**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4165-61-1 |Aniline-d7 | 99 | 224-015-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 20/21/22 40 50 48/23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect. Very toxic to aquatic
organisms. Toxic : danger of serious damage to health by prolonged
exposure through inhalation, contact with skin and if
swallowed.Hygroscopic (absorbs moisture from the air).Light
sensitive.Combustible liquid.Dangerous for the environment.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury. May
cause lacrimation (tearing), blurred vision, and photophobia. May
cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May
cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Causes symptoms similar
to those of inhalation. Substance is readily absorbed through the
skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause effects similar to those of
acute inhalation. May cause central nervous system depression,
convulsions, coma, and possible death due to respiratory paralysis.
May cause cardiac effects such as heart blocks, arrhythmias, shock
and possible death due to cardiovascular collapse.
Inhalation:
Effects may be delayed. Causes respiratory tract irritation. May
cause methemoglobinemia, cyanosis (bluish discoloration of skin due
to deficient oxygenation of the blood), convulsions, tachycardia,
dyspnea (labored breathing), and death. May cause adverse central
nervous system effects including headache, convulsions, and possible
death. Inhalation may be fatal as a result of spasm, inflammation,
edema of the larynx and bronchi, chemical pneumonitis and pulmonary
edema. Aspiration may lead to pulmonary edema.
Chronic:
May cause liver and kidney damage. May cause fetal effects. May
cause digestive tract disturbances. Repeated exposure may cause
sensitization dermatitis. Chronic exposure may cause hemolysis of
the red blood cells followed by stimulation of the bone marrow.
Laboratory experiments have resulted in mutagenic effects. May cause
cyanosis - a blue-gray coloring of the skin and lips caused by a lack
of oxygen. Animal studies have reported the development of tumors.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Absorption of this product into the body may cause cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Moderate degrees of cyanosis need to be treated only by supportive
measures: bed rest and oxygen inhalation. Cleansing of the entire
contaminated area of the body is of utmost importance. Do not
administer alcohol in any form. Individuals with liver or kidney
disorders, impaired cardiovascular status, or a history of
alcoholism may be more susceptible to the effects of this product.
Effects may be delayed. If cyanosis is severe, intravenous injection
of Methylene Blue, 1mg/kg of body weight may be of value.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Will burn if involved in a
fire. Use water spray to keep fire-exposed containers cool.
Combustible liquid. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Containers may
explode when heated. Runoff from fire control or dilution water may
cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Remove all sources of ignition. Use
a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Do not ingest or inhale. Store protected from
light. Use only in a chemical fume hood. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Do not store in direct sunlight. Store in a tightly closed
container. Keep under a nitrogen blanket. Keep from contact with
oxidizing materials. Store in a cool, dry, well-ventilated area away
from incompatible substances. Poison room locked. Keep away from
acids. Material darkens in color on storage. Store protected from
moisture. Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower. Use only
under a chemical fume hood.
Exposure Limits
CAS# 4165-61-1:
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: aromatic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 94 deg C @ 30.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 69 deg C ( 156.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0990g/cm3
Molecular Formula: C6D5ND2
Molecular Weight: 100.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Volatile in steam.
Sensitive to light. May discolor on exposure to air and light.
Conditions to Avoid:
Incompatible materials, light, ignition sources, exposure to air,
excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, bases, aluminum, fluorine,
formaldehyde, iron, nitric acid, silver perchlorate, sodium peroxide,
sulfuric acid, zinc, hydrogen peroxides, ozone, acid anhydrides,
chlorosulfonic acid, oleum, perchromates, nitromethane, dibenzoyl
peroxide, benzenediazonium-2-carboxylate, boron trichloride,
tetranitromethane, trichloronitromethane, diisopropyl
peroxydicarbonate, hexachloromelamine, peroxomonosulfuric acid,
albumin, iron salts, perchloric acid, nitrobenzene, alkalis,
moisture, potassium peroxide, glycerine, fuming nitric acid,
N-chloro compounds, N-bromoimides (e.g. n-bromosuccinimide),
peroxydisulfuric acid, nitrosyl fluoride, toluene diisocyanate.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4165-61-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Aniline-d7 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 425-488 mg/L; 5,15 min;
Microtox test at 14.9-15.1CWater flea Daphnia: LC50 = 0.10 mg/L; 48
Hr; UnspecifiedFish: Rainbow trout: LC50 = 8.2 mg/L; Max. exposure =
7 days; UnspecifiedFish: Bluegill/Sunfish: 1020 ppm; 1 Hr;
Unspecified
Other
Dangerous to aquatic life in high concentrations.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ANILINE
Hazard Class: 6.1
UN Number: 1547
Packing Group: II
IMO
Shipping Name: ANILINE
Hazard Class: 6.1
UN Number: 1547
Packing Group: II
RID/ADR
Shipping Name: ANILINE
Hazard Class: 6.1
UN Number: 1547
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 48/23/24/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation,
contact with skin and if swallowed.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 28 After contact with skin, wash immediately
with...
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 4165-61-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4165-61-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4165-61-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/11/1999 Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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