem Code 2Y
6. ACCIDENTAL RELEASE MEASURES
Spillage If cans (bulk) are damaged or punctured, clear area of all unprotected personnel and ventilate area. Collect and
allow to discharge outdoors. Dispose of empty cans to approved landfill.
7. STORAGE AND HANDLING
Storage Store out of direct sunlight and out of the reach of children, in a cool, dry, well ventilated area, removed from
oxidising agents (eg. hypochlorites), acids (sulphuric acid), heat sources and foodstuffs. Ensure containers are
adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should
have appropriate ventilation systems.
Handling Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin
contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating,
drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ventilation Ensure adequate natural ventilation. Flammable/explosive vapours may accumulate in poorly ventilated areas.
Vapours are heavier than air and may travel some distance to an ignition source and flash back.
Exposure ISOPENTANE (78-78-4)
ES-TWA: 500 mg/m3 (Denmark)
Standards
PPE Personal Protective Equipment is not required under normal conditions of use.
9. PHYSICAL AND CHEMICAL PROPERTIES
LIQUID (AEROSOL DISPENSED, 90G
Appearance Solubility (water) INSOLUBLE
CAN)
Odour SLIGHT ODOUR Specific Gravity NOT AVAILABLE
pH NOT AVAILABLE % Volatiles NOT AVAILABLE
Vapour Pressure NOT AVAILABLE Flammability HIGHLY FLAMMABLE
Vapour Density NOT AVAILABLE Flash Point NOT AVAILABLE
Melting Point NOT AVAILABLE Upper Explosion Limit NOT AVAILABLE
Boiling Point NOT AVAILABLE Lower Explosion Limit NOT AVAILABLE
Evaporation Rate NOT AVAILABLE Autoignition Temperature NOT AVAILABLE
10. STABILITY AND REACTIVITY
Incompatible with oxidising agents (eg. hypochlorites, peroxides), acids (eg. sulphuric acid), heat and ignition
Reactivity
sources.
Decomposition May evolve toxic gases (eg: carbon oxides, hydrocarbons) when heated to decomposition.
Products
11. TOXICOLOGICAL INFORMATION
Health Hazard Low toxicity. No adverse health effects are anticipated with normal use of this product. Deliberate misuse by
Summary inhaling contents may cause headache, dizziness and nausea.
Eye Irritant. Exposure may result in lacrimation, irritation, pain and redness.
Low irritant. Over exposure at high levels may result in irritation of the nose and throat, coughing and headache.
Inhalation
However, under normal conditions of use no adverse health effects are anticipated.
Non - low irritant. Prolonged and repeated use may result in slight irritation. Some individuals with sensitive skin
Skin
may experience adverse skin reactions, and would be advised to discontinue use.
Ingestion Low toxicity. Ingestion may result in gastrointestinal irritation, nausea and vomiting. However, due to product form,
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Printed: 05 Jan 2007
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ingestion is considered unlikely.
DIBROMOCHLOROPROPANE (96-12-8)
Toxicity Data
LC50 (Inhalation): 103 ppm/8hrs (rat)
LD50 (Ingestion): 170 mg/kg (rat)
12. ECOLOGICAL INFORMATION
Environment Hydrocarbon propellants will quickly evaporate from soil or water and enter the atmosphere. In the atmosphere
propellants are expected to exist entirely in the vapour phase and will react with hydroxyl radicals. Estimated half
lives vary from 6 days (butane) to 13 days (propane). Hydrocarbon propellants are not ozone depleting.
13. DISPOSAL CONSIDERATIONS
Waste Disposal For small amounts absorb contents with sand or similar and dispose of to an approved landfill site. Do not puncture
or incinerate aerosol cans. Contact the manufacturer for additional information.
Legislation Dispose of in accordance with relevant local legislation.
14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
Shipping Name AEROSOLS
UN No. 1950 DG Class 2.1 Subsidiary Risk(s) None Allocated
Pkg Group None Allocated Hazchem Code 2Y EPG 2D1
15. REGULATORY INFORMATION
Poison A poison schedule number has not been allocated to this product using the criteria in the Standard for the
Schedule Uniform Scheduling of Drugs and Poisons (SUSDP).
AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).
16. OTHER INFORMATION
Additional AEROSOL CANS may explode at temperatures approaching 50 C.
Information
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGE (TWA) or WES (WORKPLACE EXPOSURE
STANDARD) (NZ): Exposure standards are established on the premise of an 8 hour work period of normal
intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to
eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced:
strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the
exposure period and shorten the period of recuperation).
ABBREVIATIONS:
mg/m3 - Milligrams per cubic metre
ppm - Parts Per Million
TWA/ES - Time Weighted Average or Exposure Standard.
CNS - Central Nervous System
NOS - Not Otherwise Specified
pH - relates to hydrogen ion concentration - this value will relate to a scale of 0 - 14, where 0 is highly acidic and
14 is highly alkaline.
CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds.
M - moles per litre, a unit of concentration.
IARC - International Agency for Research on Cancer.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:
The recommendation for protective equipment contained within this Chem Alert report is provided as a guide
only. Factors such as method of application, working environment, quantity used, product concentration and the
availability of engineering controls should be considered before final selection of personal protective equipment is
made.
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HEALTH EFFECTS FROM EXPOSURE:
It should be noted that the effects from exposure to this product will depend on several factors including:
frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and
method of application. Given that it is impractical to prepare a Chem Alert report which would encompass all
possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
COLOUR RATING SYSTEM: RMT has assigned all Chem Alert reports a colour rating of Green, Amber or Red
for the sole purpose of providing users with a quick and easy means of determining the hazardous nature of a
product. Safe handling recommendations are provided in all Chem Alert reports so as to clearly identify how
users can control the hazards and thereby reduce the risk (or likelihood) of adverse effects. As a general
guideline, a Green colour rating indicates a low hazard, an Amber colour rating indicates a moderate hazard and
a Red colour rating indicates a high hazard.
While all due care has been taken by RMT in the preparation of the Colour Rating System, it is intended as a
guide only and RMT does not provide any warranty in relation to the accuracy of the Colour Rating System. As
far as is lawfully possible, RMT accepts no liability or responsibility whatsoever for the actions or omissions of
any person in reliance on the Colour Rating System.
This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the
Report Status
manufacturer's Material Safety Data Sheet ('MSDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer or
obtained from third party sources and is believed to represent the current state of knowledge as to the
appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding
any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this MSDS, it does not
provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any
loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a
consequence of their reliance on the information contained in this MSDS.
Risk Management Technologies
Prepared By
5 Ventnor Ave, West Perth
Western Australia 6005
Phone: +61 8 9322 1711
Fax: +61 8 9322 1794
Email: info@rmt.com.au
Web: www.rmt.com.au
MSDS Date: 15 May 2006
End of Report
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Printed: 05 Jan 2007
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