Akron Coating & Adhesives MATERIAL
367 Stanton Ave.
SAFETY DATA
Akron, OH 44301
Phone: 330-724-4716 FAX: 330-724-5923
EMERGENCY PHONE : 1-330-329-0098
THIS MATERIAL SAFTEY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS PRODUCT MAY BE CONSIDERED TO BE A HAZARDOUS CHEMICAL UNDER THAT
STANDARD. (REFER TO THE OSHA CLASSIFICATION IN SEC I.) THIS INFORMATION IS REQUIRED TO BE DISCLOSED FOR SAFETY IN
THE WORKPLACE. THE EXPOSURE TO THE COMMUNITY, IF ANY, IS QUITE DIFFERENT
I 鈥? PRODUCT IDENTIFICATION
ACA-8128
Product Name:
Synonyms: Water Based Adhesive
Chemical Family: Polyurethane
Formula: Not applicable/Mixture
Description: Heat Activated Adhesive Water Based Urethane Adhesive
Hazard Classification: Skin, eye, and respiratory irritant
Revision No.: 1
Revision Date: 3/29/05
Akron Coating & Adhesives MSDS No: None
II 鈥? COMPONENT DATA
Product Composition
CAS or Chemical Name: Urethane polymer
CAS Number: Supplier proprietary
Percentage Range: Proprietary
Hazardous Per 29 CFR 1910.1200: No
Exposure Standards: None Established
CAS or Chemical Name: N-Methylpyrrolidone
CAS Number: 872-50-4
Percentage Range: 1-3% (Contained in Urethane polymer listed above)
Hazardous Per 29 CFR 1910.1200: Yes
Exposure Standards: 10 ppm (8 Hr. TWA) 鈥? Recommended internal exposure standard
CAS or Chemical Name: Ester Urethane
CAS Number: Supplier Proprietary
Percentage Range: Proprietary
Hazardous Per 29 CFR 1910.1200: No
Exposure Standards: None Established
CAS or Chemical Name: Triethylamine
CAS Number: 121-44-8
Percentage Range: 2 鈥? 4%
Hazardous Per 29 CFR 1910.1200: Yes
Exposure Standards: OSHA PEL ACGIH(TLV)
mg/m3 mg/m3
ppm ppm
TWA 25 100 1 Skin 4.1 Skin
CEILING None None None None
STEL None None 3 Skin 12.4 Skin
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Akron Coating & Adhesives MATERIAL
367 Stanton Ave.
SAFETY DATA
Akron, OH 44301
Phone: 330-724-4716 FAX: 330-724-5923
III 鈥? PRECAUTIONS FOR SAFE HANDLING AND STORAGE
DO NOT TAKE INTERNALLY. AVOID CONTACT WITH SKIN, EYES, AND CLOTHING.
UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER, AVOID BREATHING MIST OR VAPOR
STORAGE CONDITIONS:
Store in a dry place in sealed containers. Close container when not in use. Do not expose to direct sunlight or area where
temperature can exceed 1400 F. Do not store below 320 F
PRODUCT STABILITY AND COMPATIBILITY:
Six months
SHELF LIFE LIMITATIONS:
IMCOMATIBLE MATERIALS FOR
Steel containers may rust
PACKGING
INCOMPATIBLE MATERIALS FOR
Strong oxidizers, mineral acids
STORAGE OR TRANSPORT:
IV 鈥? PHYSICAL DATA
Appearance: Milky white liquid
Melting Point: Not applicable
00 C (320 F)
Freezing Point:
1000 C (2120 F )
Boiling Point:
Decomposition Temperature: No Data
Specific Gravity: Approximately 1
Bulk Density: Approximately 1 (g/cc)
pH @ 250 C: 7.5-8.5
Vapor Pressure @ 250 C: 23.756 mm Hg
Solubility in Water: Not Applicable (Product is a dispersion)
Volatiles, Percent by Volume: 20-60%
Evaporation Rate: < 1 (Water = 1)
Vapor Density: Similar to water
Molecular Weight: Not Applicable / Mixture
Odor: Amine-like
Coefficient of Oil/Water Distribution: Not available
V 鈥? PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS
Personal Protection for Routine Use of Product:
Respiratory Protection: Respiratory protection not normally needed. If vapors, mists, or aerosols are
generated, wear a NIOSH approved respirator.
