MATERIAL SAFETY DATA SHEET
1 CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Trade Name INK TYPE 71XX
ITW TRANS TECH
Supplier
475 N. GARY AVENUE
CAROL STREAM, IL 60188 USA
Telephone Numbers - 24 Hour Emergency Assistance
Emergency (352)323-3500
Telephone Numbers - General Assistance
Information (630)752-4000
2 COMPOSITION / INFORMATION ON INGREDIENTS
Concentration
Ingredient Name CAS Number Exposure Limits / Health Hazards
N-BUTYL ACETATE 123-86-4 20 - 26 % 150 ppm OSHA, NIOSH, ACGIH
TWA
200 ppm NIOSH, ACGIH STEL
XYLENE 1330-20-7 4-6 100 ppm OSHA, NIOSH, ACGIH
TWA
150 ppm NIOSH, ACGIH STEL
1-METHOXY PROPYLACETATE-2 108-65-6 2-3 OSHA PEL: NI ACGIH TLVs: NI
Other Exposure Limits (ppm): 50
(MAK)
CYCLOHEXANONE 108-94-1 3-4 OSHA TWA: 50ppm; ACGIH TWA:
25ppm
50ppm NIOSH, ACGIH STEL
ACRYLATED OLIGOMER AND Trade Secret < 45 Not established.
MONOMER BLEND* Irritant, potential sensitizer
KETONE DERIVATIVE Trade Secret <5 Not established.
Potential irritant.
Composition Comments
The exact formula of this product is a trade secret.
3 HAZARDS IDENTIFICATION
Potential Health Effects, Skin
Skin contact, especially if prolonged, may cause irritation, rash or chemical burn to the contacted area. Effects of exposure
may be delayed 24 to 48 hours.
Potential Health Effects, Eye
Eye contact with the liquid is expected to cause severe irritation and possibly injury to the cornea.
Potential Health Effects, Ingestion
Swallowing may cause nausea, vomiting, abdominal discomfort, or even internal injury.
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Special Toxic Effects
Prolonged or repeated exposures can cause sensitization. Irritation may be delayed, so exposure can go unnoticed. Avoid
all direct contact.
Target Organs
Skin, eyes, central nervous system.
Signs & Symptoms of Short-Term (Acute) Exposure
Dizziness, irritation of mucous membranes. May effect the liver, kidneys and central nervous system. Irritant, potential
sensitizer.
Effects of Long-Term (Chronic) Exposure
Respiratory tract irritation, depression of the central nervous system.
4 FIRST AID MEASURES
Skin
Wash area thoroughly with soap and water and rinse. Wash contaminated clothing before re-use. If irritation develops and
persists, seek medical attention.
Eye
Flush at least 15 minutes with water. Seek immediate medical assistance.
Inhalation
Remove to fresh air, restore breathing. Consult a physician for medical treatment. Treat symptomatically.
Ingestion
Do not induce vomiting. Consult physician or poison contaol center immediately.
5 FIRE FIGHTING MEASURES
Extinguishing Media
CO 2 or dry chemical.
Basic Fire Fighting Procedures
Use self-contained positive-pressure breathing apparatus and protective clothing.
Unusual Fire & Explosion Hazards
Hazardous polymerization may occur. Use streams of cooling water to avoid this if necessary.
130 - 150 潞F
Flash Point
Not established
Flammability Limits in Air, Lower, % by Volume
Not established
Flammability Limits in Air, Upper, % by Volume
6 ACCIDENTAL RELEASE MEASURES
Spill or Leak Procedure
Contain and collect spillage with non-conbustible absorbent materials, e.g., sand, earth, vermiculite, diatomaceous earth
and place in container for disposal according to local regulations. Wear appropriate protective gear.
7 HANDLING & STORAGE
Storage
Store in the dark away from excessive heat, sources of ignition, sunlight and other ultraviolet light sources. Store between
50潞 and 80潞F (10潞 and 27潞C).
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
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Eye Protection: Personal Protection Equipments (PPE)
Wear chemical splash goggles. Do not wear contact lenses while handling this material.
Skin Protection: Personal Protection Equipments (PPE)
Wear chemical resistant gloves appropriate for handling acrylates, acetates and any associated cleanup solvents. Do not
use vinyl gloves. Inspect gloves frequently for cuts or holes and discard damaged gloves. Wash hands with soap and water
after handling this product. Do not clean skin with solvents; solvents might increase skin penetration by this product, as well
as being potentially toxic themselves.
Respiratory Protection: Personal Protection Equipments (PPE)
This material should be used only with adequate ventilation. Use of local exhaust ducts, fume hoods and/or other
mechanical exhaust ventilation is recommended. Respiratory equipment is not required, unless ventilation provisions are
inadequate. NIOSH/MSHS approved respirators with organic vapor cartridges are recommended.
Heat generated by UV light sources can volatilize small amounts of monomers before the polymerization is complete.
These volatilized monomers can be irritating if ventilation is inadequate.
