ZEP Inc.
11627 178th Street
Material Safety Data Sheet
Edmonton, Alberta T5S 1N6
1-800-I-877-I-BUY-ZEP (428-9937)
www.zep.com
Section 1. Chemical Product and Company Identification
Product name TIRELESS SHINE AEROSOL
Aerosol Cleaner.
Product use
Product code 0063
Date of issue Supersedes 02/14/05
02/11/08
Emergency Telephone Numbers
For MSDS Information:
Technical Services Group
Telephone (780) 453-8100
(Business Hours 8:00am - 5:00pm)
For Medical or Transportation Emergency
CANUTEC (24 Hours)
(613) 996-6666 - Call Collect
Prepared By
Technical Services Group
Printing date: 19/02/08
11627 178th Street
Edmonton, Alberta T5S 1N6
Section 2. Hazards Identification
Emergency overview
EXTREMELY FLAMMABLE.
Flammable aerosol. Do not breathe vapor or mist. Avoid contact with skin and clothing.
Contains material that may cause target organ damage, based on animal data.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all
prescribed safety precautions, including the use of proper personal protective equipment.
Dermal contact. Inhalation. Eye contact
Acute Effects Routes of Entry
Irritating to eyes. Inflammation of the eye is characterized by redness, watering and itching.
Eyes
Irritating to skin. permeator Direct contact may cause irritation and redness. Skin inflammation is
Skin
characterized by itching, scaling, or reddening. Prolonged or repeated contact may dry skin and
cause irritation.
Inhalation Irritating to respiratory system. Over-exposure by inhalation may cause respiratory irritation. Can
cause central nervous system (CNS) depression. Symptoms and signs include headache,
dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness.
Ingestion Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.
Vomiting increases risk of chemical pneumonia or pulmonary edema caused by aspiration of
hydrocarbon solvents.
Contains material which may cause damage to the following organs: kidneys, liver, heart, brain,
Chronic effects
central nervous system (CNS).
Prolonged skin contact may cause dermatitis with drying and cracking of skin.
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
Name of Hazardous Ingredients CAS number % by Weight
Proprietary 60 - 100
PROPRIETARY SOLVENT BLEND
69
HEPTANE; n-heptane
124-38-9 1-5
CARBON DIOXIDE
1
PETROLEUM SPIRITS; vm&p naphtha; refined solvent naphtha
1
ISOPROPYL ALCOHOL; ipa; dimethylcarbinol; 2-propanol
Section 4. First Aid Measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
Eye Contact
remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately.
Wash affected area with soap or mild detergent and water. Remove contaminated clothing and shoes. If irritation
Skin Contact
persists, get medical attention.
If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Inhalation
Page: 1/4
Product Name TIRELESS SHINE AEROSOL
Material Safety Data Sheet
Product code 0063
Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting unless directed to do
Ingestion
so by medical personnel. If vomiting occurs, keep head lower than hips to help prevent aspiration. Never give
anything by mouth to an unconscious person. Get medical attention immediately.
Section 5. Fire Fighting Measures
Closed cup: <-18掳C (<0掳F)
Flash Point
(Tagliabue.)
Flammable Limits Lower: 1.2%
Upper: 6.7%
Extremely flammable. (CSMA) Aerosol that may
Flammability
flash back.
Auto-ignition Temperature
Fire-fighters should wear appropriate protective equipment and self-contained breathing
Fire-Fighting Procedures
apparatus (SCBA) with a full face-piece operated in positive pressure mode. In case of fire, use
water spray (fog), foam, dry chemical or CO2.
Extremely flammable. Flammable aerosol. In a fire or if heated, a pressure increase will occur
Fire hazard
and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in
low or confined areas or travel a considerable distance to a source of ignition and flash back,
causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high
speed. Runoff to sewer may create fire or explosion hazard.
No specific data.
Products of Combustion
Not available.
Explosion hazard
Section 6. Accidental Release Measures
Large spills are unlikely due to packaging. Absorb with an inert material and place in an appropriate waste
Spill Clean up
disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional authority requirements.
