MATERIAL SAFETY DATA SHEET PAGE: 1
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
24-HOUR EMERGENCY PHONE NUMBER: 989-636-4400
Product: LUBRICANT SULLUBE
Product Code: 42836
Effective Date: 11/17/98 Date Printed: 03/03/03 MSD: 005126
The Dow Chemical Company, Midland, MI 48674
Customer Information Center: 800-258-2436
2. COMPOSITION/INFORMATION ON INGREDIENTS
Proprietary blend containing a polyoxyalkylene glycol,
a pentaerythritol ester, and other components.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
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* Green viscous liquid. Low odor. No significant immediate hazards *
* for emergency response are known. *
* *
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POTENTIAL HEALTH EFFECTS (See Section 11 for toxicological data.)
EYE: Essentially nonirritating to eyes.
SKIN: Short single exposure may cause slight skin irritation.
Prolonged or repeated exposure may cause slight skin irrita-
tion. Material may be handled at elevated temperatures; contact
with heated material may cause thermal burns. A single pro-
longed exposure is not likely to result in the material being
absorbed through skin in harmful amounts.
INGESTION: Single dose oral toxicity is considered to be low.
Small amounts swallowed incidental to normal handling
operations are not likely to cause injury; swallowing
amounts larger than that may cause injury.
INHALATION: At room temperature, vapors are minimal due to
physical properties; a single exposure is not likely to be
hazardous. If material is heated or mist is produced,
concentrations may be attained that are sufficient to cause
irritation and other effects.
SUBCHRONIC: For the major component, in animals, effects have
been reported on the following organs: kidney and liver.
(Continued on Page 2)
* or (R) Indicates a Trademark of The Dow Chemical Company
MATERIAL SAFETY DATA SHEET PAGE: 2
Product Name: LUBRICANT SULLUBE
Product Code: 42836
Effective Date: 11/17/98 Date Printed: 03/03/03 MSD: 005126
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4. FIRST AID
EYE: Flush eyes with plenty of water.
SKIN: Wash off in flowing water or shower.
INGESTION: If swallowed seek medical attention. Do not induce
vomiting unless directed to do so by medical personnel.
INHALATION: Remove to fresh air if effects occur. Consult a
physician.
NOTE TO PHYSICIAN: If burn is present, treat as any thermal
burn, after decontamination. No specific antidote. Supportive
care. Treatment based on judgment of the physician in response
to reactions of the patient.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT: 410F, 210C; 520F, 271C
METHOD USED: PMCC, COC
AUTOIGNITION TEMPERATURE: Not determined.
FLAMMABILITY LIMITS
LFL: Not determined
UFL: Not determined
HAZARDOUS COMBUSTION PRODUCTS: During a fire, smoke may contain
the original material in addition to unidentified toxic and/or
irritating compounds.
OTHER FLAMMABILITY INFORMATION: Violent steam generation or
eruption may occur upon application of direct water stream to
hot liquids. Spills of these organic liquids on hot fibrous
insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
EXTINGUISHING MEDIA: Water fog or fine spray. Carbon dioxide,
dry chemical, foam. Alcohol resistant foams (ATC type) pre-
ferred if available. General purpose synthetic foams (including
AFFF) or protein foams may function, but much less effectively.
Do not use direct water stream. May spread fire.
FIRE FIGHTING INSTRUCTIONS: Keep people away. Isolate fire area
and deny unnecessary entry. Burning liquids may be moved by
flushing with water to protect personnel and minimize pro-
(Continued on Page 3)
* or (R) Indicates a Trademark of The Dow Chemical Company
MATERIAL SAFETY DATA SHEET PAGE: 3
Product Name: LUBRICANT SULLUBE
Product Code: 42836
Effective Date: 11/17/98 Date Printed: 03/03/03 MSD: 005126
------------------------------------------------------------------------
5. FIRE FIGHTING MEASURES (CONTINUED)
perty damage. Burning liquids may be extinguished by dilution
with water. Do not use direct water stream. May spread fire.
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear positive-pressure
self-contained breathing apparatus (SCBA) and protective fire
fighting clothing (includes fire fighting helmet, coat, pants,
boots, and gloves). If protective equipment is not available or
not used, fight fire from a protected location or safe distance.
