LIQUID COPPER TEST KIT
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-36
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 1 of 11
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
LIQUID COPPER TEST KIT
STATEMENT OF HAZARDOUS NATURE
Not considered a hazardous substance according to OSHA 29
CFR 1910.1200.
SUPPLIER
Company: Aquarium Pharmaceuticals Incorporated Company: Aquarium Pharmaceuticals Incorporated
Address: Address:
50 East Hamilton Street PO Box 218
Chalfont Chalfont
PA, 18914 PA, 18914-0218
USA USA
Telephone: +1 215 822 8181 Telephone: +1 215 822 8181
Emergency Tel: +1800 222 1222 (US Only)
PRODUCT USE
Copper test kit.
SYNONYMS
"Solution ID# 3354", "Product 65L"
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
sodium diethyldithiocarbamate 148-18-5 <1
EDTA tetrasodium salt 64-02-8 <1
water 7732-18-5 >98
Section 3 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
None
EMERGENCY OVERVIEW
RISK
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where
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LIQUID COPPER TEST KIT
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-36
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 2 of 11
Section 3 - HAZARDS IDENTIFICATION
pre-existing organ (e.g. liver, kidney) damage is evident. Present definitions
of harmful or toxic substances are generally based on doses producing mortality
(death) rather than those producing morbidity (disease, ill-health).
Gastrointestinal tract discomfort may produce nausea and vomiting. In an
occupational setting however, unintentional ingestion is not thought to be cause
for concern.
EYE
Although the liquid is not thought to be an irritant, direct contact with the
eye may produce transient discomfort characterized by tearing or conjunctival
redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
INHALED
Not normally a hazard due to non-volatile nature of product.
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified using animal models). Nevertheless, good
hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects
adverse to the health (as classified using animal models); nevertheless exposure
by all routes should be minimized as a matter of course.
Section 4 - FIRST AID MEASURES
SWALLOWED
- Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons
Information Center or a doctor.
EYE
If this product comes in contact with eyes:
- Wash out immediately with water.
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
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Chemwatch Material Safety Data Sheet CHEMWATCH 4650-36
Issue Date: Tue 4-Oct-2005 CD 2005/3 Page 3 of 11
Section 4 - FIRST AID MEASURES
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
Flash Point (掳F): Not Applicable
Lower Explosive Limit (%): Not Applicable
Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳F): Not Applicable
EXTINGUISHING MEDIA
The product contains a substantial proportion of water, therefore there are no
restrictions on the type of extinguishing media which may be used. Choice of
extinguishing media should take into account surrounding areas.
Though the material is non-combustible, evaporation of water from the mixture,
caused by the heat of nearby fire, may produce floating layers of combustible
substances.
In such an event consider:
- foam
- dry chemical powder
- carbon dioxide.
FIRE FIGHTING
- Alert Emergency Responders and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves for fire only.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use fire fighting procedures suitable for surrounding area.
- Do not approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of
containers.
- Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
Decomposition may produce toxic fumes of, carbon dioxide (CO2), other pyrolysis
products typical of burning organic material.
FIRE INCOMPATIBILITY
None known.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapors and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
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Chemwatch Material Safety Data Sheet CHEMWATCH 4650-36
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Section 6 - ACCIDENTAL RELEASE MEASURES
- Wipe up.
- Place in a suitable labeled container for waste disposal.
MAJOR SPILLS
Minor hazard.
- Clear area of personnel.
- Alert Emergency Responders and tell them location and nature of hazard.
- Control personal contact by using protective equipment as required.
- Prevent spillage from entering drains or water ways.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labeled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
- Wash area and prevent runoff into drains or waterways.
- If contamination of drains or waterways occurs, advise emergency services.
ACUTE EXPOSURE GUIDELINE LEVELS (AEGL) (in ppm)
AEGL 1: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience notable discomfort, irritation, or certain asymptomatic nonsensory
effects. However, the effects are not disabling and are transient and
reversible upon cessation of exposure.
AEGL 2: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience irreversible or other serious, long-lasting adverse health effects
or an impaired ability to escape.