Ventilation: Local exhaust ventilation is recommended if vapors, mists or aerosols are
generated. Otherwise, use general exhaust ventilation.
Skin And Eye Protection: Wear impervious gloves, boots, apron and a face shield with safety glasses or
chemical goggles. A full impervious suit is recommended if exposure is
possible to large portion of body.
Other: Eye wash and safety shower should be available in the immediate work vicinity
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Akron Coating & Adhesives MATERIAL
367 Stanton Ave.
SAFETY DATA
Akron, OH 44301
Phone: 330-724-4716 FAX: 330-724-5923
VI 鈥? FIRE AND EXPLOSION HAZARD INFORMATION
Flammability Data:
Explosive: No
Flammable: No
Combustible: No
Pyrophoric: No
Flash Point: None
Autoignition Temperature: Not Applicable (aqueous dispersion)
Flammable Limits at Normal Atmospheric
Temperature and Pressure LEL 鈥? Not Applicable
(Percent Volume in Air): UEL - Not Applicable
NEPA Ratings:
Health: Not available
Flammability: Not available
Reactivity: Not available
Special Hazard Warning Not available
HMIS Rating:
Health: 1
Flammability: 0
Reactivity: 0
Extinguishing Media:
Not Applicable 鈥? Choose extinguishing media suitable for surrounding materials.
Fire Fighting Techniques and Comments:
This product would not be expected to burn unless all the water is boiled away. The remaining organic compounds may be
ignitable. Use water to cool containers exposed to fire.
USE A NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS WHEN THIS
MATERIAL IS INVOLVED IN A FIRE.
VII 鈥? REACTIVITY INFORMATION
Conditions Under Which This Product May Be Unstable:
Temperatures Above: Stable at temperatures below 1400 F
Mechanical Shock or Impact: Not considered sensitive
Electrical (Static) Discharge: Not considered sensitive
Hazardous Polymerization: Will not occur
Incompatible Materials: Strong oxidizers, mineral acids
Hazardous Decomposition: Combustion products may include oxides of carbon and nitrogen, di-isocyanates
and hydrogen cyanide
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Akron Coating & Adhesives MATERIAL
367 Stanton Ave.
SAFETY DATA
Akron, OH 44301
Phone: 330-724-4716 FAX: 330-724-5923
Summary of Reactivity:
Explosive: No
Oxidizer: No
Pyrophoric: No
Organic Peroxide: No
Water Reactive: No
Corrosive: No
VIII 鈥? FIRST AID
Eyes:
Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical attention.
Skin:
Immediately flush with water for at least 15 minutes. Get medial attention. If clothing comes in contact with the product, the
clothing should be removed immediately and should be laundered before re-use. Components of product can be absorbed through
the skin resulting in toxic effects.
Ingestion:
IMMEDIATELY CONTACT OCEAN EMERGENCY PHONE AT 1-888-289-1911
Inhalation:
Remove to fresh air immediately. If breathing has stopped, give artificial respiration and keep warm and quiet. Get medical
attention.
IX 鈥? TOXICOLOGY AND HEALTH INFORMATION
ROUTES OF ABSORPTION
Eye and skin contact, ingestion, inhalation
Warning Statements and Warning Properties
MAY CAUSE SKIN, EYE AND RESPIRATORY IRRITATION. PROLONGED OR REPEATED SKIN CONTACT MAY
CAUSE DERMATITIS. INHALATION OF HIGH CONCENTRATIONS MAY CAUSE DIZZINESS OR DROWSINESS.
CONTAINS TRIETHYLAMINE WHICH MAY CAUSE LIVER, KIDNEY, BLOOD, HEART AND LUNG EFFECTS BASED
ON ANIMAL DATA.
Human Threshold Response Data
Odor Threshold: No Data
Irritation Threshold: No Data
Immediately Dangerous to Life or Health: The IDLH concentration has not been established for this
product. For Triethylamine: 200 ppm
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Akron Coating & Adhesives MATERIAL
367 Stanton Ave.
SAFETY DATA
Akron, OH 44301
Phone: 330-724-4716 FAX: 330-724-5923
SIGNS, SYMPTOMS AND EFFECTS OF EXPOSURE
Inhalation
Acute: If inhaled, may cause irritation to the upper respiratory tract. Any irritation would be transient
with no permanent damage expected. Inhalation of high concentrations may cause headache,
dizziness, drowsiness, and nausea.