6. ACCIDENTAL RELEASE MEASURES (See Section 15 for Regulatory
Information)
PROTECT PEOPLE: Isolate area. May be a slipping hazard.
PROTECT THE ENVIRONMENT: Contain liquid to prevent contamination
of soil, surface water or ground water.
CLEANUP: Contain spill if possible.
7. HANDLING AND STORAGE
HANDLING: Product on surfaces can cause slippery conditions.
STORAGE: Keep containers tightly closed when not in use. Store
in stainless steel, polypropylene, polyethylene lined con-
tainers, Teflon, glass-lined container, aluminum, Plasite 3066
lined containers, Plasite 3070 lined containers, or 316 stain-
less steel.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Good general ventilation should be
sufficient for most conditions. Local exhaust ventilation may
be necessary for some operations.
PERSONAL PROTECTIVE EQUIPMENT
EYE/FACE PROTECTION: Use safety glasses.
SKIN PROTECTION: Use gloves impervious to this material. Use
gloves with insulation for thermal protection, when needed.
RESPIRATORY PROTECTION: For most conditions, no respiratory
protection should be needed; however, if material is heated
or sprayed, use an approved air-purifying respirator.
(Continued on Page 4)
* or (R) Indicates a Trademark of The Dow Chemical Company
MATERIAL SAFETY DATA SHEET PAGE: 4
Product Name: LUBRICANT SULLUBE
Product Code: 42836
Effective Date: 11/17/98 Date Printed: 03/03/03 MSD: 005126
------------------------------------------------------------------------
8. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONTINUED)
EXPOSURE GUIDELINES: None established.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE: Green viscous liquid.
ODOR: Low odor.
VAPOR PRESSURE: <0.01 mmHg @ 20C
VAPOR DENSITY: Not determined.
BOILING POINT: Not applicable.
SOLUBILITY IN WATER/MISCIBILITY: <1 gm/100 gm
SPECIFIC GRAVITY OR DENSITY: 0.9827 @ 25/25C
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under recommended storage conditions.
See storage section.
CONDITIONS TO AVOID: Product can oxidize at elevated tempera-
tures. Product can decompose at elevated temperatures.
INCOMPATIBILITY WITH OTHER MATERIALS: Avoid contact with
oxidizing materials. Avoid unintended contact with iso-
cyanates. The reaction of polyols and isocyanates generates
heat. Avoid contact with strong acids.
HAZARDOUS DECOMPOSITION PRODUCTS: Hazardous decomposition pro-
ducts depend upon temperature, air supply, and the presence
of other materials. Hazardous decomposition products may in-
clude and are not limited to: aldehydes, ketones, organic
acids and polymer fragments.
HAZARDOUS POLYMERIZATION: Will not occur by itself.
11. TOXICOLOGICAL INFORMATION (See Section 3 for Potential Health
Effects. For detailed toxicological data, write or call the
address or non-emergency number shown in Section 1)
ACUTE
SKIN: The LD50 for skin absorption in rabbits is greater than
2000 mg/kg. Did not cause allergic skin reaction when tested
in guinea pigs.
INGESTION: The oral LD50 for male rats is greater than 5000 mg/
kg.
(Continued on Page 5)
* or (R) Indicates a Trademark of The Dow Chemical Company
MATERIAL SAFETY DATA SHEET PAGE: 5
Product Name: LUBRICANT SULLUBE
Product Code: 42836
Effective Date: 11/17/98 Date Printed: 03/03/03 MSD: 005126
------------------------------------------------------------------------
12. ECOLOGICAL INFORMATION (For detailed Ecological data, write or call
the address or non-emergency number shown in Section 1)
ENVIRONMENTAL FATE:
MOVEMENT & PARTITIONING: No relevant information.
DEGRADATION & TRANSFORMATION: Material is ultimately
biodegradable. Reaches more than 70% mineralization in
OECD test(s) for inherent biodegradability. Biodegradation
reached in Modified Zahn-Wellens/EMPA Test (OECD Test
No. 302B) after 28 days: 86%.
