**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| | | | unlisted |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.Hygroscopic (absorbs moisture
from the air).
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes severe skin irritation and burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause burns to the digestive
tract.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Keep container tightly closed. Do not ingest
or inhale. Do not breathe spray or mist.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Keep from contact with oxidizing materials. Keep away from metals.
Corrosives area. Do not store near alkaline substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# :
United Kingdom, WEL - TWA: (listed as tellurium): 0.1 mg/m3 TWA
United Kingdom, WEL - STEL: (listed as tellurium): 0.3 mg/m3 STEL
United States OSHA: 0.1 mg/m3 TWA (listed under Tellurium).
Belgium - TWA: (listed as tellurium): 0.1 mg/m3 VLE
France - VME: (listed as tellurium): 0.1 mg/m3 VME
Germany: (listed as tellurium): 0.1 mg/m3 VME
Malaysia: (listed as tellurium): 0.1 mg/m3 TWA
Netherlands: (listed as tellurium): 0.1 mg/m3 MAC
Russia: (listed as tellurium): 0.01 mg/m3 TWA
Spain: (listed as tellurium): 0.1 mg/m3 VLA-ED
CAS# 27176-87-0:
CAS# 85536-14-7:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Viscous liquid
Color: brown
Odor: sulfur dioxide odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 315 deg C @ 760 mmHg
Freezing/Melting Point: 10 deg C
Autoignition Temperature: Not available.
Flash Point: > 200 deg C (> 392.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 1.2000
Molecular Formula: C18H30O3S
Molecular Weight: 322.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, strong bases, Corrosive to steel and
aluminum..
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# unlisted.
CAS# 27176-87-0: DB6600000
CAS# 85536-14-7 unlisted.
LD50/LC50:
Not available.
CAS# 27176-87-0: Oral, rat: LD50 = 650 mg/kg.
CAS# 85536-14-7.
Carcinogenicity:
-
Not listed by ACGIH, IARC, or NTP.
Dodecylbenzenesulfonic acid -
Not listed by ACGIH, IARC, or NTP.
Benzenesulfonic acid, 4-C10-13-sec-alkyl derivitives -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 10.8 mg/L; 96 Hr.; Static conditionsWater
flea Daphnia: EC50 = 11-23 mg/L; 48 Hr.; Unspecified
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ARYLSULPHONIC ACIDS, LIQUID
Hazard Class: 8
UN Number: 2586
Packing Group: III
IMO
Shipping Name: ARYLSULPHONIC ACIDS, LIQUID
Hazard Class: 8
UN Number: 2586
Packing Group: III
RID/ADR
Shipping Name: ARYLSULFONIC ACID, LIQUID
Hazard Class: 8
UN Number: 2586
Packing group: III
USA RQ: CAS# 27176-87-0: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# : No information available.
CAS# 27176-87-0: No information available.
CAS# 85536-14-7: 2
Canada
CAS# 27176-87-0 is listed on Canada's DSL List.
CAS# 85536-14-7 is listed on Canada's DSL List.
CAS# is not listed on Canada's Ingredient Disclosure List.
CAS# 27176-87-0 is listed on Canada's Ingredient Disclosure List.
CAS# 85536-14-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 27176-87-0 is listed on the TSCA inventory.
