**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6117-80-2 |CIS-2-BUTENE-1,4-DIOL | 97 | 228-085-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Get medical aid if irritation develops or persists.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with
flooding quantities of water until well after fire is out. Use water
spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Take precautionary measures
against static discharges. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store at
around 20C.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 6117-80-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: almost colorless
Odor: Odorless.
pH: Not available.
Vapor Pressure: 1.5 mbar @ 60 deg C
Viscosity: cP 25 deg C
Boiling Point: 235 deg C @ 760.00mm Hg
Freezing/Melting Point: 7 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: 165 deg C
Solubility in water: slightly soluble in benzene
Specific Gravity/Density: 1.0700g/cm3
Molecular Formula: C4H8O2
Molecular Weight: 88.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, temperatures
above 30C.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6117-80-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CIS-2-BUTENE-1,4-DIOL -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6117-80-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6117-80-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6117-80-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/22/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,4-Hexadien-1-Ol, 99%, Mixture of Isomers
| 111-28-4 |
|
Benzalkoniumchloride, 50 wt% Aq.Solution
| 7732-18-5 |
|
3-Bromo-1,1,1-trifluoro-2-propanol, 96% (g c)
| 88378-50-1 |
|
Glutaraldehyde sodium bisulfite addition compound, 95%
| 28959-35-5 |
|
4-Bromobenzoyl chloride, 98%
| 586-75-4 |
|
4,4'-Methylenedianiline, 99% (Titr.)
| 101-77-9 |
|
2-Methylcinnamic acid, 99%
| 2373-76-4 |
|
Platinum black, 98% Pt
| 7440-06-4 |
|
Rubidium nitrate, 99.8%
| 13126-12-0 |
|
Calcium Hypochlorite
| 7778-54-3 |
|
cis-2-Amino-1-cyclopentanecarboxylic acid hydrochloride hemihydrate
| 7664-93-9 |
|
Dichlorodiphenylmethane, 99%
| 2051-90-3 |
|
Tryptone
| |
|
2-Butene-1,4-Diol, 97% Cis
| 6117-80-2 |
|
Boric acid, 2 % w/v aqueous solution
| 7732-18-5 |
|
Molecular Sieves, 5A, Powder, Max. Grain-Size 50 Micron
| 0-00-1 |
|
Heptaldehyde, 96% (gc)
| 111-71-7 |
|
Alpha-Amylase
| 9000-90-2 |
|
Lead, 1000 ppm, standard metal solution in approx. M nitric acid
| 7439-92-1 |
|
2-Picoline, 98%
| 109-06-8 |
|
Vinyl sulfone,97% stabilized with 500 ppm hydroquinone
| 77-77-0 |
|
Potassium Chloride, saturated solution
| 7447-40-7 |
|
Potassium Chloride 3 M-4 M Solutions
| 7447-40-7 |
|
Potassium thiocyanate, 0.1N solution stabilized with 10 ppm mercuric
| 333-20-0 |
|
Sodium Thiosulfate, 0.100 N Solution
| 7732-18-5 |
|
Ethanol SDA1, Anhydrous
| 64-17-5 |
|
1-O-Octyl-beta-D-glucopyranoside
| 29836-26-8 |
|
Soap solution - Wanklyn
| 143-18-0 |
|
1-Octane sulfonic acid, sodium salt
| 5324-84-5 |
|
This is a test.
| 67-56-1 |
|
Polyurethane foam (polymer A)
| 0-00-0 |
|
Tetrabromocatechol, 96%
| 488-47-1 |
|
Alpha-Bromo-4-Nitro-O-Cresol
| 772-33-8 |
|
Trimethyl-ethoxysilane
| 7732-18-5 |
|
Diethyl citrate, tech.
| 7553-56-2 |
|
alpha-Cyano-3-hydroxycinnamic acid, 99%
| 54673-07-3 |
|
2,4,6-Triphenyl-s-triazine
| 493-77-6 |
|
Zinc Metal (Granular and Mossy)
| 7440-66-6 |
|
Magnesium Powder
| 7439-95-4 |
|
Geometric Data Fixative (BSI)
| 67-56-1 |
|
Isopropyl-dimethyl-chlorosilane
| 67-63-0 |
|
Wright Stain
| 67-56-1 |
|
Lithium diisopropylamide, 2M solution in THF/n-heptane
| 100-41-4 |
|
Gastrak 4 Molar Potassium Chloride (BSI)
| 7447-40-7 |
|
1-Acetyl-2-Phenylhydrazine, 98%
| 114-83-0 |
|
Sulfosalicylic acid 20%
| 97-05-2 |
|
Hydrochloric Acid 4N, 5N and 6N
| 7647-01-0 |
|
Hydrochloric Acid 0.01 N to 1.0N
| 7647-01-0 |
|
Hydrochloric Acid 0.1 N
| 90-43-7 |
|
Acetic acid 1N
| 64-19-7 |
|
|