**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2037-26-5 |Toluene-d8 | | 218-009-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Vapors may cause eye irritation. May cause conjunctivitis. Causes
redness and pain.
Skin:
Causes moderate skin irritation. Prolonged and/or repeated contact
may cause defatting of the skin and dermatitis. May be absorbed
through the skin. Causes symptoms similar to those of inhalation.
Causes redness and pain.
Ingestion:
Harmful if swallowed. Aspiration hazard. May cause irritation of the
digestive tract. May cause effects similar to those for inhalation
exposure. Aspiration of material into the lungs may cause chemical
pneumonitis, which may be fatal. May cause nausea and vomiting. May
cause unconsciousness.
Inhalation:
Harmful if inhaled. Inhalation of high concentrations may cause
central nervous system effects characterized by nausea, headache,
dizziness, unconsciousness and coma. High vapor concentrations may
cause drowsiness. Inhalation of vapor may cause respiratory tract
irritation. May cause heart disturbances, possibly leading to cardiac
arrest and death. May cause narcotic effects in high concentration.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
cardiac sensitization and severe heart abnormalities. May cause liver
and kidney damage. Repeated exposure may cause central nervous system
damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Possible aspiration hazard. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Use water spray to keep
fire-exposed containers cool. Water may be ineffective. Material is
lighter than water and a fire may be spread by the use of water.
Flammable liquid and vapor.
Extinguishing Media:
Use dry chemical, carbon dioxide, or alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Scoop up with a nonsparking tool, then place into a suitable
container for disposal. Use water spray to disperse the gas/vapor.
Remove all sources of ignition. Absorb spill using an absorbent,
non-combustible material such as earth, sand, or vermiculite. Do not
use combustible materials such as sawdust. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Use spark-proof
tools and explosion proof equipment. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Take
precautionary measures against static discharges. Do not get on skin
or in eyes. Do not ingest or inhale.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2037-26-5:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 110 deg C @ 760.00mm Hg
Freezing/Melting Point: -84 deg C
Autoignition Temperature: Not available.
Flash Point: 4 deg C ( 39.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9400g/cm3
Molecular Formula: C6D5CD3
Molecular Weight: 100.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, bromine trifluoride, nitric acid, silver
perchlorate, dinitrogen tetraoxide, tetranitromethane.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Not available.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2037-26-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Toluene-d8 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Toluene CAS# 108-88-3:
Fish toxicity:
LC50 juvenile striped bass
0.0054 mg/L/96H (Palawski, D. et al Trans.Am.Fish Soc. 1985, 114,
748-753).
LC50 bluegill sunfish 24 mg/L/96H (Pickering, Q.H. et al
J.Water Pollut. Control Fed. 1966, 38, 1419-1429).
LC50 goldfish 58
mg/L/48H (Bridie, A.L. et al Water Res. 1979, 13, 623).
LC50 pink
salmon 6.41 mg/L/96H (Korr, S. et al Bull. Environ. Contam. Toxicol.
1979, 21, 521-525).
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOLUENE
Hazard Class: 3
UN Number: 1294
Packing Group: II
IMO
Shipping Name: TOLUENE
Hazard Class: 3
UN Number: 1294
Packing Group: II
RID/ADR
Shipping Name: TOLUENE
Hazard Class: 3
UN Number: 1294
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20 Harmful by inhalation.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 2037-26-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2037-26-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2037-26-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/18/1998 Revision #3 Date: 10/08/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
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| ALL MSDS PAGES IN THIS GROUP
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| 71-36-3 |
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| 108-87-2 |
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| 80-62-6 |
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| 108-88-3 |
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| 75-25-2 |
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| 149099-23-0 |
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| 1450-23-3 |
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| 106-23-0 |
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| 7732-18-5 |
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| 1777-82-8 |
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