MATERIAL SAFETY DATA SHEET
www.ciscochem.com
2522 Plantation Center Drive
Matthews, NC 28105
(704) 845 9440
IN CASE OF
1. PRODUCT NAME: 142 solvent 66/3
TRANSPORT EMERGENCY
2. CHEMICAL NAME: Mixture
CONTACT CHEMTREC
3. SYNOMYMS:
USA: 1-800-424-9300
INTERNATIONAL: 1-703-527-3887
4. CAS NUMBER: Mixture
5. COMPOSITION This product may be composed, in whole or in
part, of any of the following refinery streams:
Petroleum hydrocarbon distillates [CAS No: 8052-41-3
Hydrotreated Light Distillate (Petroleum) [CAS No: 64742-47-8
This product contains the following chemical components:
C10 Alkanes and Isoparaffins 鈥? mixture 鈥? 40-60 %
C11 Alkanes and Isoparaffins 鈥? mixture 鈥? 10-30 %
C9 Naphthenes 鈥? mixture 鈥? 10-15 %
Nonane, all isomers 鈥? mixture 鈥? 1-10 %
C12 Alkanes and Isoparaffins 鈥? mixture 鈥? 0-5 %
6. PROPERTIES: PHYSICAL STATE: Liquid
COLOR: Transparent, colorless
ODOR: Characterisitc hydrocarbon solvent odor
SPECIFIC GRAVITY: 0.794 (Water = 1)
PH: Not applicable
VAPOR DENSITY: >1 (Air=1)
BOILING RANGE: 192 c 鈥? 205 c (378 F-401 F)
MELTING/FREEZING POINT: Not available
VAPOR PRESSURE: 0.07 kPa (0.5 mm Hg) (at 20 c), 0.27 torr at 20 c (68 F) by Isoteniscope, (ASTM
D-2879)
VOLATILITY: 794 g/l VOC (w/v)
SOLUBILITY IN WATER: Very Slightly soluble in cold water (<0.1% w/w).
VISCOSITY (cSt@40 c): not available
FLASH POINT: Closed up: 63 c (145 F). (Tagliabue (ASTM D-56))
ADDITIONAL PROPERTIES: Paraffin, Isoparaffin and Cycloparaffin Hydrocarbons Content => <99 Wt.
% (ASTM D-1319);
Aromatic Hydrocarbon Content = >1 Wt. % (ASTM D-1319): Average Density at 60 F = 6.61 lbs./gal.
(Calculated via ASTM D-287); Aniline Cloud Point Temperature = 162 F (72 c) (ASTM D-611); Kauri-
Butanol (KB) Value = 31 (ASTM D-1133); Boiling Point Range = 378 to 401 F (192 to 205 c) (ASTM
D-86,, D-850, or D-1078); Dry Point Temperature = 401 F (205 c) (ASTM D-86, D-850 or D-1078);
Evaporation Rate = <0.1 (n-butyl acetate = 1.0); Heat Value = 20,633 Btu. Per pound, Flash Point = 145 F
(63 c) (TCC)
STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable
HAZARDOUS POLYMERIZATION: Not expected to occur.
CONDITIONS TO AVOID: Keep away from heat, flame and other potential ignition sources. Keep away
from strong oxidizing conditions and agents.
MATERIALS INCOMPATIBILITY: Strong acids, alkalies, and oxidizers such as liquid chlorine, and
oxygen.
HAZARDOUS DECOMPOSITION PRODUCTS: No additional hazardous decomposition products were
identified other than the combustion products identified in this MSDS.
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MATERIAL SAFETY DATA SHEET
www.ciscochem.com
2522 Plantation Center Drive
Matthews, NC 28105
(704) 845 9440
7. HAZARDS: CAUTION: Combustible liquid and vapor. Harmful or fatal if swallowed 鈥? Can enter lungs and cause
damage. Can cause eye, skin or respiratory tract irritation. Spills may create a slipped hazard.
Major routes of Entry: Skin contact. Inhalation
SIGNS and SYMPTOMS of ACUTE EXPOSURE:
INHALATION: Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and
lungs. Breathing this material may cause central nervous system depression with symptoms including nau-
sea, headache, dizziness, fatigue, drowsiness, or unconsciousness. Breathing high concentrations of this
material, for example, in an enclosed space or by intentional abuse, can cause irregular heartbeats which
can cause death.
