**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 25837-05-2 |Ethylbenzene-d10, packaged in ampules | | 247-292-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
Causes mild skin irritation. Causes redness and pain.
Ingestion:
May cause irritation of the digestive tract. May cause headache.
Possible aspiration hazard. May cause nausea and vomiting. May cause
central nervous system depression. May cause effects similar to
those of acute inhalation.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. May
cause drowsiness, unconsciousness, and central nervous system
depression.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Containers may explode in the heat of a fire.
Flammable liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take
precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 25837-05-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 134.5 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 15 deg C ( 59.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with most common organic solven
Specific Gravity/Density: .9490g/cm3
Molecular Formula: C6D5C2D5
Molecular Weight: 116.25
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or
water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Not available.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 25837-05-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethylbenzene-d10, packaged in ampules -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Ethylbenzene CAS# 100-41-4:
Fish toxicity:
LC50 bluegill sunfish,
goldfish, guppy, fathead minnow
12-96 mg/l/96H (Blum, D.J.W. et al
Res.J.-Water Pollut. Control Fed. 1991, 63(3), 198-207; Pickering,
Q.J. et al J.-Water Pollut. Control Fed. 1966, 38,
1419).
Invertebrate toxicity:
EC50 Photobacterium phosphoreum 9.68
ppm/30min Microtox test (Kaiser, K.L.E. et al Water Pollut.
Res.J.Can. 1991, 26(3), 361-431).
EC50 Daphnia magna 2.1 mg/L/48H
(Vighi, M. et al Chemosphere 1987, 16(5), 1043-1051).
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ETHYLBENZENE
Hazard Class: 3
UN Number: 1175
Packing Group: II
IMO
Shipping Name: ETHYLBENZENE
Hazard Class: 3.2
UN Number: 1175
Packing Group: II
RID/ADR
Shipping Name: ETHYLBENZENE
Hazard Class: 3
UN Number: 1175
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20 Harmful by inhalation.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 29 Do not empty into drains.
WGK (Water Danger/Protection)
CAS# 25837-05-2: No information available.
Canada
CAS# 25837-05-2 is listed on Canada's NDSL List.
CAS# 25837-05-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 25837-05-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/22/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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