Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
EMERGENCY PHONE : 1-330-329-0098
THIS MATERIAL SAFTEY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS PRODUCT MAY BE CONSIDERED TO BE A HAZARDOUS CHEMICAL UNDER THAT
STANDARD. (REFER TO THE OSHA CLASSIFICATION IN SEC I.) THIS INFORMATION IS REQUIRED TO BE DISCLOSED FOR SAFETY IN
THE WORKPLACE. THE EXPOSURE TO THE COMMUNITY, IF ANY, IS QUITE DIFFERENT
I 鈥? PRODUCT IDENTIFICATION
ACA-13125A
Product Name:
Synonyms: Water Based Heat Activated Adhesive
Chemical Family: Modified Urethane
Formula: Not applicable/Mixture
Description: Heat Activated Coating Water Based Coating
Hazard Classification: Skin, eye, and respiratory irritant
Revision No.: 1
Revision Date: 3/15/06
Akron Coating & Coatings MSDS No: None
II 鈥? COMPONENT DATA
Product Composition
CAS or Chemical Name: Waterborne Urethane
CAS Number: N/A Mixture
Percentage Range: 31-33%
Hazardous Per 29 CFR 1910.1200: No
Exposure Standards: None Established
CAS or Chemical Name: N-Methylpyrrolidone
CAS Number: 872-50-4
Percentage Range: 1-3%
Hazardous Per 29 CFR 1910.1200: Yes
Exposure Standards: 10 ppm (8 Hr. TWA) 鈥? Recommended internal exposure standard
CAS or Chemical Name: Modified phenoxy resin
CAS Number: 193621-44-2
Percentage Range: 5-6%
Hazardous Per 29 CFR 1910.1200: No
Exposure Standards: None established
CAS or Chemical Name: Propylene glycol propyl ether
CAS Number: 1569-01-3
Percentage Range: 1.0-2.0%
Hazardous Per 29 CFR 1910.1200: Yes
Exposure Standards: None Established
ACA-13125A Rev. 3 Page 1 of 9
Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
CAS or Chemical Name: Butanol
CAS Number: 71-36-3
Percentage Range: 0.8-1.6%
Hazardous Per 29 CFR 1910.1200: Yes
Exposure Standards: OSHA PEL ACGIH(TLV)
mg/m3 mg/m3
ppm ppm
TWA None None None None
CEILING 50 None 50 None
STEL None None None None
CAS or Chemical Name: Modified acrylic resin
CAS Number: N?A mixture
Percentage Range: 14-18%
Hazardous Per 29 CFR 1910.1200: No
Exposure Standards: None established
CAS or Chemical Name: Modified neoprene resin
CAS Number: N/A Mixture
Percentage Range: 10-12%
Hazardous Per 29 CFR 1910.1200: No
Exposure Standards: None established
CAS or Chemical Name: Hydrated, Amorphous Silica
CAS Number: 112926-00-8
Percentage Range: 2-3%
Hazardous Per 29 CFR 1910.1200: Yes
Exposure Standards: OSHA PEL ACGIH (TLV)
mg/m3 mg/m3
ppm ppm
TWA None 6.0 None 3.0
CEILING None None None None
STEL None 6.0 None None
III 鈥? PRECAUTIONS FOR SAFE HANDLING AND STORAGE
DO NOT TAKE INTERNALLY. AVOID CONTACT WITH SKIN, EYES, AND CLOTHING.
UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER, AVOID BREATHING MIST OR VAPOR
STORAGE CONDITIONS:
Store in a dry place in sealed containers. Close container when not in use. Do not expose to direct sunlight or area where
temperature can exceed 1400 F. Do not store below 320 F
PRODUCT STABILITY AND COMPATIBILITY:
Six months
SHELF LIFE LIMITATIONS:
IMCOMATIBLE MATERIALS FOR
Steel containers may rust
PACKGING
INCOMPATIBLE MATERIALS FOR
Strong oxidizers
STORAGE OR TRANSPORT:
ACA-13125A Rev. 3 Page 2 of 9
Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
IV 鈥? PHYSICAL DATA
Appearance: Milky White Liquid
Melting Point: Not applicable
00 C (320 F)
Freezing Point:
1000 C (2120 F )
Boiling Point:
Decomposition Temperature: No Data
Specific Gravity: Approximately 1.1
Bulk Density: Approximately 1.1 (g/cc)
pH @ 250 C: 7.5-8.5
Vapor Pressure @ 250 C: 18.268 mm Hg
Solubility in Water: Not Applicable (Product is a dispersion)
Volatiles, Percent by Volume: 65%
Evaporation Rate: < 1 (Water = 1)
Vapor Density: Similar to water
Molecular Weight: Not Applicable / Mixture
Odor: Mild Sour
Coefficient of Oil/Water Distribution: Not available
V 鈥? PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS
Personal Protection for Routine Use of Product:
Respiratory Protection: Respiratory protection not normally needed. If vapors, mists, or aerosols are
generated, wear a NIOSH approved respirator.
Ventilation: Local exhaust ventilation is recommended if vapors, mists or aerosols are
generated. Otherwise, use general exhaust ventilation.
Skin And Eye Protection: Wear impervious gloves, boots, apron and a face shield with safety glasses or
chemical goggles. A full impervious suit is recommended if exposure is
possible to large portion of body.
Other: Eye wash and safety shower should be available in the immediate work vicinity
ACA-13125A Rev. 3 Page 3 of 9
Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
VI 鈥? FIRE AND EXPLOSION HAZARD INFORMATION
Flammability Data:
Explosive: No
Flammable: No
Combustible: No
Pyrophoric: No
Flash Point: None
Autoignition Temperature: Not Applicable (aqueous dispersion)
Flammable Limits at Normal Atmospheric
Temperature and Pressure LEL 鈥? Not Applicable
(Percent Volume in Air): UEL - Not Applicable
NFPA Ratings:
Health: Not available
Flammability: Not available
Reactivity: Not available
Special Hazard Warning Not available
HMIS Rating:
Health: 1
Flammability: 0
Reactivity: 0
Extinguishing Media:
Not Applicable 鈥? Choose extinguishing media suitable for surrounding materials.
Fire Fighting Techniques and Comments:
This product would not be expected to burn unless all the water is boiled away. The remaining organic compounds may be
ignitable. Use water to cool containers exposed to fire.
USE A NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS WHEN THIS
MATERIAL IS INVOLVED IN A FIRE.
ACA-13125A Rev. 3 Page 4 of 9
Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
VII 鈥? REACTIVITY INFORMATION
Conditions Under Which This Product May Be Unstable:
Temperatures Above: Stable at temperatures below 1400 F
Mechanical Shock or Impact: Not considered sensitive
Electrical (Static) Discharge: Not considered sensitive
Hazardous Polymerization: Will not occur
Incompatible Materials: Strong oxidizers
Hazardous Decomposition: Combustion products may include oxides of carbon and nitrogen, and sulfur
Summary of Reactivity:
Explosive: No
Oxidizer: No
Pyrophoric: No
Organic Peroxide: No
Water Reactive: No
Corrosive: No
VIII 鈥? FIRST AID
Eyes:
Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical attention.
Skin:
Immediately flush with water for at least 15 minutes. Get medial attention. If clothing comes in contact with the product, the
clothing should be removed immediately and should be laundered before re-use. Components of product can be absorbed through
the skin resulting in toxic effects.
Ingestion:
Do not induce vomiting, never give anything by mouth to an unconscious person. Consult a physician.
IMMEDIATELY CONTACT AKRON COATING & ADHESIVES @ 330-329-0098
Inhalation:
Remove to fresh air immediately. If breathing has stopped, give artificial respiration and keep warm and quiet. Get medical
attention.