EYE CONTACT: This product can cause transient mild eye irritation with short-term contact with liquid
sprays or mists. Symptoms include stinging, watering, redness, and swelling.
SKIN CONTACT: This product can cause mild, transient skin irritation with short-term exposure. The
Degree of irritation will depend on the amount of material that is applied to the skin and speed and thor-
oughness that it is removed. Symptoms include redness, itching, and burning of the skin. Repeated or
prolonged skin contact can produce moderate irritation (dermatitis).
INGESTION: If swallowed, this material may irritate the mucous membranes of the mouth, throat, and
esophagus. It can be readily absorbed by the stomach and intestinal tract. Symptoms include a burning
sensation of the mouth and esophagus, nausea, vomiting, dizziness,staggering gait, drowsiness, loss of
consciousness, and delirium, as well as additional central nervous system (CNS) effects. Due to its light
viscosity, there is a danger of aspiration into the lungs during vomiting. Aspiration can result in severe
lung damage or death.
CHRONIC HEALTH EFFECTS SUMMARY: Chronic effects of ingestion and subsequent aspiration into
the lungs may cause pneumatocele (lung cavity) formation and chronic lung dysfunction. Reports have as-
sociated repeated and prolonged occupational overexposure to solvents with irreversible brain and nervous
system damage (sometimes referred to as 鈥淪olvent or Painter鈥檚 Syndrome鈥?). International misuse by delib-
erately concentrating and inhaling this product may be harmful or fatal.
CONDITIONS AGGRAVATED BY EXPOSURE: Disorders of the following organs or organ systems that
may be aggravated by significant exposure to this material or its components include: Skin, Respiratory
System, Liver, Kidneys, Central Nervous System (CNS)
TARGET ORGANS: May cause damage to the following organs: kidneys, lungs liver, mucous mem-
branes, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
CARCINOGENIC POTENTIAL: This product is not known to contain any components at concentrations
above 0.1% which are considered carcinogenic by OSHA, IARC or NTP.
OSHA HEALTH HAZARD CLASSIFICATION: not listed
OSHA PHYSICAL HAZARD CLASSIFICATION: Combustible
8. FIRE FIGHTING NFPA FLAMMABILITY: NFPA Class-lll combustible liquid.
MEASURES: FLASH POINT: Closed cup: Closed cup: 63 c (145 F). (Tagliabue (ASTM D-56))
LOWER FLAMMABILITY LIMIT: AP 0.8 %
UPPER FLAMMABILITY LIMIT: AP 6 %
AUTIOGNITION TEMPERATURE: Not available
HAZARDOUS COMBUSTION PRODUCTS: Carbon dioxide, carbon monoxide, smoke, fumes, and/or
unburned hydrocarbons
SPECIAL PROPERTIES: Combustible liquid! This material releases vapors when heated above ambient
temperatures. Vapors can cause a flash fire. Vapors can travel to a source of ignition and flashback. A
vapor and air mixture can create an explosion hazard in confined spaces such as sewers. Use only with
adequate ventilation. If container is not properly cooled, it can rupture in the heat of fire.
EXTINGUISHING MEDIA: Small Fire: Use dry chemicals, carbon dioxide, foam, water fog, or inert gas
(nitrogen).
Large Fire: Use foam, water fog, or water spray. Water fog and spray are effective in cooling containers
and adjacent structures. However, water can cause frothing and/or may not extinguish the fire. Water can
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MATERIAL SAFETY DATA SHEET
www.ciscochem.com
2522 Plantation Center Drive
Matthews, NC 28105
(704) 845 9440
be used to cool the external walls of vessels to prevent excessive pressure, autoignition or explosion. DO
NOT use a solid stream of water directly on the fire as the water may spread the fire to larger area.
PROTECTION OF FIRE FIGHTERS: Fire fighter must use full bunker gear including NIOSH-approved
positive pressure self-contained breathing apparatus to protect against potential hazardous combustion
or decomposition products and oxygen deficiencies. Evacuate area and fight the fire from a maximum
distance or use unmanned hose holders or monitor nozzles. Cover pooling liquid with foam. Containers
can build pressure if exposed to radiant heat; cool adjacent containers with flooding quantities of water
until well after the fire is out. Withdraw immediately from the area if there is a rising sound from a vent-
ing safety device or discoloration of vessels, tanks, or pipelines. Be aware that burning liquid will float
on water. Notify appropriate authorities of potential fire and explosion hazard if liquid enter sewers or
waterways.
