ZEP Inc.
11627 - 178th Street
Material Safety Data Sheet
Edmonton, Alberta T5S 1N6
1-877-I-BUY-ZEP (428-9937)
and Safe Handling and Disposal Information
www.zep.com
SECTION I - PRODUCT INFORMATION
04/21/08
Issue Date
Supersedes 04/20/05
Product Name BIG ORANGE (AEROSOL)
Product No. 0114
Aerosol Solvent Degreaser
For MSDS Information:
Zep Inc.
Technical Services: (780) 453-8100
For Medical Emergency (24 Hour Service):
CANUTEC: (613) 996-6666 Call Collect
Printing date: 23/04/08 For a Transportation Emergency (24 Hour Service):
CANUTEC: (613) 996-6666 Call Collect
SECTION II - HAZARDOUS INGREDIENTS
** D-LIMONENE ** orange distillate; citrus terpene; cyclohexene, 1-methyl-4-(1-methylethenyl)-, (R)-; CAS# 5989-27-5 TLV: Not Available; % IN
PROD: 60-100
LD50: >5000 mg/kg SPECIES: RAT ROUTE: ORL
LC50: Not Available SPECIES: Not Available ROUTE: Not Available
** BLEND OF [ISOBUTANE; CAS# 75-28-5; RTECS# TZ4300000] & [PROPANE; CAS# 74-98-6; RTECS# TX2775000] & [n-BUTANE; CAS#
106-97-8; RTECS# EJ4200000] OSHA PEL-1000 ppm ** TLV: 800; % IN PROD: 10-30
LD50: Not Available SPECIES: Not Available ROUTE: Not Available
LC50: Not Available SPECIES: Not Available ROUTE: Not Available
** NONYLPHENOXYPOLY(ETHYLENEOXY)ETHANOL ** npe; poly(oxy-1,2-ethanediyl), alpha-(nonylphenyl)-omega- hydroxy; CAS# 9016-45-9;
RTECS# MD0905000; OSHA PEL_ N/D TLV: Not Available; % IN PROD: 3-7
LD50: >5000 mg/kg SPECIES: RAT ROUTE: ORL
LC50: Not Available SPECIES: Not Available ROUTE: Not Available
THE WHMIS CLASSIFICATION FOR THIS PRODUCT IS: A B5 D2B
SECTION III - TOXICOLOGICAL PROPERTIES
SPECIAL NOTE: MSDS data pertains to the product as dispensed from the container. Adverse health effects would not be expected under recommended
conditions of use so long as prescribed safety precautions are practiced.
EFFECTS OF ACUTE EXPOSURE:
This product can be an eye irritant. Inflammation of eye tissue is characterized by redness, watering, and/or itching. One of the ingredients in this product
has caused sensitization reactions in a small percentage of the general population.
EFFECTS OF CHRONIC EXPOSURE:
Contact, especially if prolonged or repeated, may cause redness, itching, or irritation of the skin. None of the ingredients are listed as carcinogens by
IARC, NTP, or OSHA.
PRIMARY ROUTES OF ENTRY: Eyes, Skin
SECTION IV - FIRST AID MEASURES
SKIN: Wash contaminated skin thoroughly with soap or a mild detergent. Apply a skin cream with lanolin. Get medical attention if irritation persists.
EYES: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting upper and lower lids. Get medical attention at once.
INHALE: If symptoms occur, move affected person to fresh air. If symptoms persist, get medical attention promptly.
INGEST: If this product is swallowed, do not induce vomiting. If individual is alert, give plenty of water to drink. Get medical attention at once.
SECTION V - PHYSICAL DATA
BOILING POINT (C) : Not Available SPECIFIC GRAVITY : 0.859
FREEZING POINT (C) : Not Available VOC CONTENT (CONCENTRATE) : 94.9%
VAPOR PRESSURE(mmHg) : 40 P.S.I. EVAPORATION RATE (Not Available = 1) : Not Available
VAPOR DENSITY(AIR-1) : Not Available pH(CONCENTRATE) : Not Available
SOLUBILITY IN WATER : COMPLETE pH(USE DILUTION OF Not Available) : Not Available
APPEARANCE AND ODOR : A CLEAR LIQUID WITH AN ORANGE FRAGRANCE.
SECTION VI - PREVENTATIVE MEASURES
Page: 1/2
Product name: BIG ORANGE (AEROSOL)
Product No. 0114 Material Safety Data Sheet
SPECIAL PROTECTION INFORMATION:
PROTECTIVE CLOTHING: Wear nitrile gloves or use gloves with demonstrated resistance to the ingredients in this product.
EYE PROTECTION: Wear tight-fitting splash-proof safety glasses especially if contact lenses are worn.
RESPIRATORY PROTECTION: Keep face away from spray mist and do not breathe vapors.
VENTILATION: Ventilation should be equal to outdoors. Use exhaust fans and/or exhaust hood in enclosed spaces.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Observe safety precautions in Section 6 during clean-up. Large spills are unlikely due to packaging. Spill may be absorbed on an inert absorbent material
(e.g. Zep-O-Zorb), and placed in a suitable container for disposal. Wash area thoroughly with a detergent solution.
WASTE DISPOSAL METHOD:
Product is consumed in use. Do not crush, puncture, or incinerate spent containers. Large numbers of aerosol containers may require handling as a
hazardous waste. Check local, provincial, and federal regulations for proper disposal methods in your area.
PRECAUTIONS TO BE TAKEN WHEN HANDLING AND STORING:
Flammable! Store and use away from heat, sparks, open flame, and any source of ignition. Do not store at temperatures above 120F (39C) or in direct
sunlight. Do not puncture or incinerate container. Keep product away from skin and eyes. Do not breathe spray mists or vapors. Clothing or shoes which
become contaminated with substance should be removed promptly and not reworn until thoroughly cleaned. Keep out of the reach of children
TRANSPORTATION DATA
TDG I.D. NUMBER: Not Available
TDG PROPER SHIPPING NAME: CONSUMER COMMODITY,
TDG HAZARD CLASS: ORM-D
TDG PACKAGING GROUP: Not Available
TDG LABEL/PLACARD:ORM-D
SECTION VII - FIRE AND EXPLOSION HAZARDS
FLASH POINT(C) (METHOD USED): EXTREMELY FLAMMABLE CSMA
FLAMMABLE LIMITS : LOWER: Not Available UPPER: Not Available
CONDITIONS OF FLAMMABILITY: Heat, sparks, and open flame
AUTOIGNITION TEMPERATURE (C) : Not Available
MEANS OF EXTINCTION: Carbon dioxide, dry chemical, water fog, foam.
FIRE FIGHTING: Wear self-contained positive pres. breathing apparatus.
FIRE HAZARD: Direct water onto intact containers to prevent bursting.
HAZARDOUS COMBUSTION PRODUCTS: Carbon dioxide, carbon monoxide, and other unidentified organic compounds.
EXPLOSION DATA: Not Available
SECTION VIII - REACTIVITY DATA
STABILITY: Stable
INCOMPATIBILITY(AVOID): Heat, flame, spark, strong acids and/or oxidizers.
REACTIVITY: Will not occur.
HAZARDOUS DECOMPOSITION: Carbon dioxide, carbon monoxide, and other unidentified organic compounds.
SECTION IX - PREPARATION INFORMATION
Prepared By: Zep Technical Services, Zep Inc., Edmonton, Alberta
For MSDS Information, telephone: (780) 453-8100
Date of Preparation : 04/21/08
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