**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 100-41-4 |Ethylbenzene | 13 | 202-849-4 |
|----------------|--------------------------------------|----------|-----------|
| 108-18-9 |Diisopropylamine | 2.8 | 203-558-5 |
|----------------|--------------------------------------|----------|-----------|
| 109-99-9 |Tetrahydrofuran | 26 | 203-726-8 |
|----------------|--------------------------------------|----------|-----------|
| 142-82-5 |n-Heptane | 29 | 205-563-8 |
|----------------|--------------------------------------|----------|-----------|
| 4111-54-0 |Lithium diisopropylamide | 21.4 | 223-893-0 |
|----------------|--------------------------------------|----------|-----------|
| 7439-95-4 |Magnesium | Balance | 231-104-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F C N
Risk Phrases: 11 19 34 50/53 65
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. May form explosive peroxides. Causes burns. Very
toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment. Harmful: may cause lung damage if
swallowed.Air sensitive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May cause liver and kidney
damage. May cause circulatory system failure. May cause central
nervous system depression, characterized by excitement, followed by
headache, dizziness, drowsiness, and nausea. Advanced stages may
cause collapse, unconsciousness, coma and possible death due to
respiratory failure. Substance poses serious aspiration hazard.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Chronic:
May cause liver and kidney damage. Adverse reproductive effects have
been reported in animals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately.
Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Water Reactive. Material will react with water and may release
a flammable and/or toxic gas. Use water spray to keep fire-exposed
containers cool. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Extremely
flammable liquid and vapor. Vapor may cause flash fire.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not expose spill to water. A vapor suppressing foam may be used to
reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Do not
get in eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Do not ingest or inhale. Do not allow contact with
water. Store and handle protected from air. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Use only with adequate ventilation.
Keep away from heat, sparks and flame.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Keep under a nitrogen blanket. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from water. Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 100-41-4:
United Kingdom, WEL - TWA: 100 ppm TWA; 441 mg/m3 TWA
United Kingdom, WEL - STEL: 125 ppm STEL; 552 mg/m3 STEL
United States OSHA: 100 ppm TWA; 435 mg/m3 TWA
Belgium - TWA: 100 ppm VLE; 442 mg/m3 VLE
Belgium - STEL: 125 ppm VLE; 551 mg/m3 VLE
France - VME: 100 ppm VME; 435 mg/m3 VME
Germany: 100 ppm TWA; 440 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 217 mg/m3 OEL
Malaysia: 100 ppm TWA; 434 mg/m3 TWA
Netherlands: 50 ppm MAC; 215 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 100 ppm VLA-ED; 441 mg/m3 VLA-ED
Spain: 200 ppm VLA-EC; 884 mg/m3 VLA-EC
CAS# 108-18-9:
United Kingdom, WEL - TWA: 5 ppm TWA; 21 mg/m3 TWA
United Kingdom, WEL - STEL: 15 ppm STEL; 63 mg/m3 STEL
United States OSHA: 5 ppm TWA; 20 mg/m3 TWA
Belgium - TWA: 5 ppm VLE; 21 mg/m3 VLE
France - VME: 5 ppm VME; 20 mg/m3 VME
Germany: 20 mg/m3 TWA
Germany: Skin absorber
Malaysia: 5 ppm TWA; 21 mg/m3 TWA
Netherlands: 5 ppm MAC; 20 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 21 mg/m3 VLA-ED
CAS# 109-99-9:
United Kingdom, WEL - TWA: 50 ppm TWA; 150 mg/m3 TWA
United Kingdom, WEL - STEL: 100 ppm STEL; 300 mg/m3 STEL
United States OSHA: 200 ppm TWA; 590 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 599 mg/m3 VLE
Belgium - STEL: 100 ppm VLE; 300 mg/m3 VLE
France - VME: 200 ppm VME; 590 mg/m3 VME
Germany: 50 ppm TWA; 150 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 590 mg/m3 OEL
Malaysia: 200 ppm TWA; 590 mg/m3 TWA
Netherlands: 100 ppm MAC; 300 mg/m3 MAC
Russia: 100 mg/m3 TWA
Spain: 50 ppm VLA-ED; 150 mg/m3 VLA-ED
Spain: 100 ppm VLA-EC; 300 mg/m3 VLA-EC
CAS# 142-82-5:
United Kingdom, WEL - TWA: 500 ppm TWA
United Kingdom, WEL - STEL: 1500 ppm STEL
United States OSHA: 500 ppm TWA; 2000 mg/m3 TWA
Belgium - TWA: 400 ppm VLE; 1664 mg/m3 VLE
Belgium - STEL: 500 ppm VLE; 2085 mg/m3 VLE
France - VME: 400 ppm VME; 1600 mg/m3 VME
Germany: 500 ppm TWA; 2100 mg/m3 TWA
Japan: 200 ppm OEL; 820 mg/m3 OEL
Malaysia: 400 ppm TWA; 1640 mg/m3 TWA
Netherlands: 400 ppm STEL; 1600 mg/m3 STEL
Netherlands: 300 ppm MAC; 1200 mg/m3 MAC
Spain: 500 ppm VLA-ED; 2085 mg/m3 VLA-ED
CAS# 4111-54-0:
CAS# 7439-95-4:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: red-orange
Odor: Pungent
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 60 - 136 deg C @ 760 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -18 deg C ( -0.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes in water
Specific Gravity/Density: .7900g/cm3
Molecular Formula: C6H14LiN
Molecular Weight: 107.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Combines vigorously with water with the
evolution of heat. May form explosive peroxides.