General
Face shields, polyethylene aprons and tyvek outer garments afford general body/clothing protection.
9 PHYSICAL & CHEMICAL PROPERTIES
Odor and Appearance
Variously colored Viscous liquid Solvent odor.
not determined
Boiling Point
1.02 - 1.25
Specific Gravity
< 27
Percent Volatile
<1
Evaporation Rate
> 1 at 20潞C
Vapor Density
Insoluble
Solubility In Water
2.7 lb./gal.
Volatile Organic
10 STABILITY & REACTIVITY
Stability/Incompatibility
Stable under normal conditions of use.
Conditions to avoid: Excessive heat, sunlight and other UV light sources.
Materials to Avoid: Polymerization catalysts, oxidizing agents and peroxides.
Hazardous Reactions/Decomposition Products
Burning may produce carbon monoxide, nitrogen oxides and other toxic fumes. Incomplete combustion would result in the
boiling off of acrylic monomers and generation of smoke. No hazardous decomposition products are expected during
normal storage and usage conditions.
Hazardous Polymerization
May occur.
Conditions to avoid: Excessive heat, sunlight and other uv light sources, polymerization catalysts, peroxides, and oxidizing
agents.
11 TOXICOLOGICAL INFORMATION
Routes of Exposure
Inhalation of vapors, direct contact with skin or eyes.
12 ECOLOGICAL INFORMATION
EcoToxicological Information
No applicable data for this section.
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13 DISPOSAL CONSIDERATIONS
Waste Disposal
Chemical incinerator or state approved waste disposal site. Comply with federal, state and local regulations.
RCRA Hazardous Waste No: D001, due to ignitability
14 TRANSPORT INFORMATION
Department of Transportation (DOT) Requirements:
General Transportation Information for Bulk Shipments
Proper Shipping Name Printing Ink
UN/NA Code 1210
Packaging Group III
Labels Required Flammable Liquid (for air transport)
15 REGULATORY INFORMATION
Federal Regulations
CERCLA:
Reportable waste quantity (RQ): Cyclohexanone - 5,000 lbs.; Butyl acetate - 5,000 lbs.; Xylene - 100 lbs.
See Section 11 for concentration of these ingredients: Cyclohexanone (3-4% by weight), Butyl acetate (20-26% by weight),
Xylene (4-6% by weight).
Title III - Clean Air Act - Hazardous Air Pollutants:
Section 112 - Cyclohexanone (SOCMI Chemical); Xylene (SOCMI Chemical, Hazardous, Organic and Volatile Air Pollutant)
Toxic Substances Control Act (TSCA) Status: All ingredients are listed.
State Regulations
California's Proposition 65: This product may contain trace amounts of chemicals known to the State of California to cause
cancer, birth defects or other reproductive harm.
Delaware Air Quality Management List: DRQ: 5000 (Butyl acetate & Xylene): DRQ: 100 (Cyclohexanone)
Florida Toxic Substance: Listed as a toxic substance by the state of Florida. (Butyl acetate, Cyclohexanone & Xylene)
Massachusetts Haz. Substance Codes: Butyl acetate (2,3,4,5,F8): Xylene (2,4,F8,F8): Cyclohexanone (2,4,6,F8)
Minnesota Haz. Substance: Codes: ANO Hazards: skin Carcinogen: No
New Jersey RTK Haz. Substance: Xylene (#2014 and DOT# 1307) New York List of Haz. Substances: RQ-Air: Butyl
acetate (5000), Xylene (1000), Cyclohexanone (5000) RQ-Land: Butyl acetate (100, Xylene (1), Cyclohexanone (1) Note:
No notes associated with any of the ingredients in this ink series.
Pennsylvania Haz. Substance code: Butyl acetate, xylene and cyclohexanone have each been assigned code "E"
Washington Air Contaminant: TWA (ppm): 150 (Butyl acetate): 100 (Xylene): 25 (Cyclohexanone)
TWA (mg): 710 (Butyl acetate), 435 (Xylene), 100 (Cyclohexanone)
STEL (ppm): 200 (Butyl acetate), 150 (Xylene)
STEL (mg): 950 (Butyl acetate), 655 (Xylene)
Skin: Cyclohexanone (Protective measures should be taken to prevent or reduce skin absorption).
Other States: Not determined
NFPA Ratings
Health Flammability Reactivity Special Hazards
HMIS Ratings
Health 2 Flammability 2 Reactivity 1 Personal Prot. Equip. C
Following ingredients of this product are listed in SARA313
SARA Listed Ingredient Name CAS Number Maximum %
XYLENE 1330-20-7 6.0
Listed on the following Regulatory List(s)
SARA 313
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16 OTHER INFORMATION
Disclaimer
To the best of our knowledge, the information contained herein is accurate. However, Trans Tech does not assume any
liability whatsoever for the accuracy or completeness of this information. Final determination of suitability of any material is
the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
6/12/2008 9/6/2005
Replaces Sheet Dated
Completed On
Completed By
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