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                                       BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 1 of 12




Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
BARIUM CHLORIDE

SYNONYMS

Ba-Cl2, "anhydrous barium chloride", "barium dichloride"

PROPER SHIPPING NAME
BARIUM COMPOUND, N.O.S.
(contains barium chloride)

PRODUCT USE
Used in the manufacture of pigments and glass; as a mordant for acid dyes, in aluminium
refining; as a pesticide; as a water softener; for tanning and finishing leather.

SUPPLIER
Company: APS Specialty Chemicals Company: Ajax Chemicals Division
AUS Telephone: +61 02 9839 4000
Company: Ecolab
Company: Chem- Supply Pty Ltd AUS Emergency Tel: 008 032114
AUS Telephone: +61 2 8440 2000
Company: Orica
Company: Merck Pty Ltd AUS Emergency Tel: +1800 033 111 (All Hours)
AUS Emergency Tel: +61 3 9728 5855

Company: Sigma- Aldrich Pty Ltd
AUS Emergency Tel: +44 8701906777


HAZARD RATINGS

Flammability
Toxicity
Body Contact
Reactivity
Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 2 of 12



Section 2 - HAZARDS IDENTIFICATION


STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC,
and the ADG Code.




POISONS SCHEDULE
S6

RISK SAFETY
Harmful by inhalation. Keep locked up.
Toxic if swallowed. Do not breathe dust.
Skin contact may produce health damage*. Wear suitable protective clothing.
Cumulative effects may result following In case of insufficient ventilation wear
exposure*. suitable respiratory equipment.
May produce discomfort of the respiratory Use only in well ventilated areas.
system*.
* (limited evidence). Keep container in a well ventilated place.
To clean the floor and all objects contaminated
by this material use water.
This material and its container must be disposed
of in a safe way.
Keep away from food drink and animal feeding
stuffs.
Take off immediately all contaminated clothing.
This material and its container must be disposed
of as hazardous waste.


Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
barium chloride 10361-37-2 >98


Section 4 - FIRST AID MEASURES


SWALLOWED
路 IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
路 For advice, contact a Poisons Information Centre or a doctor.
路 Urgent hospital treatment is likely to be needed.
路 In the mean time, qualified first-aid personnel should treat the patient following
observation and employing supportive measures as indicated by the patient's condition.
路 If the services of a medical officer or medical doctor are readily available, the
patient should be placed in his/her care and a copy of the MSDS should be provided.
Further action will be the responsibility of the medical specialist.
路 If medical attention is not available on the worksite or surroundings send the patient
to a hospital together with a copy of the MSDS.
路 Where medical attention is not immediately available or where the patient is more than
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 3 of 12
Section 4 - FIRST AID MEASURES

15 minutes from a hospital or unless instructed otherwise:
路 INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean
patient forward or place on left side (head-down position, if possible) to maintain open
airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.

EYE
If this product comes in contact with the eyes:
路 Immediately hold eyelids apart and flush the eye continuously with running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 Continue flushing until advised to stop by the Poisons Information Centre or a doctor,
or for at least 15 minutes.
路 Transport to hospital or doctor without delay.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.

SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear.
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.

INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.

NOTES TO PHYSICIAN
路 After ingestion of barium acid salts, severe gastro-intestinal irritation followed by
muscle twitching, progressive flaccid paralysis and severe hypokalemia and hypertension,
occurs.
路 Respiratory failure, renal failure and occasional cardiac dysrhythmias may result from
an acute ingestion.
路 Use sodium sulfate as a cathartic. Add 5-10 gm of sodium sulfate to lavage solution or
as fluid supplement to Ipecac syrup (the sulfate salt is not absorbed)
路 Monitor cardiac rhythm and serum potassium closely to establish the trend over the
first 24 hours. Large doses of potassium may be needed to correct the hypokalemia.
路 Administer generous amounts of fluid replacement but monitor the urine and serum for
evidence of renal failure. [Ellenhorn and Barceloux: Medical Toxicology].
Antidote- sodium sulfite solution, oral, gastric tube, potassium
[OHS]


Section 5 - FIRE FIGHTING MEASURES


EXTINGUISHING MEDIA
路 Water spray or fog.
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.

FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 4 of 12
Section 5 - FIRE FIGHTING MEASURES

路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water courses.
路 Use fire fighting procedures suitable for surrounding area.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.

FIRE/EXPLOSION HAZARD
路 Non combustible.
路 Not considered a significant fire risk, however containers may burn.
Decomposition may produce toxic fumes of: hydrogen chloride, metal oxides.
Decomposes at high temperatures to produce barium oxide. Barium oxide is strongly
alkaline and, upon contact with water, is exothermic. When barium oxide reacts with
oxygen to give a peroxide, there is a fire and explosion risk.
May emit poisonous fumes.

FIRE INCOMPATIBILITY
None known.

HAZCHEM: 2Z


Section 6 - ACCIDENTAL RELEASE MEASURES


EMERGENCY PROCEDURES

MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Use dry clean up procedures and avoid generating dust.
路 Place in a suitable labelled container for waste disposal.

MAJOR SPILLS
After clean up operations, decontaminate and launder all protective clothing and
equipment before storing and re-using.

EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing

life-threatening health effects is:
barium chloride 50 mg/m鲁

irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
barium chloride 2.5 mg/m鲁

other than mild, transient adverse effects without perceiving a clearly defined odour is:
barium chloride 1.5 mg/m鲁

The threshold concentration below which most people will experience no appreciable risk of health effects:
barium chloride 0.5 mg/m鲁

American Industrial Hygiene Association (AIHA)

Ingredients considered according to the following cutoffs
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 5 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES

Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture

Personal Protective Equipment advice is contained in Section 8 of the MSDS.


Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 DO NOT allow material to contact humans, exposed food or food utensils.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately. Launder contaminated clothing before re
-use.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.

SUITABLE CONTAINER
Glass container.
路 Lined metal can, lined metal pail/ can.
路 Plastic pail.
路 Polyliner drum.
路 Packing as recommended by manufacturer.
路 Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY
Metals and their oxides or salts may react violently with chlorine trifluoride. Chlorine
trifluoride is a hypergolic oxidiser. It ignites on contact (without external source of
heat or ignition) with recognised fuels - contact with these materials, following an
ambient or slightly elevated temperature, is often violent and may produce ignition. The
state of subdivision may affect the results.
Avoid reaction with oxidising agents.
Avoid strong acids.
Avoid reaction bromine trifluoride and 2-furan percarboxylic acid.

STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
_____________________________________________________

SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 6 of 12
Section 7 - HANDLING AND STORAGE

X X + X X +
_____________________________________________________
+: May be stored together
O: May be stored together with specific preventions
X: Must not be stored together



Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
Source Material TWA mg/m鲁
_________ _________ _____
Australia Exposure Standards barium chloride (Barium, 0.5
soluble compounds (as Ba))


EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
barium chloride 50


MATERIAL DATA
The recommended TLV-TWA is based on satisfactory results achieved while employing an
internal limit for barium nitrate at a national laboratory. It is not known what degree
of added safety this limit incorporates.
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.

PERSONAL PROTECTION
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 7 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EYE
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].

HANDS/FEET
Suitability and durability of glove type is dependent on usage. Factors such as:
路 frequency and duration of contact,
路 chemical resistance of glove material,
路 glove thickness and
路 dexterity,
are important in the selection of gloves.
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.

OTHER
路 Overalls.
路 Eyewash unit.
路 Barrier cream.
路 Skin cleansing cream.

RESPIRATOR
Protection Factor Half- Face Respirator Full- Face Respirator Powered Air Respirator
10 x ES P1 Air- line* -- PAPR- P1 -
50 x ES Air- line** P2 PAPR- P2
100 x ES - P3 -
Air- line* -
100+ x ES - Air- line** PAPR- P3

* - Negative pressure demand ** - Continuous flow.

The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.

ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear approved
respirator. Correct fit is essential to obtain adequate protection. Supplied-air type
respirator may be required in special circumstances. Correct fit is essential to ensure
adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area. Air contaminants
generated in the workplace possess varying "escape" velocities which, in turn, determine
the "capture velocities" of fresh circulating air required to effectively remove the
contaminant.


Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., evaporating 0.25- 0.5 m/s (50- 100 f/min.)
from tank (in still air).
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 8 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

aerosols, fumes from pouring operations, 0.5- 1 m/s (100- 200 f/min.)
intermittent container filling, low speed
conveyer transfers, welding, spray drift,
plating acid fumes, pickling (released at low
velocity into zone of active generation)
direct spray, spray painting in shallow booths, 1- 2.5 m/s (200- 500 f/min.)
drum filling, conveyer loading, crusher dusts,
gas discharge (active generation into zone of
rapid air motion)
grinding, abrasive blasting, tumbling, high 2.5- 10 m/s (500- 2000 f/min.)
speed wheel generated dusts (released at high
initial velocity into zone of very high rapid
air motion).


Within each range the appropriate value depends on:


Lower end of the range Upper end of the range
1: Room air currents minimal or favourable to 1: Disturbing room air currents
capture
2: Contaminants of low toxicity or of nuisance 2: Contaminants of high toxicity
value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood- local control only



Simple theory shows that air velocity falls rapidly with distance away from the opening
of a simple extraction pipe. Velocity generally decreases with the square of distance
from the extraction point (in simple cases). Therefore the air speed at the extraction
point should be adjusted, accordingly, after reference to distance from the contaminating
source. The air velocity at the extraction fan, for example, should be a minimum of 1-2
m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from
the extraction point. Other mechanical considerations, producing performance deficits
within the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or used.


Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE
Colourless crystals or white powder, odourless with bitter salty taste; mixes with water
(310 g/l).

PHYSICAL PROPERTIES
Solid.
Mixes with water.

Molecular Weight: 208.24 Boiling Range (掳C): 1560
Melting Range (掳C): 963 Specific Gravity (water=1): 3.9
Solubility in water (g/L): Miscible pH (as supplied): Not applicable
pH (1% solution): Not available. Vapour Pressure (kPa): Negligible
Volatile Component (%vol): Negligible Evaporation Rate: Not applicable
Relative Vapour Density (air=1): Not applicable. Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable
Autoignition Temp (掳C): Not available. Decomposition Temp (掳C): Not Applicable
State: Divided solid Viscosity: Not Applicable
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 9 of 12



Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.


Section 11 - TOXICOLOGICAL INFORMATION


POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED
Ingestion of soluble barium compounds may result in ulceration of the mucous membranes of
the gastrointestinal tract, tightness in the muscles of the face and neck,
gastroenteritis, vomiting, diarrhoea, muscular tremors and paralysis, anxiety, weakness,
laboured breathing, cardiac irregularity due to contractions of smooth striated and
cardiac muscles (often violent and painful), slow irregular pulse, hypertension,
convulsions and respiratory failure.
Toxic effects may result from the accidental ingestion of the material; animal
experiments indicate that ingestion of less than 40 gram may be fatal or may produce
serious damage to the health of the individual.

EYE
Although the material is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may cause transient discomfort characterised by tearing or
conjunctival redness (as with windburn). Slight abrasive damage may also result. The
material may produce foreign body irritation in certain individuals.

SKIN
Open cuts, abraded or irritated skin should not be exposed to this material.
Skin contact with the material may damage the health of the individual; systemic effects
may result following absorption.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
The material is not thought to be a skin irritant (as classified by EC Directives using
animal models). Abrasive damage however, may result from prolonged exposures. Good
hygiene practice requires that exposure be kept to a minimum and that suitable gloves be
used in an occupational setting.

INHALED
Barium fumes are respiratory irritants. Over-exposure to barium dusts and fume may result
in rhinitis, frontal headache, wheezing, laryngeal spasm, salivation and anorexia. Long
term effects include nervous disorders and adverse effects on the heart, circulatory
system and musculature. Heavy exposures may result in a benign pneumoconiosis.
Inhalation of dusts, generated by the material, during the course of normal
handling, may be harmful.
There is some evidence to suggest that the material can cause respiratory irritation in
some persons. The body's response to such irritation can cause further lung damage.