Chronic: Prolonged or repeated inhalation of this product may cause allergic respiratory sensitization.
Skin
Acute: Skin contact may produce mild irritation consisting of transient redness. This irritant effect would
not result in permanent damage.
Chronic: Since liquid material may be absorbed through the skin, prolonged or repeated contact may result
in absorption of harmful amounts. Prolonged or repeated skin contact may cause dermatitis.
Repeated or prolonged skin contact may also cause some individuals to develop skin rash or other
skin complications due to allergic skin sensitization.
Eye
Contact with the eyes would be expected to cause irritation consisting of reversible redness, swelling, tearing, and mucous
discharge to the conjunctiva. Blurred vision may occur.
This precut contains triethylamine. Exposure to triethylamine liquid or vapor may cause corneal clouding experienced as hazy
vision which will clear upon removal from exposure and not be expected to result in permanent eye damage.
Ingestion
Acute: No data is available on the effects of acute ingestion of this product. However, ingestion may
cause gastrointestinal discomfort with any or all of the following symptoms: nausea, lethargy or
diarrhea.
Chronic: There are no known or reported effects from chronic exposure
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Skin
Skin contact may aggravate and existing dermatitis
INTERACTIONS WITH OTHER CHEMICALS WHICH ENHANCE TOXICITY
None known or reported
ANIMAL TOXICOLOGY
Inhalation LC 50: No Data. Believed to be slightly toxic
Dermal LD 50: No Data. Believed to be slightly toxic
Oral LD 50: No Data. Believed to be slightly toxic
Irritation: Skin, eye, mucous membrane, and respiratory irritant.
Acute Target organ Toxicity
May cause skin, eye, mucous membrane, and respiratory tract irritation. Inhalation of high concentrations of vapors may cause
dizziness or drowsiness.
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Akron Coating & Adhesives MATERIAL
367 Stanton Ave.
SAFETY DATA
Akron, OH 44301
Phone: 330-724-4716 FAX: 330-724-5923
Chronic Target Organ Toxicity
This product may cause dermatitis upon prolonged or repeated skin contact. Rabbits exposed for six weeks to Triethylamine, a
component of this product, via inhalation of concentrations greater than the TLV, developed lung, liver and kidney damage. In
addition, inhalation of Triethylamine produced changes in the heart tissue. Rats exposed for six months to Triethylamine, via
inhalation of concentrations lower than the TLV, developed nervous system, blood, and lung effects.
Reproductive and Developmental Toxicity
There are no known or reported effects on reproductive function or fetal development from exposure to this product. N-
Methylpyrrolidone was evaluated for its potential to induce developmental/reproductive effects via oral, dermal, and inhalation
routes of administration. Only at high maternally toxic doses was fetotoxicity observed; no other developmental or reproductive
effects were noted.
Carcinogenicity
This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP, or EPA
Mutagenicity
This product is not known or reported to be mutagenic.
Aquatic Toxicity
None known or reported for this product. Individual constituents are as follows:
N-Methylpyrrolidone 鈥?
Bluegill (Lepomis macrochirus) LC50: 832 mg/l, 220 C
Fathead Minnow (Pimephales promelas) LC50: 1072 mg/l, 220 C
Trout (Salmo gairdnerii) LC50: 3048 mg/l, 220 C
X 鈥? TRANSPORTATION INFORMATION
If this material is shipped offsite, DOT classification and other shopping classification should be described
XI 鈥? SPILL AND LEAKAGE PROCEDURES
FOR ALL SPILL AND LEAK ACCIDENTS, CONTACT: OCEAN NETWORK EMERGENCY PHONE: 1-888-289-1911
Reportable Quantity: This product is subject to a Reportable Quantity (RQ) with respect to triethylamine (5000 lbs.).
RQ鈥檚 are subject change and reference should be made to 40CFR 302.4 for the current requirements.
Spill Mitigation Procedures:
Air Release: Vapors may be suppressed by the use of water fog or spray. Contain all liquid for disposal.
Water Release: Notify all downstream water users of possible contamination. Divert water flow around spill if
possible and safe to do so. If unable to divert, create an overflow dam to contain material.
Continue to handle as described in land spill
Land Spill: Confine to a small area. Use absorbent to clean up. Place in appropriately marked container for
disposal.
Spill Residues:
Dispose of per guidelines under Section XII, WASTE DISPOSAL.
