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MSDS Material Safety Data Sheet
CAS

2008-39-1
32351-70-5
73404-32-3
7732-18-5

File Name: gardnwise_com---33253.asp
Material
Safety
Hi-Yield(R) Spot Weed Killer / Triamine
Data
Sheet
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Name: Voluntary Purchasing Groups, Inc. Box 460, Bonham, TX 75418
Emergency Telephone: (903) 583-5501 or (800) 424-9300 (Chemtrec)
For Additional Information Contact: Product Manager or Date Prepared: 01/23/00
Chemtrec
Common Name (Used on Label): Chemical Family: Herbicide mixture
Hi-Yield(R) Spot Weed Killer / Triamine
Chemical Name: Mixture Formula: Mixture
Trade Name & Synonyms: Hi-Yield(R) Spot Weed Killer / Triamine

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS

HAZARDOUS COMPONENT CAS NUMBER % (TYPICAL) TLV (UNITS) PEL (UNITS)
Dimethylamine Salt of 2, 4- 2008-39-1 0.16 10 mg/m3 10 mg/m3
Dichlorophenoxyacetic Acid [1]
Dimethylamine Salt of 2-(2-Methyl-4- 32351-70-5 0.16 Not established Not established
Chlorophenoxy) Propionic Acid
Dimethylamine Salt of 2-(2,4- 73404-32-3 0.16 Not established Not established
Dichlorophenoxy) Propionic Acid
Water 7732-18-5 99.5 Not established Not established
[1]NOTE: This is a toxic chemical and is subject to the reporting requirements of section 313 of Title III of the
Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
PEL: Permissible Exposure Limit established by the Occupational Safety and Health Administration.
TLV: Threshold Limit Value recommended by the American conference of Governmental Industrial Hygienists.

SECTION 3 - PHYSICAL DATA


BOILING POINT (掳F) SPECIFIC GRAVITY (H2O=1) VAPOR PRESSURE (mm Hg)
207 degrees F 1.01 Equivalent to VP or Water
PERCENT VOLATILE BY VOLUME (%) VAPOR DENSITY (AIR=1) EVAPORATION RATE (ethyl ether=1)
Not determined Not determined Not determined
SOLUBILITY IN WATER REACTIVITY IN WATER
Complete Will not evolve flammable or toxic gases
APPEARANCE AND ODOR
Dark amber liquid; amine odor


SECTION 4 - FIRE AND EXPLOSION DATA

FLASH POINT (掳F) FLAMMABLE LIMITS IN AIR (% by volume)
Aqueous Solution, does not flash Lower: Not determined Upper: Not determined
EXTINGUISHING MEDIA AUTO IGNITION TEMPERATURE
Dry chemical, CO2, foam, water spray (to cool) Not determined

Product Name: Hi-Yield(R) Spot Weed Killer / Triamine ID Number: Page: 1
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers will burst from stream pressure under extreme fire conditions.
SPECIAL FIRE FIGHTING PROCEDURES
Will produce noxious fumes under extreme fire conditions. Use self-contained breathing apparatus in confined areas
and in smoke. Utilize self-contained breathing apparatus will full facepiece operated in pressure demand or other
positive pressure mode.


SECTION 5 - HEALTH INFORMATION

PRIMARY ROUTES OF EXPOSURE AND TARGET ORGANS
Eye and skin contact, ingestion, inhalation
SIGNS AND SYMPTOMS OF EXPOSURE
(1) ACUTE OVEREXPOSURE
Eye contact may cause severe irritation with corneal injury. Prolonged skin exposure may cause skin irritation.
Ingestion may produce irritation of the mouth, esophagus, and stomach. Inhalation has been reported to reduce
pulmonary edema. May have neurological effects including vertigo, headache, malaise, and paresthesias. Higher
doses may produce muscle twitching, spasms, followed by profound muscle weakness, and unconsciousness.
Stiffness of the legs has been observed in severely poisoned persons.
(2) CHRONIC OVEREXPOSURE
Prolonged exposure may cause skin and eye irritation with corneal injury.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Disorders of the eyes, skin, or nervous system.
CHEMICAL/COMPONENT LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN
2,4-D, Dimethylamine
NTP IARC OSHA
YES NO YES NO YES NO
OTHER EXPOSURE LIMITS
Not determined
EMERGENCY AND FIRST AID PROCEDURES
EYE OR SKIN CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician.
Flush skin with water. Wash clothing before reuse. INGESTION: Promptly drink milk, egg whites, gelatin solution, or
large quantities of water. Seek medical attention. INHALATION: Remove to fresh air. If coughing or difficulty in
breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. If not breathing, give artificial
respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician.

SECTION 6 - REACTIVITY DATA


STABILITY CONDITIONS TO AVOID
Unstable Stable Does not apply
INCOMPATIBILITY (Materials to Avoid)
Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition will produce toxic agents.
HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID
May Occur Will Not occur Does not apply




Product Name: Hi-Yield(R) Spot Weed Killer / Triamine ID Number: Page: 2
SECTION 7 - SPILL OR LEAK PROCEDURES


STEPS TO BE TAKEN IN CASE MATERIAL IS LEAKED OR SPILLED
Contain spill. Absorb material with dry granules or sand. Place in a sealed, labeled container in a secure area for
proper disposal or reuse. Comply with all applicable governmental regulations concerning spill reporting, handling, and
disposal of waste.
WASTE DISPOSAL METHOD
Wastes are toxic. Dispose of in accordance with Federal, State, and local regulations.

SECTION 8 - PERSONAL PROTECTION INFORMATION

RESPIRATORY PROTECTION
Utilize NIOSH/MSHA approved respirator when mists are present.
VENTILATION
General or local exhaust to maintain employee exposure below the TLV/PEL, and control mists.
PROTECTIVE GLOVES
Rubber, PVC, or other impervious chemical gloves.
EYE PROTECTION
Chemical splash goggles (ANSI Z87.1 1979)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Protective coveralls and rubber splash apron as necessary to prevent skin contact.

SECTION 9 - SPECIAL PRECAUTIONS

PRECAUTIONS TO BE TAKEN IN HANDLING & STORING
Keep away from children. Do not get into eyes, skin or clothing. Do not store near fertilizers, seeds, insecticides, or
fungicides. Store in a cool, dry area.
OTHER PRECAUTIONS
Read the precautions on the product label before using or handling. Use only as directed on label. Keep out of reach
of children.

SECTION 10 - OTHER INFORMATION




The information contained within was obtained from authoritative sources and is believed to be accurate
for the manner in which the product is intended to be used. Other uses could result in ramifications which
are not included within this document.




Product Name: Hi-Yield(R) Spot Weed Killer / Triamine ID Number: Page: 3

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