MATERIAL SAFETY DATA SHEET
1.2
Version:
BASIC BARIUM PETRONATE庐 Barium Sulfonate DATE OF ISSUE: 01/08/2006
Date printed: 12/30/2006
________________________________________________________________________________________________________
1. PRODUCT AND COMPANY IDENTIFICATION
Product name : BASIC BARIUM PETRONATE庐 Barium Sulfonate
Oil Soluble Barium Sulfonate
Chemical name:
Petroleum Additive
Use of substance/preparation:
Chemtura USA Corporation
Supplier:
Chemtura Corporation (Worldwide HQ)
199 Benson Road
Middlebury, CT 06749 USA
CHEMTREC (24 hours) 800-424-9300
Emergency telephone number
Chemtura Corporation Emergency Response
(24 hours) 800-292-5898
For additional emergency telephone numbers
see section 16 of the Safety Data Sheet.
866-430-2775
Environmental, Health and Safety Department:
800 325 6252
Customer Service:
2. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT % BY WEIGHT
oil soluble barium sulfonate 40 - 45
CAS# Trade secret
Barium Carbonate 10 - 15
CAS# 513-77-9
One or more of the following: < 50
CAS# -
Distillates (petroleum), solvent-refined heavy praffinic
CAS# 64741-88-4
Distillates (petroleum), hydrotreated heavy parafinic
CAS# 64742-54-7
Distillates (petroleum), solvent-refined heavy nphthenic
CAS# 64741-96-4
Distillates (petroleum), hydrotreated heavy naphthenic
CAS# 64742-52-5
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MATERIAL SAFETY DATA SHEET
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Version:
BASIC BARIUM PETRONATE庐 Barium Sulfonate DATE OF ISSUE: 01/08/2006
Date printed: 12/30/2006
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water soluble barium compounds < 0.5
CAS# Trade secret
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
NORMAL PRECAUTIONS COMMON TO SAFE MANUFACTURING PRACTICE SHOULD BE FOLLOWED
IN HANDLING AND STORAGE.
4. FIRST AID MEASURES
Swallowing
Obtain medical attention., Do not induce vomiting., Rinse mouth with water.
Skin contact
Wash thoroughly with warm water using a mild soap., Remove contaminated clothing., Obtain medical attention if
irritation persists.
Inhalation
Remove to fresh air., Obtain medical attention., Aspiration may cause pulmonary edema or aspiration pneumonia.
Eye contact
Immediately flush eyes with water and continue washing for at least 15 minutes., Obtain medical attention if
irritation persists.
Notes to physician
WHEN MOLTEN ONLY (molten product can cause thermal burns) -
5. FIRE-FIGHTING MEASURES
Flash point: > 356 掳F > 180 掳C
NFPA CLASSIFICATION
Health: 1 Flammability: 1 Reactivity: 0 Special provisions:
Special fire fighting procedures
Do not discharge extinguishing waters into streams, rivers and lakes.
Special protective equipment for firefighters
Body covering protective clothing, full "turn-out" gear.
Self-contained breathing apparatus.
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MATERIAL SAFETY DATA SHEET
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BASIC BARIUM PETRONATE庐 Barium Sulfonate DATE OF ISSUE: 01/08/2006
Date printed: 12/30/2006
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Extinguishing media
Suitable: Extinguish with:
- dry chemical
- CO2
- foam
- water fog
Unsuitable: - water jets
Unusual fire and explosion hazards
Heat from fire can generate flammable vapor.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Wear suitable protective equipment., Eliminate sources of ignition.
Environmental precautions
Product has very low solubility in water., Prevent from entering sewer system, surface water or soil.
Methods for cleaning up
Small spill:
Absorb on inert material such as sand, earth, vermiculite.
Collect for disposal.
Large spill:
Dike to contain spill.
Pump product to salvage tank.
7. HANDLING AND STORAGE
HANDLING
Handling precautions
Electrically bond and ground all containers and equipment before transfer or use of material., Avoid contact with eyes, skin and
clothing., Avoid breathing vapor, aerosol and mist., Use with adequate ventilation., Wash thoroughly after handling.
Other precautions
Electrically bond and ground all containers and equipment.
STORAGE
Storage requirements
Store in a cool, dry place., Keep container tightly closed.
Further information on storage
Keep away from strong oxidizing agents.
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MATERIAL SAFETY DATA SHEET
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Version:
BASIC BARIUM PETRONATE庐 Barium Sulfonate DATE OF ISSUE: 01/08/2006
Date printed: 12/30/2006
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMIT VALUES
Country
Component Type Value Remark
water soluble barium compounds TWA - 0.5 mg/m3 as soluble barium compounds, calculated as
ACGIH barium
Component Type Value Remark
Mineral Oil Mist TWA (mist), 5.0 mg/m3 If used in way that generates a "mist" observe the limits for
ACGIH Mineral Oil Mist.
STEL (mist), 10.0 mg/m3
ACGIH
PERSONAL PROTECTION
Respiratory protection
A approved respirator with dual organic vapor/mist and particulates cartridge if vapor concentration exceeds permissible exposure
limit., Self-contained breathing apparatus in high vapor concentrations.
Hand protection / protective gloves
Neoprene type gloves.
Eye protection
Safety goggles.
Skin protection
Rubber or plastic apron
Other protective equipment
Eye bath, Safety shower
Industrial hygiene measures
Do not eat or drink at work.
