**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 77-77-0 |Vinyl sulfone, 97%, stabilized with 50| | 201-057-6 |
| |0 ppm hydroquinone | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ C
Risk Phrases: 25 27 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Very toxic in contact with skin. Causes
burns.Cancer suspect agent.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. Allow the victim to rinse his mouth and then
to drink 2-4 cupfuls of water, and seek medical advice.
Inhalation:
Remove from exposure to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
Autoignition Temperature: Not available.
Flash Point: 102 deg C ( 215.60 deg F)
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Not available.
Storage:
Refrigerator (approx 4??C).
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA-approved (or equivalent)
full-facepiece airline respirator in the positive
pressure mode with emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Not available.
Appearance: clear light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: 234.3 deg C @ 760.00mmHg
Freezing/Melting Point: - 26.00 - - 0.00 deg
Decomposition Temperature: Not available.
Solubility: miscible
Specific Gravity/Density: 1.1770g/cm3
Molecular Formula: C4H6O2S
Molecular Weight: 118.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 77-77-0: KM7175000
LD50/LC50:
CAS# 77-77-0: Oral, rat: LD50 = 32 mg/kg; Skin, rabbit: LD50 = 22
mg/kg.
Carcinogenicity:
Vinyl sulfone, 97%, stabilized with 500 ppm hydroquinone -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: I
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: I
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Dangerous Goods Code: 6.1(25A)
UN Number: 2810
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ C
Risk Phrases:
R 25 Toxic if swallowed.
R 27 Very toxic in contact with skin.
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 77-77-0:
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
WHMIS: Not available.
CAS# 77-77-0 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 77-77-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/01/1994 Revision #2 Date: 9/02/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,4-Hexadien-1-Ol, 99%, Mixture of Isomers
| 111-28-4 |
|
Benzalkoniumchloride, 50 wt% Aq.Solution
| 7732-18-5 |
|
3-Bromo-1,1,1-trifluoro-2-propanol, 96% (g c)
| 88378-50-1 |
|
Glutaraldehyde sodium bisulfite addition compound, 95%
| 28959-35-5 |
|
4-Bromobenzoyl chloride, 98%
| 586-75-4 |
|
4,4'-Methylenedianiline, 99% (Titr.)
| 101-77-9 |
|
2-Methylcinnamic acid, 99%
| 2373-76-4 |
|
Platinum black, 98% Pt
| 7440-06-4 |
|
Rubidium nitrate, 99.8%
| 13126-12-0 |
|
Calcium Hypochlorite
| 7778-54-3 |
|
cis-2-Amino-1-cyclopentanecarboxylic acid hydrochloride hemihydrate
| 7664-93-9 |
|
Dichlorodiphenylmethane, 99%
| 2051-90-3 |
|
Tryptone
| |
|
2-Butene-1,4-Diol, 97% Cis
| 6117-80-2 |
|
Boric acid, 2 % w/v aqueous solution
| 7732-18-5 |
|
Molecular Sieves, 5A, Powder, Max. Grain-Size 50 Micron
| 0-00-1 |
|
Heptaldehyde, 96% (gc)
| 111-71-7 |
|
Alpha-Amylase
| 9000-90-2 |
|
Lead, 1000 ppm, standard metal solution in approx. M nitric acid
| 7439-92-1 |
|
2-Picoline, 98%
| 109-06-8 |
|
Vinyl sulfone,97% stabilized with 500 ppm hydroquinone
| 77-77-0 |
|
Potassium Chloride, saturated solution
| 7447-40-7 |
|
Potassium Chloride 3 M-4 M Solutions
| 7447-40-7 |
|
Potassium thiocyanate, 0.1N solution stabilized with 10 ppm mercuric
| 333-20-0 |
|
Sodium Thiosulfate, 0.100 N Solution
| 7732-18-5 |
|
Ethanol SDA1, Anhydrous
| 64-17-5 |
|
1-O-Octyl-beta-D-glucopyranoside
| 29836-26-8 |
|
Soap solution - Wanklyn
| 143-18-0 |
|
1-Octane sulfonic acid, sodium salt
| 5324-84-5 |
|
This is a test.
| 67-56-1 |
|
Polyurethane foam (polymer A)
| 0-00-0 |
|
Tetrabromocatechol, 96%
| 488-47-1 |
|
Alpha-Bromo-4-Nitro-O-Cresol
| 772-33-8 |
|
Trimethyl-ethoxysilane
| 7732-18-5 |
|
Diethyl citrate, tech.
| 7553-56-2 |
|
alpha-Cyano-3-hydroxycinnamic acid, 99%
| 54673-07-3 |
|
2,4,6-Triphenyl-s-triazine
| 493-77-6 |
|
Zinc Metal (Granular and Mossy)
| 7440-66-6 |
|
Magnesium Powder
| 7439-95-4 |
|
Geometric Data Fixative (BSI)
| 67-56-1 |
|
Isopropyl-dimethyl-chlorosilane
| 67-63-0 |
|
Wright Stain
| 67-56-1 |
|
Lithium diisopropylamide, 2M solution in THF/n-heptane
| 100-41-4 |
|
Gastrak 4 Molar Potassium Chloride (BSI)
| 7447-40-7 |
|
1-Acetyl-2-Phenylhydrazine, 98%
| 114-83-0 |
|
Sulfosalicylic acid 20%
| 97-05-2 |
|
Hydrochloric Acid 4N, 5N and 6N
| 7647-01-0 |
|
Hydrochloric Acid 0.01 N to 1.0N
| 7647-01-0 |
|
Hydrochloric Acid 0.1 N
| 90-43-7 |
|
Acetic acid 1N
| 64-19-7 |
|
|