9. PERSONAL ENGINEERING CONTROLS: Provide exhaust ventilation or other engineering controls to keep the
PROTECTION airborne concentrations of vapor or mists below the applicable workplace exposure limits indicated below.
MEASURES: All electrical equipment should comply with the National Electric Code. An emergency eye wash station
and safety shower should be located near the work-station.
PERSONAL PROTECTIVE EQUIPMENT: Personal Protective equipment should be selected based upon
the conditions under which this material is used. A hazard assessment of the work area for PPE require-
ments should be conducted represent the minimum requirements of personal protective equipment. For
certain operations, additional PPE may be required.
EYE PROTECTION: Safety glasses equipped with side shields are recommended as minimum protec-
tion in industrial settings. Chemical goggles should be worn during transfer operations or when there is a
likelihood of misting, splashing, or spraying of this material. Suitable eye wash water should be readily
available.
HAND PROTECTION: Avoid skin contact. Use heavy duty gloves constructed of chemical resistant
materials such as Viton R or heavy nitrile rubber. Wash hands with plenty of mild soap and water before
eating, drinking, smoking, use of toilet facilities or leaving work. DO NOT use gasoline, kerosene or harsh
abrasives as skin cleaners.
BODY PROTECTION: Avoid skin contact. Wear long-sleeved fire-retardant garments (e.g, Nomex R)
while working with flammable and combustible liquids.
Additional chemical-resistant protective gear may be required if splashing or spraying conditions ex-
ist. This may include an apron, boots and additional facial protection. If product comes in contact with
clothing, immediately remove soaked clothing and shower. Promptly remove and discarded contaminated
leather goods.
RESPIRATORY PROTECTION: For unknown vapor concentrations or concentrations exceeding respira-
tor protection factors, use a positive-pressure, pressure-demand, self-contained apparatus (SCBA). Due
to fire and explosion hazards, do not enter atmospheres containing concentrations greater than 20% of the
lower flammable limit under any circumstances. Protection factors vary depending upon the type of respi-
rator used. Respirators should be used in accordance with OSHA requirements (29CFR 1910.134).
GENERAL COMMENTS: Warning! Use of this material is spaces without adequate ventilation may re-
sult in generation of hazardous levels of combustion products and/or inadequate oxygen levels for breath-
ing. Odor is an inadequate warning for hazardous conditions.
10. FIRST AID Take proper precautions to ensure your own health and safety before attempting rescue or providing first
PROCEDURES: aid.
INHALATION: Immediately move victim to fresh air. If victim is not breathing, immediately begin res-
cue breathing. If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). If breathing
is difficult, 100 percent humidified oxygen should be administered by a qualified individual. Seek medical
attention immediately.
EYE CONTACT: Check for and remove contact lenses. If irritation or redness develops, flush eyes with
cool, clean, low-pressure water for at leas 15 min. Hold eyelids apart to ensure complete irrigation of the
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MATERIAL SAFETY DATA SHEET
www.ciscochem.com
2522 Plantation Center Drive
Matthews, NC 28105
(704) 845 9440
eye and eyelid tissue. Do not use eye ointment. Seek medical attention immediately.
SKIN CONTACT: Remove contaminated shoes and clothing. Flush affected area with large amounts of
water. If skin surface is not damaged, apply a clean dressing and seek medical attention. Do not use oint-
ments. If skin surface is damaged, clean effected area thoroughly with mild soap and water. Seek medical
attention if tissue appears damaged or if pain or irritation persists.
INGESTION: Do not induce vomiting. If spontaneous vomiting is about to occur, place victim鈥檚 head be-
low knees. If victim is drowsy or unconscious, place on the left side with head down, Never give anything
by mouth to a person who is not fully conscious. Do not leave victim unattended. Seek medical attention
immediately.
NOTES TO PHYSICIAN: Inhalation: inhalation overexposure can produce toxic effects. Monitor for
respiratory distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract
inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with assisted ventilation, as
required.
This material (or a component) sensitizes the heart to effects of sympathomimetic amines. Epinephrine
and other synpathomimetic drugs may irritate cardiac arrhythmias in individuals exposed to this material.