Conditions to Avoid:
Ignition sources, contact with water, excess heat, prolonged exposure
to air.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, alcohols.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, lithium hydroxide,
amines, oxides of magnesium, oxides of lithium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-41-4: DA0700000
CAS# 108-18-9: IM4025000
CAS# 109-99-9: LU5950000
CAS# 142-82-5: MI7700000
CAS# 4111-54-0 unlisted.
CAS# 7439-95-4: FW6475100
LD50/LC50:
CAS# 100-41-4: Draize test, rabbit, eye: 500 mg Severe; Inhalation,
mouse: LC50 = 35500 mg/m3/2H; Inhalation, rat: LC50 = 55000
mg/m3/2H; Oral, rat: LD50 = 3500 mg/kg; Oral, rat: LD50 = 3500
mg/kg; Skin, rabbit: LD50 = 17800 uL/kg.
CAS# 108-18-9: Inhalation, mouse: LC50 = 4200 mg/m3/2H; Inhalation,
rat: LC50 = 4800 mg/m3/2H; Oral, mouse: LD50 = 2120 mg/kg; Oral,
rabbit: LD50 = 4700 mg/kg; Oral, rat: LD50 = 770 mg/kg; Skin, rabbit:
LD50 = >10 gm/kg.
CAS# 109-99-9: Inhalation, rat: LC50 = 21000 ppm/3H; Oral, rat: LD50
= 1650 mg/kg.
CAS# 142-82-5: Inhalation, rat: LC50 = 103 gm/m3/4H.
CAS# 4111-54-0.
CAS# 7439-95-4.
Not available.
Carcinogenicity:
Ethylbenzene -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 6/11/04
IARC: Group 2B carcinogen
Diisopropylamine -
Not listed by ACGIH, IARC, or NTP.
Tetrahydrofuran -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
n-Heptane -
Not listed by ACGIH, IARC, or NTP.
Lithium diisopropylamide -
Not listed by ACGIH, IARC, or NTP.
Magnesium -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Cas# 100-41-4:
LC50(96Hr.) rainbow trout = 14.0 mg/L; Static
Bioassay.
LC50(96Hr.) fathead minnow= 12.1 mg/L; Flow-through
Bioassay.
LC50(96Hr.) Bluegill =- 150 mg/L; Static
Bioassay.
EC50(48Hr.)Water Flea = 2.1 mg/L; Static
Bioassay.
EC50(48Hr.)Water Flea = 2.1 mg/L; Static Bioassay.
EC50(30
min.)Photobacterium phosphoreum = 9.68 mg/L; Microtox System.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOMETALLIC COMPOUND SOLUTION, WATER-REACTIVE,
FLAMMABLE, N.O.S.*
Hazard Class: 4.3 (3)
UN Number: 3207
Packing Group: I
IMO
Shipping Name: ORGANOMETALLIC COMPOUND SOLUTION, WATER-REACTIVE,
FLAMMABLE, N.O.S.
Hazard Class: 4.3 (3)
UN Number: 3207
Packing Group: I
RID/ADR
Shipping Name: ORGANOMETALLIC COMPOUND SOLUTION, WATER-REACTIVE,
FLAMMABLE,N.O.S.
Hazard Class: 4.3
UN Number: 3207
Packing group: I
USA RQ: CAS# 100-41-4: 1000 lb final RQ; 454 kg final RQ
USA RQ: CAS# 109-99-9: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C N
Risk Phrases:
R 11 Highly flammable.
R 19 May form explosive peroxides.
R 34 Causes burns.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 100-41-4: 1
CAS# 108-18-9: 2
CAS# 109-99-9: 1
CAS# 142-82-5: 1
CAS# 4111-54-0: No information available.
CAS# 7439-95-4: No information available.
Canada
CAS# 100-41-4 is listed on Canada's DSL List.
CAS# 108-18-9 is listed on Canada's DSL List.
CAS# 109-99-9 is listed on Canada's DSL List.
CAS# 142-82-5 is listed on Canada's DSL List.
CAS# 4111-54-0 is listed on Canada's DSL List.
CAS# 7439-95-4 is listed on Canada's DSL List.
CAS# 100-41-4 is listed on Canada's Ingredient Disclosure List.
CAS# 108-18-9 is listed on Canada's Ingredient Disclosure List.
CAS# 109-99-9 is listed on Canada's Ingredient Disclosure List.
CAS# 142-82-5 is listed on Canada's Ingredient Disclosure List.
CAS# 4111-54-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 7439-95-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-41-4 is listed on the TSCA inventory.
CAS# 108-18-9 is listed on the TSCA inventory.
CAS# 109-99-9 is listed on the TSCA inventory.
CAS# 142-82-5 is listed on the TSCA inventory.
CAS# 4111-54-0 is listed on the TSCA inventory.
CAS# 7439-95-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 19 May form explosive peroxides.
R 36/37 Irritating to eyes and respiratory system.
R 38 Irritating to skin.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 6/24/1999 Revision #3 Date: 10/18/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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