**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 621-95-4 |4,4'-Ethylenedianiline | 95% | 210-716-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 20/21/22 40 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect. Very toxic to aquatic
organisms.The toxicological properties of this material have not been
fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Inhalation of
aniline causes anoxia due to the formation of methemoglobin.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death. May
cause cancer according to animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin,
and clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 621-95-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: light brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 136 - 138 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H16N2
Molecular Weight: 212.1254
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 621-95-4: BY0200000
LD50/LC50:
Not available.
Carcinogenicity:
4,4'-Ethylenedianiline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 621-95-4: No information available.
Canada
CAS# 621-95-4 is listed on Canada's NDSL List.
CAS# 621-95-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 621-95-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/13/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Octakis-6-Bromo-6-Deoxy-??5-Cyclodextrin
| 53784-84-2 |
|
Octakis-6-Iodo-6-Deoxy-??5-Cyclodextrin
| 168296-33-1 |
|
4-Chromanol 96%
| 1481-93-2 |
|
Octakis-6-(Dimethyl-Tert-Butylsilyl)-6-Deoxy-??5-Cyclodextrin
| 0-01-1 |
|
Diphenyl phthalate
| 84-62-8 |
|
DL-4-Chlorophenylalanine Methyl Ester Hydrochloride, 99%
| 14173-40-1 |
|
1H-Benzotriazole, 98%
| 95-14-7 |
|
m-Cresol, 95%
| 108-39-4 |
|
Thiodiglycolic Acid,98%
| 123-93-3 |
|
n-Acetyl-s-(2-hydroxyethyl)-l-cysteine
| 15060-26-1 |
|
Methyl 4-(3-Oxo-3-Phenyl-1-Propenyl) Benzoate, 98+% (NMR)
| 98258-72-1 |
|
Barium oxide
| 1304-28-5 |
|
Zinc Sulfide, Pieces, 3-12 mm, 99.9%
| 1314-98-3 |
|
Bromobenzene-d5, 99.5 atom% D
| 4165-57-5 |
|
Toluene-d8, 99.5+ atom % D
| 2037-26-5 |
|
1-Butanol-d10, packaged in ampules, 99+ atom % D
| 71-36-3 |
|
Ethylbenzene-d10, packaged in ampules, 99+ atom% D
| 25837-05-2 |
|
Mesitylene-d12, packaged in ampule, 98 atom% D
| 69441-16-3 |
|
Methylcyclohexane-d14, packaged in ampules, 99 atom % D
| 108-87-2 |
|
Methyl-d3 methacrylate-d5, stabilized
| 80-62-6 |
|
Aniline-d7, 99 atom% D
| 4165-61-1 |
|
Benzyl chloroformate, 50 wt% solution in toluene
| 108-88-3 |
|
Nitrobenzene-D5, 99.5 Atom% D
| 4165-60-0 |
|
1,1,2,2-Tetrachloroethane-d2, 99.5+ atom% D
| 33685-54-0 |
|
4,4'-Ethylenedianiline, 95%
| 621-95-4 |
|
Bromoform-d, stabilized with copper, 99 atom% D
| 75-25-2 |
|
1,2-Bis(dichlorophosphino)ethane, 97%
| 28240-69-9 |
|
N-Benzyl-4-cyano-4-(1-piperidino)-piperidine
| 84254-97-7 |
|
1,3,6,8-Pyrenetetrasulfonic Acid Tetrasodium Salt, 85+% (UV-VIS)
| 59572-10-0 |
|
Dittmer reagent, 95%
| |
|
Isoquinoline, 97%
| 119-65-3 |
|
Alkylbenzene sulfonic acid, mixture of C10-C13 isomers
| |
|
Methyltriallylsilane
| 1112-91-0 |
|
Tetraallylsilane
| 1112-66-9 |
|
2-Ethoxy-2-(2'-phenylsulfonylethyl)-1,3-dioxolane
| 149099-23-0 |
|
Sodium Hydride, Dispersion in Mineral Oil, 75%
| 7646-69-7 |
|
Hexaphenyldisilane
| 1450-23-3 |
|
Citronellal (pract), 93% (gc)
| 106-23-0 |
|
Hydriodic Acid, 57 Wt.% Aq. Solution, Distilled, Unstabilized
| 7732-18-5 |
|
Cyclopentylamine, 99+%
| 1003-03-8 |
|
(Bromomethyl)triphenylphosphonium bromide, 98%
| 1034-49-7 |
|
Methyl trans-3-methoxyacrylate, 95%
| 5788-17-0 |
|
Benzyltriphenylphosphonium borohydride, 98%
| 18117-29-8 |
|
2-Methyl-6-phenylbenzothiazole, 97%
| 107559-02-4 |
|
Ethylenediaminetetraacetic acid ferric sodium salt, trihydrate, 98%
| 15708-41-5 |
|
2,4-Dichlorobenzyl Alcohol, 99%
| 1777-82-8 |
|
Diethyldithiocarbamic Acid Diethylammonium Salt, 98% (Titr.)
| 1518-58-7 |
|
Hydriodic acid, reagent ACS, 55% in water, without stabilizer
| 10034-85-2 |
|
2,2,6,6-Tetramethyl-4-Piperidone Hydrochloride, 97%
| 33973-59-0 |
|
Cellulose Acetate Hydrogen Phthalate, Acetyl Content 17.0-22.0%
| 9004-38-0 |
|
|