Section 7. Handling and Storage
Store and use away from heat, sparks, open flame or any other ignition source. Avoid contact with eyes, skin and
Handling
clothing. Avoid breathing vapors, spray or mists. Use only with adequate ventilation. Wash thoroughly after handling.
CONTENTS UNDER PRESSURE. Store and use away from heat, sparks, open flame or any other ignition source. Store
Storage
below 120掳F (49掳C). Keep container tightly closed in a cool, well-ventilated place. Do not puncture or incinerate
container. Keep out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Product name Exposure limits
PROPRIETARY SOLVENT BLEND OSHA PEL (United States).
TWA: 500 ppm 8 hour(s).
ACGIH TLV (United States).
TWA: 50 ppm 8 hour(s).
Heptane ACGIH/OSHA (United States).
TWA: 400 ppm 8 hour(s).
ACGIH/OSHA (United States).
STEL: 400 ppm 15 minute(s).
Carbon Dioxide ACGIH TLV (United States).
TWA: 5000 ppm 8 hour(s).
STEL: 30000 ppm 15 minute(s).
Isopropyl Alcohol ACGIH TLV (United States).
TWA: 200 ppm 8 hour(s).
OSHA PEL (United States).
TWA: 400 ppm 8 hour(s).
ACGIH/OSHA (United States).
STEL: 400 ppm 15 minute(s).
Personal Protective Equipment (PPE)
splash goggles
Eyes
Hands and Chemical-resistant gloves.
Body
Respiratory Use with adequate ventilation. Provide exhaust ventilation or other engineering
controls to keep the airborne concentrations of vapors below their respective
occupational exposure limits. Wear appropriate respirator when ventilation is
inadequate. Approved/certified respirator with organic vapor cartridge.
Page: 2/4
Product Name TIRELESS SHINE AEROSOL
Material Safety Data Sheet
Product code 0063
Section 9. Physical and Chemical Properties
Liquid. [Aerosol.] Color Clear , Colorless.
Physical State
Not available. Odor Hydrocarbon. [Slight]
pH
143掳C (290掳F) Initial Vapor Pressure Not determined.
Boiling Point
0.73 (Water = 1) Vapor Density >1 [Air = 1]
Specific Gravity
Insoluble in the following materials: cold water. Evaporation Rate Not determined.
Solubility
VOC (Consumer) 70.9% 4.33 (lb/gal) 519 (g/l)
Freezing Point
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Reactive or incompatible with the following materials: oxidizing materials.
Incompatibility
Hazardous Polymerization Will not occur.
Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be
produced.
Section 11. Toxicological Information
Carcinogenicity No known significant effects or critical hazards.
Acute Toxicity
Product/ingredient name Result Species Dose Exposure
Proprietary Ingredient LD50 Oral Mouse 15000 mg/kg -
LC50 Inhalation Gas. Mouse 18295 ppm 2 hours
Proprietary Ingredient LC50 Inhalation Vapor Rat 3400 ppm 4 hours
Proprietary Ingredient LD50 Dermal Rabbit 13000 mg/kg -
LD50 Oral Rat 4700 mg/kg -
LC50 Inhalation Vapor Rat 22500 ppm 8 hours
LC50 Inhalation Vapor Rat 19000 ppm 8 hours
Section 12. Ecological Information
No known significant effects or critical hazards.
Environmental Effects
Aquatic Ecotoxicity
Not available.
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with applicable regulations. Consult your local or regional authorities for additional information.
Waste Stream Code: D001
Classification: - [Hazardous waste.]
Origin: - [RCRA waste.]
Section 14. Transport Information
Regulatory information UN number Proper shipping name Classes PG* Label Additional information
TDG Classification 1950 Aerosols, flammable 2.1 - Explosive Limit
and Limited
Quantity Index
2
1
-
IMDG Class
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to
the Bill of Lading with your shipment. Limited Quantity: Small quantities of controlled goods are not regulated as Dangerous
Goods according to TDG regulations.
PG* : Packing group
Page: 3/4
Product Name TIRELESS SHINE AEROSOL
Material Safety Data Sheet
Product code 0063
Section 15. Regulatory Information
Canada
Class A: Compressed gas.
WHMIS (Canada)
Class B-5: Flammable aerosol.
Class D-2B: Material causing other toxic effects (Toxic).
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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