**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 95-14-7 |1H-Benzotriazole | 98% | 202-394-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22 36/38 5
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to eyes and skin.
Heating may cause an explosion.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. Moderately toxic to
humans by ingestion. May be harmful if swallowed. May cause central,
peripheral, and autonomic nervous system effects.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
May cause central, peripheral, and autonomic nervous system effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear. Do NOT use
mouth-to-mouth resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. This material in
sufficient quantity and reduced particle size is capable of creating
a dust explosion. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with skin
and eyes. Avoid contact with heat, sparks and flame. Avoid ingestion
and inhalation. Wash clothing before reuse.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Keep from contact with oxidizing materials.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Good general ventilation should be sufficient to control airborne
levels. Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: yellow-beige
Odor: characteristic odor - weak odor
pH: Not available.
Vapor Pressure: .04 mm Hg @ 20C
Viscosity: Not available.
Boiling Point: 201 - 204 deg C @ 15.00mmHg
Freezing/Melting Point: 96.00 - 97.00 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 195 deg C ( 383.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 20 g/l (20 c)
Specific Gravity/Density:
Molecular Formula: C6H5N3
Molecular Weight: 119.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, may decompose if heated.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, dust
generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 95-14-7: DM1225000
LD50/LC50:
CAS# 95-14-7: Inhalation, rat: LC50 = 1910 mg/m3/3H; Oral, mouse:
LD50 = 615 mg/kg; Oral, rat: LD50 = 560 mg/kg; Skin, rat: LD50 = >1
gm/kg.
Carcinogenicity:
1H-Benzotriazole -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Shipping Name: Not regulated.
Dangerous Goods Code:
UN Number:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 36/38 Irritating to eyes and skin.
R 5 Heating may cause an explosion.
Safety Phrases:
S 15 Keep away from heat.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 95-14-7: 2
United Kingdom Occupational Exposure Limits
Canada
CAS# 95-14-7 is listed on Canada's DSL List.
CAS# 95-14-7 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 95-14-7: OEL-RUSSIA:STEL 5 mg/m3;Skin
US FEDERAL
TSCA
CAS# 95-14-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/18/1998 Revision #3 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Octakis-6-Bromo-6-Deoxy-??5-Cyclodextrin
| 53784-84-2 |
|
Octakis-6-Iodo-6-Deoxy-??5-Cyclodextrin
| 168296-33-1 |
|
4-Chromanol 96%
| 1481-93-2 |
|
Octakis-6-(Dimethyl-Tert-Butylsilyl)-6-Deoxy-??5-Cyclodextrin
| 0-01-1 |
|
Diphenyl phthalate
| 84-62-8 |
|
DL-4-Chlorophenylalanine Methyl Ester Hydrochloride, 99%
| 14173-40-1 |
|
1H-Benzotriazole, 98%
| 95-14-7 |
|
m-Cresol, 95%
| 108-39-4 |
|
Thiodiglycolic Acid,98%
| 123-93-3 |
|
n-Acetyl-s-(2-hydroxyethyl)-l-cysteine
| 15060-26-1 |
|
Methyl 4-(3-Oxo-3-Phenyl-1-Propenyl) Benzoate, 98+% (NMR)
| 98258-72-1 |
|
Barium oxide
| 1304-28-5 |
|
Zinc Sulfide, Pieces, 3-12 mm, 99.9%
| 1314-98-3 |
|
Bromobenzene-d5, 99.5 atom% D
| 4165-57-5 |
|
Toluene-d8, 99.5+ atom % D
| 2037-26-5 |
|
1-Butanol-d10, packaged in ampules, 99+ atom % D
| 71-36-3 |
|
Ethylbenzene-d10, packaged in ampules, 99+ atom% D
| 25837-05-2 |
|
Mesitylene-d12, packaged in ampule, 98 atom% D
| 69441-16-3 |
|
Methylcyclohexane-d14, packaged in ampules, 99 atom % D
| 108-87-2 |
|
Methyl-d3 methacrylate-d5, stabilized
| 80-62-6 |
|
Aniline-d7, 99 atom% D
| 4165-61-1 |
|
Benzyl chloroformate, 50 wt% solution in toluene
| 108-88-3 |
|
Nitrobenzene-D5, 99.5 Atom% D
| 4165-60-0 |
|
1,1,2,2-Tetrachloroethane-d2, 99.5+ atom% D
| 33685-54-0 |
|
4,4'-Ethylenedianiline, 95%
| 621-95-4 |
|
Bromoform-d, stabilized with copper, 99 atom% D
| 75-25-2 |
|
1,2-Bis(dichlorophosphino)ethane, 97%
| 28240-69-9 |
|
N-Benzyl-4-cyano-4-(1-piperidino)-piperidine
| 84254-97-7 |
|
1,3,6,8-Pyrenetetrasulfonic Acid Tetrasodium Salt, 85+% (UV-VIS)
| 59572-10-0 |
|
Dittmer reagent, 95%
| |
|
Isoquinoline, 97%
| 119-65-3 |
|
Alkylbenzene sulfonic acid, mixture of C10-C13 isomers
| |
|
Methyltriallylsilane
| 1112-91-0 |
|
Tetraallylsilane
| 1112-66-9 |
|
2-Ethoxy-2-(2'-phenylsulfonylethyl)-1,3-dioxolane
| 149099-23-0 |
|
Sodium Hydride, Dispersion in Mineral Oil, 75%
| 7646-69-7 |
|
Hexaphenyldisilane
| 1450-23-3 |
|
Citronellal (pract), 93% (gc)
| 106-23-0 |
|
Hydriodic Acid, 57 Wt.% Aq. Solution, Distilled, Unstabilized
| 7732-18-5 |
|
Cyclopentylamine, 99+%
| 1003-03-8 |
|
(Bromomethyl)triphenylphosphonium bromide, 98%
| 1034-49-7 |
|
Methyl trans-3-methoxyacrylate, 95%
| 5788-17-0 |
|
Benzyltriphenylphosphonium borohydride, 98%
| 18117-29-8 |
|
2-Methyl-6-phenylbenzothiazole, 97%
| 107559-02-4 |
|
Ethylenediaminetetraacetic acid ferric sodium salt, trihydrate, 98%
| 15708-41-5 |
|
2,4-Dichlorobenzyl Alcohol, 99%
| 1777-82-8 |
|
Diethyldithiocarbamic Acid Diethylammonium Salt, 98% (Titr.)
| 1518-58-7 |
|
Hydriodic acid, reagent ACS, 55% in water, without stabilizer
| 10034-85-2 |
|
2,2,6,6-Tetramethyl-4-Piperidone Hydrochloride, 97%
| 33973-59-0 |
|
Cellulose Acetate Hydrogen Phthalate, Acetyl Content 17.0-22.0%
| 9004-38-0 |
|
|