CHRONIC HEALTH EFFECTS
Barium compounds may cause high blood pressure, airway irritation and damage the liver,
spleen and bone marrow. Prolonged exposure may cause a lung inflammation and scarring.
Symptoms of this include a worsening dry cough, shortness of breath on exertion,
increased chest expansion and weakness. Stringy phlegm in the cough appears later, with
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION

more difficulty in breathing and a further loss of lung capacity. Barium sulfate does not
cause permanent scarring of the lungs.
Long term exposure to high dust concentrations may cause changes in lung function i.e.
pneumoconiosis; caused by particles less than 0.5 micron penetrating and remaining in the
lung. Prime symptom is breathlessness; lung shadows show on X-ray.
Substance accumulation, in the human body, may occur and may cause some concern following
repeated or long-term occupational exposure.

TOXICITY AND IRRITATION
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 11.4 mg/kg Nil Reported
Oral (rat) LD50: 118 mg/kg
Intravenous (Rat) LD: 20 mg/kg
Oral (Mouse) LD: 70 mg/kg
Subcutaneous (Mouse) LD: 10 mg/kg
Intravenous (Mouse) LD50: 12 mg/kg
Oral (Dog) LD: 90 mg/kg
Subcutaneous (Dog) LD: 10 mg/kg
Subcutaneous (Cat) LD: 18 mg/kg
Subcutaneous (Rat) LD50: 178 mg/kg
Intravenous (Cat) LD: 40 mg/kg
Oral (Rabbit) LD: 170 mg/kg
Subcutaneous (Rabbit) LD: 40 mg/kg
Intravenous (Rabbit) LD: 15 mg/kg
Oral (Guinea pig) LD50: 76 mg/kg
Subcutaneous (Guinea pig) LD: 55 mg/kg
Oral (Mouse) LD50: 150 mg/kg
Intraperitoneal (Mouse) LD50: 56.2 mg/kg
Oral (Rat) LD50: 397 mg/kg
None (None) None: None None



Section 12 - ECOLOGICAL INFORMATION

DO NOT discharge into sewer or waterways.
Harmful to aquatic life.


Section 13 - DISPOSAL CONSIDERATIONS

路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Management Authority for disposal.
路 Bury residue in an authorised landfill.
路 Recycle containers if possible, or dispose of in an authorised landfill.
路 Containers may still present a chemical hazard/ danger when empty.
路 Return to supplier for reuse/ recycling if possible.
Otherwise:
路 If container can not be cleaned sufficiently well to ensure that residuals do not
remain or if the container cannot be used to store the same product, then puncture
containers, to prevent re-use, and bury at an authorised landfill.
路 Where possible retain label warnings and MSDS and observe all notices pertaining to the
product.
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 11 of 12



Section 14 - TRANSPORTATION INFORMATION




Labels Required: TOXIC
HAZCHEM: 2Z

UNDG:
Dangerous Goods Class: 6.1 Subrisk: None
UN Number: 1564 Packing Group: III
Shipping Name:BARIUM COMPOUND, N.O.S.
(contains barium chloride)

Air Transport IATA:
ICAO/IATA Class: 6.1 ICAO/IATA Subrisk: None
UN/ID Number: 1564 Packing Group: III
Special provisions: A3谩A82
Shipping Name: BARIUM COMPOUND N.O.S.

Maritime Transport IMDG:
IMDG Class: 6.1 IMDG Subrisk: None
UN Number: 1564 Packing Group: III
EMS Number: F- A, S- A Special provisions: 177
Shipping Name: BARIUM COMPOUND, N.O.S.


Section 15 - REGULATORY INFORMATION


POISONS SCHEDULE: S6

REGULATIONS
barium chloride (CAS: 10361-37-2) is found on the following regulatory lists;
Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply - inorganic chemicals)
Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm (IRRIG)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Agricultural uses (Stock)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water quality
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not been established



Section 16 - OTHER INFORMATION


Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 6-Feb-2007
BARIUM CHLORIDE
Chemwatch Material Safety Data Sheet (REVIEW)
For Workplace - Small Volume Use Only. CHEMWATCH 1564-3
Issue Date: 6-Feb-2007 Version No:2
NC317TLP CD 2007/3 Page 12 of 12
Section 16 - OTHER INFORMATION

Print Date: 17-Dec-2007

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