ENGINEERING CONTROLS
Ventilation
Special, local ventilation is needed at points where vapors can be expected to escape to the workplace air.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Viscous liquid
Physical state
Brown
Color
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MATERIAL SAFETY DATA SHEET
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BASIC BARIUM PETRONATE庐 Barium Sulfonate DATE OF ISSUE: 01/08/2006
Date printed: 12/30/2006
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Mild petroleum
Odor
OTHER PROPERTIES
No data available.
Boiling point
> 1 at 16 掳C
Specific gravity (H2O=1)
> 1 g/cm3 at 16 掳C
Density
Negligible
Insoluble
Solubility in water
Soluble
Solubility in organic solvents
log POW: > 6
Partitioning coefficient
This product is soluble in oil.
> 356 掳F
Flash point
> 180 掳C
Method: Cleveland open cup ASTM D 92
Nil
Percent volatiles
> 30 mm2/s at 40 掳C
Kinematic viscosity
10. STABILITY AND REACTIVITY
Stability: Stable.
Incompatible materials
Stable under normal conditions.
Hazardous polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
SWALLOWING
Test results
Acute toxicity: Rat
LD50
Result: > 2,000 mg/kg
SKIN CONTACT
Acute effects
May cause irritation.
EYE CONTACT
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MATERIAL SAFETY DATA SHEET
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Version:
BASIC BARIUM PETRONATE庐 Barium Sulfonate DATE OF ISSUE: 01/08/2006
Date printed: 12/30/2006
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Acute effects
May cause irritation.
12. ECOLOGICAL INFORMATION
No information available.
13. DISPOSAL CONSIDERATIONS
Avoid discharge to sewers and natural waters., Incinerate in a furnace where permitted under
General:
national and local regulations.
Non-cleaned packages
Empty drums should be decontaminated and either passed to an an approved drum reconditioner or destroyed., Containers that
cannot be cleaned must be treated as waste.
14. TRANSPORT INFORMATION
DOT Classification
Not regulated if shipped or transported at temperatures under 100掳C (212 掳F) or in containers less than 450 liter.
If shipped at temperatures >= 100 掳C (212 掳F) and in containers >= 450 liters (119 US gal), this product is regulated as:
ELEVATED TEMPERATURE LIQUID, N.O.S., Class 9, UN 3257, PGIII, ERG 128.
IMDG Classification
Not regulated if shipped or transported at temperatures under 100掳C (212 掳F) or in containers less than 450 liter.
If shipped at temperatures >= 100 掳C (212 掳F) and in containers >= 450 liters (119 US
Proper shipping name:
gal), this product is regulated as: ELEVATED TEMPERATURE LIQUID, N.O.S.,
Class 9, UN 3257, PGIII, ERG 128.
ICAO Classification
This product is not regulated by ICAO @ <100掳C
FORBIDDEN BY AIR @ >= 100掳C
15. REGULATORY INFORMATION
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BASIC BARIUM PETRONATE庐 Barium Sulfonate DATE OF ISSUE: 01/08/2006
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Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of
release of toxic chemicals that appear in 40CFR372 (for SARA 313). This information must be included in MSDS's that
are copied and distributed for this material.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
oil soluble barium sulfonate Trade secret 40.00 - 45.00
Water Soluble Barium Compounds - < 0.50
Inorganic barium compound Not established
New Jersey Worker and Community Right-To-Know Act (Labeling Requirements)
Chemical name CAS# New Jersey TS Number
oil soluble barium sulfonate Trade secret 136411-5423P
Barium Carbonate 513-77-9
One or More of the Following Mineral Oils (Severly Treated) 64742-54-7 64742-54-7, 64741-96-4,
64742-52-5, 64742-54-7
CHEMICAL INVENTORY
Canada: This product is on the DSL.
Europe: The ingredients of this mixture are on the EINECS inventory.
United States: This product is on the TSCA inventory.
Australia: This product is on the AICS inventory.
China: This product is on the IECSC Inventory.
Japan: This product is on the ENCS inventory.
Korea: This product is listed on the Existing Chemicals List (ECL).
Philippines: This product is on the PICCS.
16. OTHER INFORMATION
FURTHER INFORMATION
MAY BE ON THE INVENTORY LIST BUT NOT NECESSARILY REGISTERED, (Korea, China, New Zealand) CONSULT
REGULATORY SPECIALIST.
Emergency Telephone Numbers
All +44 (0)208 762 8322
Latin America:
HMIS RATING
Health: 1 Flammability: 1 Reactivity: 0 PPI:
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MATERIAL SAFETY DATA SHEET
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Version:
BASIC BARIUM PETRONATE庐 Barium Sulfonate DATE OF ISSUE: 01/08/2006
Date printed: 12/30/2006
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STP Standard temperature and pressure
W/W 0 (HMIS)
1 (HMIS) Slight hazard
2 (HMIS) Moderate hazard
Copyright
3 (HMIS) Serious hazard
2005
4 (HMIS) Severe hazard
Chemtura
X (HMIS) Personal protection rating to be supplied by user depending on use
Corporati
conditions
on
THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN CHEMTURA CORPORATION.
WE BELIEVE THAT THE INFORMATION CONTAINED HEREIN IS CURRENT AS OF THE DATE OF THIS SAFETY
DATA SHEET. SINCE THE USE OF THIS INFORMATION AND OF THESE OPINIONS AND THE CONDITIONS OF USE
OF THIS PRODUCT ARE NOT WITHIN THE CONTROL OF CHEMTURA CORPORATION, IT IS THE USER'S
OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCTS.
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