MATERIAL SAFETY DATA SHEET Product Name:
Stove Oil (3430)
SECTION 1 鈥? PRODUCT IDENTIFICATION AND USE
Stove oil 1223
Product name PIN #, UN #
None Class 3
Chemical name TDG, DOT class
Fuel oil No. 1 III
Common names Packing group
and synonyms Range Oil
Fuel Kerosene
Product use Shipping name
Combustible liquid Class B Division 3
WHMIS
classification Toxic material Class D Division 2 Subdivision B
NFPA Health 2 Health 2
Hazard codes HMIS
Flammability 2 Flammability 2
Reactivity 0 Reactivity 0
NFPA & HMIS Ratings: 0=Insignificant/No Hazard. 1=Slight Hazard. 2=Moderate Hazard. 3=High/Serious Hazard. 4=Extreme/Severe Hazard.
Irving Oil Limited, Refining Division (506) 202-2000
Supplier Phone
Box 1260, Saint John 1-800-424-9300
Emergency (Chemtrec)
New Brunswick Canada E2L 4H6 (506) 202-3000
Refinery
SECTION 2 鈥? HAZARDOUS INGREDIENTS
ACGIH-TLVs OSHA PELs NIOSH RELs LD50 LC50
Ingredients CAS# Wt (%)
(2004) (2004) (general industry) (2004) (rat, oral) (rat, 4 hours)
200 mg/m3 TWA NAv for this product
100 mg/m3 TWA ~5g/m3
Fuel oil No. 1 8008-20-6 100 >5 g/kg
name or CAS#
(total hydrocarbon vapour)
May contain:
0.5 ppm TWA 1 ppm TWA 0.1 ppm TWA
Benzene 71-43-2 Trace 0.9 g/kg 13,200 ppm
2.5 ppm STEL 5 ppm STEL 1.0 ppm STEL
May also contain:
Sulphur 7704-34-9 Trace NAv NAv NAv >0.008 g/kg NAv
Which, under certain circumstances, may result in the evolution of:
10 ppm TWA
Hydrogen sulphide (H2S) 7783-04-6 NAp 20 ppm CEILING 10 ppm CEILING NAp 444 ppm
15 ppm STEL
Stove oil is a complex mixture of hydrocarbons. Its exact composition depends on the source of the crude oil from which it was produced and the refining methods
used. Stove oil contains hundreds of individual organic chemicals. This section identifies only some of the well-known chemical constituents.
SECTION 3 鈥? PHYSICAL DATA
Liquid 0.81 @ 15藲C
Form Specific gravity
Colourless to pale yellow 4.5 (air = 1)
Colour Vapour density
Typical petroleum odour 10.5 mm Hg @ 38藲C
Odour Vapour pressure
3
0.55 mg/m NAv
Odour threshold Evaporation rate
NAp 157 to 261藲C (315 to 501藲F)
PH Boiling point
Coefficient of water/oil distribution 3.3 to >6 (Log Poct) - 47藲C (- 53藲F)
Freezing point
SECTION 4 鈥? FIRE AND EXPLOSION HAZARDS
Yes
No Conditions Easily ignited by heat, sparks or flames.
Flammability
o
38 to 72藲C (100 to 162藲F) (cc) Auto ignition temperature 210 C (410藲F)
Flash point
0.7% Upper flammable limit 5%
Lower flammable limit
Mechanical impact Not expected to be sensitive Yes
Explosion data: Sensitivity to: Static discharge
In general, do not extinguish fire unless flow can be stopped. Use carbon dioxide, dry chemical, or
Means of extinction
foam. Cool containers with flooding quantities of water until well after the fire is out.
Vapour is heavier than air. It may travel along the ground and collect in low-lying areas such as tanks,
Special precautions
basements or sewers. May travel to a source of ignition and flash back. Containers may explode when
heated.
Carbon monoxide. Nitrogen oxides. Aromatic hydrocarbons.
Hazardous combustion products
SECTION 5 鈥? REACTIVITY INFORMATION
Stable
Stability
Sources of ignition. Static discharges. High temperatures.
Conditions to avoid
Oxidizers such as peroxides, nitric acid, and perchlorates.
Incompatible substances
Carbon monoxide, nitrogen oxides. Aromatic hydrocarbons. H2S and sulphur dioxide
Hazardous decomposition products
(SO2) may be produced from minor amounts of sulphur in the product.
The information contained in this form is based on data from sources considered to be reliable but Irving Oil Limited does not guarantee the accuracy or completeness thereof. The
information is provided as a service to the persons purchasing or using the material to which it refers and Irving Oil Limited expressly disclaims all liability for loss or damage including
consequential loss or for injury to persons including death. The information shall not be reproduced, published or distributed in any manner without prior consent in writing of Irving Oil
Limited
Page 1 of 3
MATERIAL SAFETY DATA SHEET Product Name:
Stove Oil (3430)
SECTION 6 鈥? HEALTH HAZARD INFORMATION
Route of Entry Eye Hazardous Contact Eye
Skin absorption Stove oil itself, as well as some components Skin contact
Inhalation
Ingestion
Headache and other symptoms of central nervous system (CNS) depression, such as nausea and
Acute exposure
dizziness, as well as burning sensation in chest following inhalation. Aspiration into the lungs can cause
severe pneumonitis (serious lung irritation), chest pain, and/or pulmonary edema (swelling). Ingestion may
produce nausea, vomiting, and cramping.
