**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 67-63-0 |Isopropyl alcohol | 70 % | 200-661-7 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 30 % | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury.
Skin:
Prolonged and/or repeated contact may cause defatting of the skin
and dermatitis. May cause irritation with pain and stinging,
especially if the skin is abraded.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. May cause central nervous system
depression, characterized by excitement, followed by headache,
dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory
failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by headache, dizziness, unconsciousness and
coma. Inhalation of vapor may cause respiratory tract irritation. May
cause narcotic effects.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Urine acetone test may be helpful in diagnosis.
Antidote:
None reported
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Containers may explode in the heat of a fire. This chemical
poses an explosion hazard. May form explosive peroxides. Vapors may
be heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then
place into a chemical waste container. Remove all sources of
ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid contact
with skin and eyes. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Avoid ingestion and inhalation.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a
respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: Not available.
Odor: Characteristic odor.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 2.07
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: Not available.
Molecular Weight: Not available.
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. This material may be
sensitive to peroxide formation.
Conditions to Avoid:
Ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, acetaldeyde, chlorine, ethylene oxide, acids and
isocyanates, hydrogen + palladium, nitroform, oleum, phosgene,
potassium t-butoxide, oxygen, trinitromethane, barium perchlorate,
tetrafluoroborate, chromium trioxide, sodium dichromate + sulfuric
acid, aluminum, and aluminum triisopropoxide. Isopropyl alcohol has
been reported to be susceptible to autoxidation and should therefore
be considered peroxidizable. It Refer to the NFPA manual for more
specific information.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-63-0: NT8050000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 67-63-0: Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 =
6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit: LD50 = 12800
mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Isopropyl alcohol -
IARC: Group 3 carcinogen
Water -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Not regulated as a hazardous material.
IATA
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 7732-18-5:
Canada
CAS# 67-63-0 is listed on Canada's DSL/NDSL List.
CAS# 7732-18-5 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 67-63-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 67-63-0:. OEL-AUSTRALIA:TWA 400 ppm (980 mg/m3);STEL 500 ppm (12
25 mg/m3). OEL-BELGIUM:TWA 400 ppm (985 mg/m3);STEL 500 ppm (1230 mg/m
3). OEL-DENMARK:TWA 200 ppm (490 mg/m3);Skin. OEL-FRANCE:STEL 400 ppm
(980 mg/m3). OEL-GERMANY:TWA 400 ppm (980 mg/m3). OEL-JAPAN:STEL 400 p
pm (980 mg/m3). OEL-THE NETHERLANDS:TWA 400 ppm (980 mg/m3);Skin. OEL-
THE PHILIPPINES:TWA 400 ppm (980 mg/m3). OEL-RUSSIA:STEL 400 ppm (10 m
g/m3). OEL-SWEDEN:TWA 150 ppm (350 mg/m3);STEL 250 ppm (600 mg/m3). OE
L-SWITZERLAND:TWA 400 ppm (980 mg/m3);STEL 800 ppm. OEL-TURKEY:TWA 200
ppm (500 mg/m3). OEL-UNITED KINGDOM:TWA 400 ppm (980 mg/m3);STEL 500
ppm;Skin. OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OE
L IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/04/1996 Revision #4 Date: 10/16/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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