**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7664-93-9 |Sulfuric acid | 51.0 % | 231-639-5 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 12054-85-2 |Ammonium Molybdate, tetrahydrate | < 0.1% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Water-Reactive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. May cause severe irritation of the respiratory
tract with sore throat, coughing, shortness of breath and delayed
lung edema.
Chronic:
Prolonged or repeated inhalation may cause nosebleeds, nasal
congestion, erosion of the teeth, perforation of the nasal septum,
chest pain and bronchitis. Prolonged or repeated eye contact may
cause conjunctivitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing
and shoes. SPEEDY ACTION IS CRITICAL!
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Contact with water can cause violent liberation of
heat and splattering of the material.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Use dry chemical to fight fire.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Keep container tightly closed. Do not allow
contact with water. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Keep container closed when
not in use. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134. Always use a NIOSH-approved respirator when
necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid;Sulfuric acid
Appearance: Not available.
Odor: Caustic
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: >1
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 209 - 210 deg C
Decomposition Temperature: Not available.
Solubility: soluble in water
Specific Gravity/Density: Not available.
Molecular Formula: C6H11NO2.HCl
Molecular Weight: 174.63
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, contact with water, metals, excess heat,
combustible materials, organic materials, amines, bases.
Incompatibilities with Other Materials:
Acetic anhydride, acetone cyanhydrin, acetone + nitric acid, acetone
+ potassium dichromate, acetoninitrile, acrolein, acrylonitrile,
alcohols + hydrogen peroxide, allyl alcohol, allyl chloride,
2-aminoethanol, ammonium hydroxide, ammonium triperchromate,
aniline, bromates + metals, bromine pentafluoride, n-butyraldehyde,
carbides, cesium acetylene carbide, chlorates, chlorine trifluoride,
chlorosulfonic acid, cuprous nitride, diisobutylene,
epichlorohydrin, ethylene cyanohydrin, ethylene diamine, ethylene
glycol, ethylenimine, fulminates, other acids, iodine heptafluoride,
metals, isoprene, lithium silicide, mercuric nitride, mesityl oxide,
p-nitrotoluene, pentasilver trihydroxydiaminophosphate, perchlorates,
permanganates + benzene, phosphorus, phosphorus isocyanate, picrates,
potassium t-butoxide, potassium chlorate, permanganates,
beta-propiolactone, propylene oxide, pyridine, rudibium acetylene
carbide, and sodium.
Hazardous Decomposition Products:
Oxides of sulfur.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7664-93-9: WS5600000
CAS# 7732-18-5: ZC0110000
CAS# 12054-85-2 unlisted.
LD50/LC50:
CAS# 7664-93-9: Inhalation, mouse: LC50 =320 mg/m3/2H; Inhalation,
rat: LC50 =510 mg/m3/2H; Oral, rat: LD50 = 2140 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 12054-85-2.
Carcinogenicity:
Sulfuric acid -
OSHA: Select carcinogen
IARC: Group 1 carcinogen
Water -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Ammonium Molybdate, tetrahydrate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Dangerous Goods Code: 8(39C)
UN Number: 3261
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident of if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7664-93-9: 2
CAS# 7732-18-5:
CAS# 12054-85-2: 1
Canada
CAS# 7664-93-9 is listed on Canada's DSL/NDSL List.
CAS# 7732-18-5 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 7664-93-9 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 12054-85-2 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7664-93-9:. OEL-ARAB Republic of Egypt:TWA 1 mg/m3. OEL-AUSTRALI
A:TWA 1 mg/m3. OEL-BELGIUM:TWA 1 mg/m3;STEL 3 mg/m3. OEL-CZECHOSLOVAKI
A:TWA 1 mg/m3;STEL 2 mg/m3. OEL-DENMARK:TWA 1 mg/m3. OEL-FINLAND:TWA 1
mg/m3;STEL 3 mg/m3;Skin. OEL-FRANCE:TWA 1 mg/m3;STEL 3 mg/m3. OEL-GER
MANY:TWA 1 mg/m3. OEL-HUNGARY:STEL 1 mg/m3. OEL-JAPAN:TWA 1 mg/m3
-THE NETHERLANDS:TWA 1 mg/m3. OEL-THE PHILIPPINES:TWA 1 mg/m3. OEL-POL
AND:TWA 1 mg/m3. OEL-RUSSIA:STEL 1 mg/m3;Skin. OEL-SWEDEN:TWA 1 mg/m3;
STEL 3 mg/m3. OEL-SWITZERLAND:TWA 1 mg/m3;STEL 2 mg/m3. OEL-THAILAND:T
WA 1 mg/m3. OEL-TURKEY:TWA 1 mg/m3. OEL-UNITED KINGDOM:TWA 1 mg/m3
L IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OEL IN NEW ZEA
LAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 12054-85-2 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR270.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/27/1995 Revision #2 Date: 4/05/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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