Note: H2S may offgas from the product in confined spaces such as the headspace in tanks, even though the
concentration of sulphur in the product is minimal. H2S is very toxic. At concentrations as low as 1 to 5 ppm,
nausea and severe eye irritation may occur. Sense of smell may be impaired at about 20 ppm, with
headache and respiratory tract lung irritation. At 250 to 500 ppm, potentially fatal pulmonary edema (fluid
in the lungs) may occur. Dizziness, sudden (often fatal) collapse, unconsciousness, and death occur at
higher concentrations. Pulmonary edema may be delayed as long as 48 hours.
Chronic exposure Dermatitis. Possibly blood and nervous system disorders. Fatigue, and severe nervous and respiratory
system symptoms may follow survival of H2S poisoning.
Not classified by EPA, IARC, NTP, or OSHA. ACGIH classifies Mutagenicity Not known to be mutagenic
Carcinogenicity
this product as an 鈥渁nimal carcinogen with unknown relevance Sensitization NAv
for humans鈥?. Benzene is a recognized carcinogen. Irritancy Skin, eye
Exposure to fuel oils during refining is considered 鈥減robably Teratogenicit
NAv
y
carcinogenic to humans鈥?.
Reproductive
Nav
toxicity
Other CNS depressants are expected to produce additive or synergistic effects. May increase the
Toxicologically
synergistic products photosensitizing ability of certain chemicals, such as dinitrochlorobenzene (DNCB).
SECTION 7 鈥? FIRST AID
Move victim to fresh air Give artificial respiration if breathing has stopped and if a qualified AR administrator is
Inhalation
available. Apply CPR if both pulse and breathing have stopped. Obtain medical attention immediately.
Never give anything by mouth if the person is unconscious, rapidly losing consciousness, or convulsing. If the
Ingestion
person is conscious, have them drink 8 to 10 ounces of water or milk to dilute the material in the stomach. Do
not induce vomiting. If vomiting occurs spontaneously, have the person lean forward to avoid aspiration. Obtain
medical attention immediately.
If irritation occurs, flush eye with lukewarm, gently flowing fresh water for at least 10 minutes.
Eye
Quickly and gently blot away excess chemical. Gently remove contaminated clothing and shoes under running
Skin
water. Wash gently and thoroughly with water and non-abrasive soap. Obtain medical assistance.
SECTION 8 鈥? PRECAUTIONARY MEASURES
Do not attempt rescue of an H2S knockdown victim without the use of proper respiratory protective equipment.
Gloves Nitrile, Viton鈩?, polyethylene preferred.
Personal
protective Eye Chemical safety goggles or face shield, as a good general safety practice.
equipment Respiratory NIOSH-approved. SCBA or air line respirator with escape cylinder for confined spaces or work with
sulphur-containing product. A qualified occupational health and safety professional should advise
on respirator selection. If an air-purifying respirator is appropriate, use one with a P series filter and
organic vapour cartridges.
Clothing & Coveralls to prevent skin contact with product. If clothing or footwear becomes contaminated with
footwear product, completely decontaminate it before re-use, or discard it.
The information contained in this form is based on data from sources considered to be reliable but Irving Oil Limited does not guarantee the accuracy or completeness thereof. The
information is provided as a service to the persons purchasing or using the material to which it refers and Irving Oil Limited expressly disclaims all liability for loss or damage including
consequential loss or for injury to persons including death. The information shall not be reproduced, published or distributed in any manner without prior consent in writing of Irving Oil
Limited
Page 2 of 3
MATERIAL SAFETY DATA SHEET Product Name:
Stove Oil (3430)
Enclose processes. Avoid generating mists. Use local exhaust ventilation to remove vapour at its site of
Engineering
controls generation. Handle laboratory samples in a fume hood. Use mechanical ventilation in confined spaces.
Keep containers closed. Keep work area free of ignition sources. Use non-sparking equipment, explosion-
Handling
procedures & proof ventilation, and intrinsically safe electrical equipment. Ground handling equipment. Have clean
equipment emergency eyewash and shower readily available in the work area.
Keep unauthorized persons away. Eliminate all sources of ignition. Ventilate area. Stop leak if it can be done
Leak & spill
Procedure safely. Prevent entry into sewers, waterways, or confined spaces. Absorb or cover with dry earth, sand or
other non-combustible material and use clean, non-sparking tools to transfer to container.
Waste disposal Consult local authorities for advice.
Cool, dry, well-ventilated area. No ignition sources. Containers should be vented and equipped with a flame
Storage
arrester.
Stable during transport. May be transported hot.
Shipping
SECTION 9 鈥? PREPARATION DATE OF MSDS
Irving Oil Limited, Refining Division (506) 202-3000
Prepared by Phone
June 1, 2006 (506) 202-2000
Revision date To re-order MSDS, phone
The information contained in this form is based on data from sources considered to be reliable but Irving Oil Limited does not guarantee the accuracy or completeness thereof. The
information is provided as a service to the persons purchasing or using the material to which it refers and Irving Oil Limited expressly disclaims all liability for loss or damage including
consequential loss or for injury to persons including death. The information shall not be reproduced, published or distributed in any manner without prior consent in writing of Irving Oil
Limited
Page 3 of 3
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