ACA-13125A Rev. 3 Page 5 of 9
Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
IX 鈥? TOXICOLOGY AND HEALTH INFORMATION
ROUTES OF ABSORPTION
Eye and skin contact, ingestion, inhalation
Warning Statements and Warning Properties
MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. PROLONGED OR REPEATED SKIN CONTACT MAY
CAUSE DERMATITIS. INHALATION OF HIGH CONCENTRATIONS MAY CAUSE DIZZINESS OR DROWSINESS. DO
NOT ADD NITRITES OR OTHER NITROSATING AGENTS TO THIS PRODUCT BECAUSE A NITROSAMINE MAY BE
FORMED. NITROSAMINES MAY CAUSE CANCER
Human Threshold Response Data
Odor Threshold: No Data
Irritation Threshold: No Data
Immediately Dangerous to Life or Health: The IDLH concentration has not been established for this
product.
SIGNS, SYMPTOMS AND EFFECTS OF EXPOSURE
Inhalation
Acute: If inhaled, may cause irritation to the upper respiratory tract. Any irritation would be transient
with no permanent damage expected. Inhalation of high concentrations may cause headache,
dizziness, drowsiness, and nausea.
Chronic: Prolonged or repeated inhalation of this product may cause allergic respiratory sensitization.
Skin
Acute: Skin contact may produce mild irritation consisting of transient redness. This irritant effect would
not result in permanent damage.
Chronic: Since liquid material may be absorbed through the skin, prolonged or repeated contact may result
in absorption of harmful amounts. Prolonged or repeated skin contact may cause dermatitis.
Repeated or prolonged skin contact may also cause some individuals to develop skin rash or other
skin complications due to allergic skin sensitization.
Eye
Contact with the eyes would be expected to cause irritation consisting of reversible redness, swelling, tearing, and mucous
discharge to the conjunctiva.
ACA-13125A Rev. 3 Page 6 of 9
Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
Ingestion
Acute: No data is available on the effects of acute ingestion of this product. However, ingestion may
cause gastrointestinal discomfort with any or all of the following symptoms: nausea, lethargy or
diarrhea.
Chronic: There are no known or reported effects from chronic exposure
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Skin
Skin contact may aggravate and existing dermatitis
INTERACTIONS WITH OTHER CHEMICALS WHICH ENHANCE TOXICITY
None known or reported
ANIMAL TOXICOLOGY
Inhalation LC 50: No Data. Believed to be slightly toxic
Dermal LD 50: No Data. Believed to be slightly toxic
Oral LD 50: No Data. Believed to be slightly toxic
Irritation: Skin, eye, mucous membrane, and respiratory irritant.
Acute Target organ Toxicity
May cause skin, eye, mucous membrane, and respiratory tract irritation. Inhalation of high concentrations of vapors may cause
dizziness or drowsiness.
Chronic Target Organ Toxicity
This product may cause dermatitis upon prolonged or repeated skin contact. N-methyl pyrrolidone has oral (rat) and dermal
(rabbit) LD50 values of 4200 mg/kg and 8000 mg/kg respectively.
Reproductive and Developmental Toxicity
Teratogenic effects: male and female rats exposed orally to 500 mg/kg/day in feed for 10 weeks before mating and throughout
pregnancy: fetolethality. In earlier studies, 300 mg/kg/day was a clear no effect level
Carcinogenicity
Not considered a carcinogen
Mutagenicity
Not mutagenic
Aquatic Toxicity
Not toxic to aquatic life
ACA-13125A Rev. 3 Page 7 of 9
Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
X 鈥? TRANSPORTATION INFORMATION
US DOT
PROPER SHIPPING NAME: Not Regulated for non-bulk quantites
STATUS ON SUBSTANCE LISTS:
The concentrations shown are maximum or ceiling levels (%weight) to be used for calculation for regulations.
Trade Secrets are Indicated by 鈥淭S鈥?
Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on
Threshold Planning Quantites (RQ鈥檚) in 40CFR 302.4.
Components present in this product at a level which could require reporting under the statute (40CFR 355) are:
NONE.
XI 鈥? SPILL AND LEAKAGE PROCEDURES
FOR ALL SPILL AND LEAK ACCIDENTS, CONTACT: AKRON COATING & COATINGS PHONE: 1-330-329-0098
Reportable Quantity: This product is not subject to a Reportable Quantity (RQ). RQ鈥檚 are subject change and reference
should be made to 40CFR 355 for the current requirements.
Spill Mitigation Procedures:
Air Release: Vapors may be suppressed by the use of water fog or spray. Contain all liquid for disposal.
Water Release: Notify all downstream water users of possible contamination. Divert water flow around spill if
possible and safe to do so. If unable to divert, create an overflow dam to contain material.
Continue to handle as described in land spill
Land Spill: Confine to a small area. Use absorbent to clean up. Place in appropriately marked container for
disposal.
Spill Residues:
Dispose of per guidelines under Section XII, WASTE DISPOSAL.
Personal Protection for Emergency Spill and Firefighting Situations:
USE NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS WHEN THIS
MATERIAL IS INVOLVED IN A FIRE. USE FULL PROTECTIVE CLOTHING.
XII 鈥? WASTE DISPOSAL
CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FORM THE USE OF THIS MATEIRAL.
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND
CONTAINERS. IN COMPLIANCE WITH ALL REVELANT LOCAL, STATE, AND FEDERAL LAWS AND
REFULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NON HAZARDOUS
WASTES.
ACA-13125A Rev. 3 Page 8 of 9
Akron Coating & Adhesives
MATERIAL
367 Stanton Ave.
Akron, Ohio 44301
SAFETY DATA
Phone: 330-724-4716 FAX: 330-724-5923
XIII 鈥? ADDITIONAL REGULATORY STATUS INFORMATION
TSCA 鈥? The components of this developmental product are listed on the Toxic Substances Control Act Chemical Substance
Inventory
This product contains no components that are subject to 40CFR 721.80(f), 721.90(a)(4), (b)(4) (where n=10) and 721.125 (a), (b),
(c), (i), and (k). For additional assistance contact Akron Coating & Coatings.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 鈥? PROPOSITION 65:
鈥淲ARNING: This product contains detectable amounts of a chemical (s) known to the State of California to cause cancer and/or
birth defects or other reproductive harm.鈥?
SARA 鈥? This developmental product contains a toxic chemical or chemicals subject to the reporting requirement of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40CFR 372.
CHEMICALS LISTED ARE : None
XIV 鈥? ADDITIONAL INFORMATION
THE INFORMATION PROVIDED ON THIS MSDS IS THE BEST ESTIMATE OF TECHNICALLY QUALIFIED
INDIVIDUALS BUT MAY NOT BE BASED ON DIRECT TOXICOLOGY TESTING OR EXPERIENCE IN EMERGENCY
SITUATIONS. IT MUST BE USED BY OR UNDER THE DIRECT SUPERVISION OF TECHNICALLY QUALIFIED
INDIVIDUALS (AS DEFINED IN 40CFR 710.2). CONSULT PLANT PROCEDURES IN THE EVENT OF A SPILL OR
LEAK FOR HANDLING AND ENVIRONMENTAL INFORMATION
THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE
TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR
THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING
WITH OR HANDLING THIS PRODUCT. AKRON COATING & COATINGS BELIEVES THIS INFORNMATION TO BE
RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION, BUT MAKES NO WARRANTY THAT IT IS.
ADDITIONALLY, IF THIS MSDS IS MORE THATN THREE YEARS ORL, YOU SHOULD CONTACT AKRON COATING
& COATINGS AT 330-724-4716 TO MAKE SURE THAT THIS SHEET IS CURRENT.
ACA-13125A Rev. 3 Page 9 of 9
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