AEGL 3: The airborne concentration of a substance above which it is predicted
that the general population, including susceptible individuals, could
experience life-threatening health effects or death.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
individuals could be exposed for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
sodium diethyldithiocarbamate 500 mg/m鲁
EDTA tetrasodium salt 150 mg/m鲁
water 500 mg/m鲁
irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
sodium diethyldithiocarbamate 100 mg/m鲁
EDTA tetrasodium salt 30 mg/m鲁
water 500 mg/m鲁
other than mild, transient adverse effects
without perceiving a clearly defined odour is:
sodium diethyldithiocarbamate 6 mg/m鲁
EDTA tetrasodium salt 4 mg/m鲁
water 500 mg/m鲁
The threshold concentration below which most people.
will experience no appreciable risk of health effects:
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Chemwatch Material Safety Data Sheet CHEMWATCH 4650-36
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Section 6 - ACCIDENTAL RELEASE MEASURES
sodium diethyldithiocarbamate 2 mg/m鲁
EDTA tetrasodium salt 1.25 mg/m鲁
water 500 mg/m鲁
American Industrial Hygiene Association (AIHA)
Ingredients considered according exceed the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
RECOMMENDED STORAGE METHODS
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer
- Check all containers are clearly labeled and free from leaks.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data available: sodium diethyldithiocarbamate as (CAS: 148-18-5) / (CAS: 20624-25-3)
No data available: EDTA tetrasodium salt as (CAS: 64-02-8) / (CAS: 10378-23-1) / (CAS: 13235-36-4)
No data available: water as (CAS: 7732-18-5)
Not available. Refer to individual constituents.
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
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LIQUID COPPER TEST KIT
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-36
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :100 mg/m鲁.
INGREDIENT DATA
For each of the following
SODIUM DIETHYLDITHIOCARBAMATE:
EDTA TETRASODIUM SALT:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁.
WATER:
No exposure limits set by NOHSC or ACGIH.
PERSONAL PROTECTION
Glasses:
Chemical goggles.
Gloves:
When handling larger quantities:
General purpose rubber glove.
Respirator:
Particulate
EYE
- Safety glasses with side shields
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.
HANDS/FEET
Wear general protective gloves, e.g.. light weight rubber gloves.
OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
- Overalls.
- Barrier cream.
- Eyewash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 -1 P -
1000 50 - -1 P
5000 50 Airline* -
5000 100 - -2 P
10000 100 - -3 P
100+ Airline* *
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
Use appropriate NIOSH-certified respirator based on informed professional
judgement. In conditions where no reasonable estimate of exposure can be
made, assume the exposure is in a concentration IDLH and use NIOSH-certified
full face pressure demand SCBA with a minimum service life of 30 minutes, or
a combination full facepiece pressure demand SAR with auxiliary self-contained
air supply. Respirators provided only for escape from IDLH atmospheres shall be
NIOSH-certified for escape from the atmosphere in which they will be used.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear an approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.0
Solubility in water (g/L): Miscible pH (as supplied): 10.5-11.6
pH (1% solution): Not Available Vapor Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapor Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid
APPEARANCE
Clear colorless alkaline liquid; mixes with water.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerization will not occur.
STORAGE INCOMPATIBILITY
Avoid contamination of water, foodstuffs, feed or seed.
None known.
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LIQUID COPPER TEST KIT
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-36
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Section 11 - TOXICOLOGICAL INFORMATION
Liquid Copper Test Kit
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
SODIUM DIETHYLDITHIOCARBAMATE:
TOXICITY IRRITATION
Oral (rat) LD50: 1500mg/kg Nil Reported
Oral (rat) LD50: >1000 mg/kg
Intraperitoneal (rat) LD50: 1250 mg/kg
Oral (mouse) LD50: 1500 mg/kg
Intraperitoneal (mouse) LD50: 1032 mg/kg
Oral (rabbit) LD50: 500 mg/kg
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
EDTA TETRASODIUM SALT:
TOXICITY IRRITATION
Oral (rat) LD50: 2000-3200 mg/kg* Skin (rabbit):500 mg/24h-Moderate
Eyes (rabbit): 1.9 mg
Eyes (rabbit):100 mg/24h-Moderate
*[BASF]
WATER:
TOXICITY IRRITATION
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
Refer to data for ingredients, which follows:
SODIUM DIETHYLDITHIOCARBAMATE:
Information on the environmental impact of dithiocarbamates with respect to
persistence and bioaccumulation in different species and food chains is limited.
Available information suggests that these compounds are degraded in the presence
of moisture, oxygen, etc. to form a number of compounds, some of which are
toxicologically important.
Soil organisms are capable of metabolizing dithiocarbamates; breakdown products
appear to affect enzyme activities, respiration and nitrification at dose levels
of the order of 10 mg/kg dry soil or more.
Generally dithiocarbamates have an LC50 of less than 1 mg/l for invertebrates
(Daphnia) and between 1 and 4 mg/l for algae (Chlorella).
The acute toxicity in fish is higher. The sac fry and early fry stages of
rainbow trout have a higher sensitivity than other early life stages and
embryotoxic and teratogenic effects have been induced by certain
dithiocarbamates. Bioaccumulation, however, is low (bioconcentration factor.