CAS# 85536-14-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/25/1997 Revision #5 Date: 3/18/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Octakis-6-Bromo-6-Deoxy-??5-Cyclodextrin
| 53784-84-2 |
|
Octakis-6-Iodo-6-Deoxy-??5-Cyclodextrin
| 168296-33-1 |
|
4-Chromanol 96%
| 1481-93-2 |
|
Octakis-6-(Dimethyl-Tert-Butylsilyl)-6-Deoxy-??5-Cyclodextrin
| 0-01-1 |
|
Diphenyl phthalate
| 84-62-8 |
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DL-4-Chlorophenylalanine Methyl Ester Hydrochloride, 99%
| 14173-40-1 |
|
1H-Benzotriazole, 98%
| 95-14-7 |
|
m-Cresol, 95%
| 108-39-4 |
|
Thiodiglycolic Acid,98%
| 123-93-3 |
|
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| 15060-26-1 |
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Methyl 4-(3-Oxo-3-Phenyl-1-Propenyl) Benzoate, 98+% (NMR)
| 98258-72-1 |
|
Barium oxide
| 1304-28-5 |
|
Zinc Sulfide, Pieces, 3-12 mm, 99.9%
| 1314-98-3 |
|
Bromobenzene-d5, 99.5 atom% D
| 4165-57-5 |
|
Toluene-d8, 99.5+ atom % D
| 2037-26-5 |
|
1-Butanol-d10, packaged in ampules, 99+ atom % D
| 71-36-3 |
|
Ethylbenzene-d10, packaged in ampules, 99+ atom% D
| 25837-05-2 |
|
Mesitylene-d12, packaged in ampule, 98 atom% D
| 69441-16-3 |
|
Methylcyclohexane-d14, packaged in ampules, 99 atom % D
| 108-87-2 |
|
Methyl-d3 methacrylate-d5, stabilized
| 80-62-6 |
|
Aniline-d7, 99 atom% D
| 4165-61-1 |
|
Benzyl chloroformate, 50 wt% solution in toluene
| 108-88-3 |
|
Nitrobenzene-D5, 99.5 Atom% D
| 4165-60-0 |
|
1,1,2,2-Tetrachloroethane-d2, 99.5+ atom% D
| 33685-54-0 |
|
4,4'-Ethylenedianiline, 95%
| 621-95-4 |
|
Bromoform-d, stabilized with copper, 99 atom% D
| 75-25-2 |
|
1,2-Bis(dichlorophosphino)ethane, 97%
| 28240-69-9 |
|
N-Benzyl-4-cyano-4-(1-piperidino)-piperidine
| 84254-97-7 |
|
1,3,6,8-Pyrenetetrasulfonic Acid Tetrasodium Salt, 85+% (UV-VIS)
| 59572-10-0 |
|
Dittmer reagent, 95%
| |
|
Isoquinoline, 97%
| 119-65-3 |
|
Alkylbenzene sulfonic acid, mixture of C10-C13 isomers
| |
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Methyltriallylsilane
| 1112-91-0 |
|
Tetraallylsilane
| 1112-66-9 |
|
2-Ethoxy-2-(2'-phenylsulfonylethyl)-1,3-dioxolane
| 149099-23-0 |
|
Sodium Hydride, Dispersion in Mineral Oil, 75%
| 7646-69-7 |
|
Hexaphenyldisilane
| 1450-23-3 |
|
Citronellal (pract), 93% (gc)
| 106-23-0 |
|
Hydriodic Acid, 57 Wt.% Aq. Solution, Distilled, Unstabilized
| 7732-18-5 |
|
Cyclopentylamine, 99+%
| 1003-03-8 |
|
(Bromomethyl)triphenylphosphonium bromide, 98%
| 1034-49-7 |
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| 5788-17-0 |
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Benzyltriphenylphosphonium borohydride, 98%
| 18117-29-8 |
|
2-Methyl-6-phenylbenzothiazole, 97%
| 107559-02-4 |
|
Ethylenediaminetetraacetic acid ferric sodium salt, trihydrate, 98%
| 15708-41-5 |
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2,4-Dichlorobenzyl Alcohol, 99%
| 1777-82-8 |
|
Diethyldithiocarbamic Acid Diethylammonium Salt, 98% (Titr.)
| 1518-58-7 |
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Hydriodic acid, reagent ACS, 55% in water, without stabilizer
| 10034-85-2 |
|
2,2,6,6-Tetramethyl-4-Piperidone Hydrochloride, 97%
| 33973-59-0 |
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Cellulose Acetate Hydrogen Phthalate, Acetyl Content 17.0-22.0%
| 9004-38-0 |
|
|