ECOTOXICOLOGY: Material is moderately toxic to aquatic organisms
on an acute basis (LC50 between 1 and 10 mg/L in most sensitive
species). Acute LC50 for fathead minnow (Pimephales promelas)
is 51 ppm. Acute LC50 for water flea Daphnia pulex is 2.8 ppm.
13. DISPOSAL CONSIDERATIONS (See Section 15 for Regulatory Information)
DISPOSAL: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY
BODY OF WATER. All disposal methods must be in compliance with
all Federal, State/Provincial and local laws and regulations.
Regulations may vary in different locations. Waste character-
izations and compliance with applicable laws are the responsi-
bility solely of the waste generator. THE DOW CHEMICAL COMPANY
HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS
SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION 2
(Composition/Information On Ingredients).
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options in-
clude sending to a licensed, permitted: recycler, reclaimer,
incinerator or other thermal destruction device.
As a service to its customers, Dow can provide names of
information resources to help identify waste management
companies and other facilities which recycle, reprocess or
manage chemicals or plastics, and that manage used drums.
Telephone Dow's Customer Information Center at
800-258-2436 or 989-832-1556 for further details.
14. TRANSPORT INFORMATION
DEPARTMENT OF TRANSPORTATION (D.O.T.):
This product is not regulated by D.O.T. when shipped domestically by
(Continued on Page 6)
* or (R) Indicates a Trademark of The Dow Chemical Company
MATERIAL SAFETY DATA SHEET PAGE: 6
Product Name: LUBRICANT SULLUBE
Product Code: 42836
Effective Date: 11/17/98 Date Printed: 03/03/03 MSD: 005126
------------------------------------------------------------------------
14. TRANSPORT INFORMATION (CONTINUED)
land.
CANADIAN TDG INFORMATION:
For TDG regulatory information, if required, consult transportation
regulations, product shipping papers, or your Dow representative.
15. REGULATORY INFORMATION (Not meant to be all-inclusive--selected
regulations represented)
NOTICE: The information herein is presented in good faith and
believed to be accurate as of the effective date shown above. However,
no warranty, express or implied is given. Regulatory requirements
are subject to change and may differ from one location to another;
it is the buyer's responsibility to ensure that its activities comply
with federal, state or provincial, and local laws. The following
specific information is made for the purpose of complying with
numerous federal, state or provincial, and local laws and regulations.
See other sections for health and safety information.
U.S. REGULATIONS
=================
SARA 313 INFORMATION: To the best of our knowledge, this product
contains no chemical subject to SARA Title III Section 313 supplier
notification requirements.
SARA HAZARD CATEGORY: This product has been reviewed according to the
EPA "Hazard Categories" promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and
is considered, under applicable definitions, to meet the following
categories:
Not to have met any hazard category
TOXIC SUBSTANCES CONTROL ACT (TSCA):
All ingredients are on the TSCA inventory or are not required to be
listed on the TSCA inventory.
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(Continued on Page 7)
* or (R) Indicates a Trademark of The Dow Chemical Company
MATERIAL SAFETY DATA SHEET PAGE: 7
Product Name: LUBRICANT SULLUBE
Product Code: 42836
Effective Date: 11/17/98 Date Printed: 03/03/03 MSD: 005126
------------------------------------------------------------------------
REGULATORY INFORMATION:(CONTINUED)
STATE RIGHT-TO-KNOW: This product is not known to contain any
substances subject to the disclosure requirements of
New Jersey
Pennsylvania
OSHA HAZARD COMMUNICATION STANDARD:
This product is not a "Hazardous Chemical" as defined by the OSHA
Hazard Communication Standard, 29 CFR 1910.1200.
CANADIAN REGULATIONS
=====================
WHMIS INFORMATION: The Canadian Workplace Hazardous Materials
Information System (WHMIS) Classification for this product is:
This product is not a "Controlled Product" under WHMIS.
16. OTHER INFORMATION
REVISION INDICATOR: Revised Section 13, Disposal.
* or (R) Indicates a Trademark of The Dow Chemical Company
The Information Herein Is Given In Good Faith, But No Warranty,
Express Or Implied, Is Made. Consult The Dow Chemical Company For
Further Information.
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