EDTA TETRASODIUM SALT:
Not readily biodegradable. Harmful to aquatic organisms.
May cause long term adverse effects in the aquatic environment. [ORICA]
Toxicity to fish: LC50 (96h): >500 mg/l (Leuciscus idus)
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Section 12 - ECOLOGICAL INFORMATION
Toxicity to daphnae (acute): EC50 (48h): >100 mg/l
Toxicity to algae EC50 (72h): 10-100 mg/l
COD Value: 570 mg O2/g
BOD5-Value: 20 mg O2/g
Toxicity to bacteria: 50 mg/l Warburg test
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Instructions
All waste must be handled in accordance with local, state and federal
regulations.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult Waste Management
Authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licensed land-fill or Incineration in a licensed
apparatus (after admixture with suitable combustible material)
- Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
DOT Information
Shipping Name: None
Hazard Class: None
SubRisk: None
UN/NA Number: None
Packing Group: None
Additional Shipping Information:
International Transport Regulations:
IMO: None
Section 15 - REGULATORY INFORMATION
RISK
US Federal Regulations
A. General Product Information
In addition to Federal and State regulation, local regulations may
apply. Check with your local regulatory authorities.
B. Component Information
This material contains one or more of the following chemicals required
to be identified under SARA Section 302 (40 CFR 455 Appendix A)
SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4):
-------------------------------------------------------------------
sodium diethyldithiocarbamate (148-18-5,<1% )
CERCLA: fianl RQ is not established; statutory R Q = 1 pound (0.454
kg)
-------------------------------------------------------------------
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Section 15 - REGULATORY INFORMATION
Component TSCA
sodium diethyldithiocarbamate Y
EDTA tetrasodium salt Y
State Regulations
A. General Product Information
B. Component Information
The following components appear on one or more of the following state
hazardous substance lists.
Component CAS No CA FL MA MN NJ PA
sodium diethyldithiocarbamate 148-18-5 N N N N N N
EDTA tetrasodium salt 64-02-8 N N N N N N
Y=Yes this material appears on that state's hazardous substances list.
N=No this material does not appear on that state's hazardous substances list.
Other Regulations
A. General Product Information
All components are listed in the European Inventory of New and
Existing Chemical Substances (EINECS)
B. Component Information
CANADA
The following component(s) are identified under the Canadian
Hazardous Products Act Ingredient Disclosure List:
All of this product's components are on the Canadian Domestic
.
REGULATIONS
sodium diethyldithiocarbamate (CAS: 148-18-5) is found on the following
regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US DOE Temporary Emergency Exposure Limits (TEELs)
US Washington Dangerous waste constituents list
Canadian Ingredient Disclosure List (SOR/88-64)
US RCRA (Resource Conservation & Recovery Act) - Phase 4 LDR Rule - Universal
Treatment Standards
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
sodium diethyldithiocarbamate (CAS: 20624-25-3) is found on the following
regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US Washington Dangerous waste constituents list
Canadian Ingredient Disclosure List (SOR/88-64)
US RCRA (Resource Conservation & Recovery Act) - Phase 4 LDR Rule - Universal
Treatment Standards
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
EDTA tetrasodium salt (CAS: 64-02-8) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
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LIQUID COPPER TEST KIT
Chemwatch Material Safety Data Sheet CHEMWATCH 4650-36
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Section 15 - REGULATORY INFORMATION
US EPA High Production Volume Program Chemical List
US DOE Temporary Emergency Exposure Limits (TEELs)
US Food Additive Database
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
EDTA tetrasodium salt (CAS: 10378-23-1) is found on the following regulatory
lists
US DOE Temporary Emergency Exposure Limits (TEELs)
US California OEHHA/ARB - Acute Reference Exposure Levels and Target Organs
(RELs) - Respiratory
water (CAS: 7732-18-5) is found on the following regulatory lists
Canadian Domestic Substances List (DSL)
US Toxic Substances Control Act (TSCA)
US DOE Temporary Emergency Exposure Limits (TEELs)
US Californian Proposition 65 - Priority List for the Development of MADLs for
Chemicals Causing Reproductive Toxicity
No data available for EDTA tetrasodium salt as CAS: 13235-36-4.
Section 16 - OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but the
author makes no warranty of merchantability or any other warranty, expressed or
implied, with respect to this information. The author makes no representations
and assumes no liability for any direct, incidental or consequential damages
resulting from its use. For additional technical information please call our
toxicology department on +800 CHEMCALL.
Issue Date: Tue 4-Oct-2005
Print Date: Thu 6-Oct-2005
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