Personal Protection for Emergency Spill and Firefighting Situations:
USE NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS WHEN THIS
MATERIAL IS INVOLVED IN A FIRE. USE FULL PROTECTIVE CLOTHING.
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Akron Coating & Adhesives MATERIAL
367 Stanton Ave.
SAFETY DATA
Akron, OH 44301
Phone: 330-724-4716 FAX: 330-724-5923
XII 鈥? WASTE DISPOSAL
CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FORM THE USE OF THIS MATEIRAL.
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND
CONTAINERS. IN COMPLIANCE WITH ALL REVELANT LOCAL, STATE, AND FEDERAL LAWS AND
REFULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NON HAZARDOUS
WASTES.
XIII 鈥? ADDITIONAL REGULATORY STATUS INFORMATION
TSCA 鈥? The components of this developmental product are listed on the Toxic Substances Control Act Chemical Substance
Inventory
This product contains a component that is subject to 40CFR 721.80(f), 721.90(a)(4), (b)(4) (where n=10) and 721.125 (a), (b), (c),
(i), and (k). For additional assistance contact Akron Coating & Adhesives.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 鈥? PROPOSITION 65:
鈥淲ARNING: This product contains detectable amounts of a chemical (s) known to the State of California to cause cancer and/or
birth defects or other reproductive harm.鈥?
SARA 鈥? This developmental product contains a toxic chemical or chemicals subject to the reporting requirement of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40CFR 372.
CHEMICALS LISTED ARE : N-methylpyrrolidone and Triethylamine
XIV 鈥? ADDITIONAL INFORMATION
THE INFORMATION PROVIDED ON THIS MSDS IS THE BEST ESTIMATE OF TECHNICALLY QUALIFIED
INDIVIDUALS BUT MAY NOT BE BASED ON DIRECT TOXICOLOGY TESTING OR EXPERIENCE IN EMERGENCY
SITUATIONS. IT MUST BE USED BY OR UNDER THE DIRECT SUPERVISION OF TECHNICALLY QUALIFIED
INDIVIDUALS (AS DEFINED IN 40CFR 710.2). CONSULT PLANT PROCEDURES IN THE EVENT OF A SPILL OR
LEAK FOR HANDLING AND ENVIRONMENTAL INFORMATION
XV 鈥? MAJOR REFERENCES
Bretherick, L., Handbook of Reactive Chemical Hazards, 3rd Ed., Boston MA: Butterworths, 1985
1.
2. Registry of Toxic Effects of Chemical Substances, on-line database, 1999
3. NIOSH pocket Guide to Chemical Hazards. Washington DC: U.S. Government Printing Office, 1997
4. Lee, K. P. et al, Toxicity of N-Methyl-2-Pyrrolidone (NMP): Teratogenic Subchronic, and Two Year Inhalation Studies,
Fundamental and Applied Toxicology 9,, pp. 222-235, 1987
5. Wells, D.A. et al, Mutagenicity and Cytotoxity of N-Methyl-2-Pyrrolidone and 4-Methylamino Butanoic Acid in
Salmonella/Microsome Assay, Journal of Applied Toxicology, Vol. 8(2), 135-139, 1988
6. Becci, P.J. et al, Teratogenicity Study of N-Methylpyrrolidone After Dermal Application to Sprague-Dawley Rats,
Fundamental And Applied Toxicology 2: pp. 73-76
Sittig, Marshall, Handbook of Toxic and Hazardous Chemicals and Carcinogens, 2nd Ed. Noyes Publications, Park Ridge
7.
NJ, 1985
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Akron Coating & Adhesives MATERIAL
367 Stanton Ave.
SAFETY DATA
Akron, OH 44301
Phone: 330-724-4716 FAX: 330-724-5923
8. Zeiger, E. et al, Salmonella Mutagenicity Tests: III. Results from the Testing
9. ACGIH Documentation of the Threshold Limit Values and Biological Exposure
10. Other References are available upon request
THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE
TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR
THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING
WITH OR HANDLING THIS PRODUCT. AKRON COATING & ADHESIVES BELIEVES THIS INFORNMATION TO BE
RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION, BUT MAKES NO WARRANTY THAT IT IS.
ADDITIONALLY, IF THIS MSDS IS MORE THATN THREE YEARS ORL, YOU SHOULD CONTACT AKRON COATING
& ADHESIVES AT 330-724-4716 TO MAKE SURE THAT THIS SHEET IS CURRENT.
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