Administration of sympathomimetic drugs should be avoided.
Ingestion: If ingested, this material presents a significant aspiration and chemical pneumonitis hazard.
Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is
obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelen-
burg and left lateral decubitus position.
11. EXPOSURE PETROLEUM HYDROCARBON DISTILLATES: ACGIH (United States). 鈥? TWA: 100ppm, OSHA
LIMITS: (United States). 鈥? TWA: 500 ppm
NONANE, ALL ISOMERS: ACGIH (United States). 鈥? TWA: 200 ppm
12. TOXICOLOGICAL Studies on laboratory animals have shown similar materials to cause eye and respiratory tract irritation.
INFORMATION: Studies of similar materials on laboratory animals have resulted in skin irritation after repeated or pro-
longed contact. Prolonged or repeated contact can result in defatting and drying of the skin which may
result in skin irritation and rash (dermatitis).
PETROLEUM HYDROCARBON DISTILLATES: Dermal, Acute LD50 (rabbit): >3000mg/kg, Inhala-
tion Acute LC50 (rat): >5.5mg/l (8hours)
Studies on laboratory animals have associated similar materials with eye and respiratory tract irritation.
Studies on laboratory animals have shown similar materials to cause skin irritation after repeated or pro-
longed contact. Repeated direct application of Stoddard Solvent to the skin can produce defatting derma-
titis and kidney damage in laboratory animals. Rats developed kidney damage and elevated blood urea
nitrogen levels when exposed to a concentration of 1.9 mg/L for 65 days. The kidney damage occurred
only in male rats and appeared to involve both the tubules and glomeruli. The significance of these animal
study results to human health is unclear.
13. ECOLOGICAL ECOTOXICITY: This mixture contains components that are potentially toxic to freshwater and saltwater
INFORMATION: ecosystems.
ENVIRONMENTAL FATE: This mixture will normally float on water with its lighter components
evaporation rapidly. In stagnant or slow-flowing waterways, a hydrocarbon layer can cover a large surface
area. As a result, this covering layer might limit or eliminate natural atmospheric oxygen transport into the
water. With time, if not removed, oxygen depletion in the waterway might be enough to cause a fish a kill
or create an anaerobic environment. This coating action can also be harmful or fatal to plankton, algae,
aquatic life, and water birds.
14. DISPOSAL Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly,
CONSIDERAIONS: it is the responsibility of user to determine the proper storage, transportation, treatment and/or disposal
methodologies for spent materials and residues at the time of disposition.
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MATERIAL SAFETY DATA SHEET
www.ciscochem.com
2522 Plantation Center Drive
Matthews, NC 28105
(704) 845 9440
Conditions of use may cause this material to become a 鈥渉azardous waste鈥?, as defined by federal or state
regulations. It is the responsibility of the user to determine if the material is a RCRA 鈥渉azardous waste鈥? at
the time of disposal. Transportation, treatment, storage and disposal of waste material must be conducted
in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or local regula-
tions may be more restrictive. Contact the RCRA/Superfund Hotline at (800) 424-9346 or your regional
US EPA office for guidance concerning case specific disposal issues.
15. CARCINOGENIC CALIFORNIA PROPOSITION 65: This product is not known to contain any components for which the
PROPERTIES & State of California has found to cause cancer, birth defects or other reproductive harm.
NOTIFICATIONS:
16. TRANSPORT The shipping description below may not represent requirements for all modes of transportation, shipping
INFORMATION: methods or locations outside of the United States.
US DOT Status: A U.S. Department of Transportation (DOT) regulated material.
PROPER SHIPPING NAME: Petroleum Distillates, n.o.s., (Solvent Naphtha), Combustible Liquid,
UN1268, PG lll
HAZARD CLASS: Combustible liquid
PACKING GROUPS: III
UN/NA NUMBER: UN1268
REPORTABLE QUANTITY: A Reportable Quantity (RQ) has not been established for this material
PLACARDS: Combustible 3
EMERGENCY RESPONSE GUIDE NO. : 128
HAZMAT STCC No: 4910256
MARPOL III STATUS: Not a DOT 鈥淢arine pollutant鈥? per 49 CFR 171.8.
17. HANDLING & HANDLING: A spill or leak can cause an immediate fire or explosion hazard. Keep closed and do not
STORAGE: handle or store near heat, sparks, or any other potential ignition sources. Do not contact with oxidizible
materials. Do not breathe vapor. Use only with adequate ventilation and personal protection. Never
siphon by mouth. Avoid contact with eyes, skin, and clothing. Prevent contact with food and tobacco
products. Do not take internally.
When performing repairs and maintenance on contaminated equipment, keep unnecessary persons away
from the area. Eliminate all potential ignition sources. Drain and purge equipment, as necessary, to
remove material residues. Follow proper entry procedures, including compliance with 29 CFR 1910.146
prior to entering confined spaces such as tanks or pits. Use gloves constructed of impervious materials
and protective clothing if direct contact is anticipated. Provide ventilation to maintain exposure potential
below applicable exposure limits. Use appropriate respiratory protection when concentrations exceed any
established occupational exposure level (See section 8). Promptly remove contaminated clothing. Wash
exposed skin thoroughly with soap and water after handling.
A static electrical charge an accumulate when this material is flowing through pipes, nozzles or filters and
when it is agitated. A static spark discharge an ignite accumulated vapors particularly during dry weather
conditions. Always bond receiving containers to the fill pipe before and during loading. Always keep
nozzle in contact with the container throughout the loading process. Do not fill any portable container in
or on a vehicle. DO NOT use compressed air for filling, discharging or other handling operations.
Product container is not designed for elevated pressure. Do not pressurize, cut, weld, braze solder, drill,
or grind on containers. Do not expose product containers to flames, sparks, heat or other potential ignition
sources. Empty containers may contain product residues that can ignite with explosive force. Observe
label precautions. Consult appropriate federal, state and local authorities before reusing, reconditioning,
reclaiming, recycling or disposing or empty containers and/or waste residues of this product.
HEALTH HAZAERD: HMIS 鈥? 1, NFPA 鈥? 1
FIRE HAZARD: HMIS 鈥? 2, NFPA 鈥? 2
REACTIVITY: HMIS 鈥? 0, NFPA 鈥? 0 = CHRONIC HEALTH HAZARD
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MATERIAL SAFETY DATA SHEET
www.ciscochem.com
2522 Plantation Center Drive
Matthews, NC 28105
(704) 845 9440
STORAGE: Keep container closed. Store in a cool, dry, well-ventilated area. Do not store with oxidizing
agents. Do not store at elevated temperatures or in direct sunlight for extended periods of time. Consult
appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or
disposing of empty containers or waste residues of this product.
CERCLA: The Comprehensive Environmental Response, compensation, and Liability Act of 1980 (CER-
CLA) requires notification of the National Response Center concerning release of quantities of 鈥渉azardous
substances鈥? equal to or greater than the reportable quantities (RQ鈥檚) listed in 40 CFR 302.4. As defined by
CERCLA, the term 鈥渉azardous substance鈥? does not include petroleum, including crude oil or any fraction
thereof which is not otherwise specifically designated in 40 CFR 302.4. This product or refinery stream
is not known to contain chemical substance subject to this statute. However, it is recommended that you
contact state and local authorities to determine if there are any other reporting requirements in the event of
a spill.
CLEAN WATER ACT (CWA): This material is classified as an oil under section 311 of the Clean Water
Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen
on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must
be reported to the EPA鈥檚 National Response Center at (800) 424-8802.
18. ACCIDENTAL Combustible liquid! Release causes an immediate fire or explosion hazard. Evacuate all non-essential
RELEASE personnel from immediate area and establish a 鈥渞egulated zone鈥? with site control and security. A vapor-
MEASURES: suppressing foam may be use to reduce vapors. Eliminate all ignition sources. All equipment used when
handling this material must be grounded. Stop the leak If it can done without risk. Do not touch or walk
through spilled material. Remove spillage immediately from hard, smooth walking areas. Prevent its entry
into waterways, sewers, basements, or confined areas. Absorb or cover with dry earth, sand or other non-
combustible material and transfer to appropriate waste containers. Use clean, non-sparking tools to collect
absorbed material.
For large spills, secure the area and control access. Dike far ahead a liquid spill to ensure complete col-
lection. Water mist or spray may be used to reduce or disperse vapors; bit, it may not prevent ignition
in closed spaces. This material will float on water and its run-off may create an explosion or fire hazard.
Verify that responders are properly HAZWOPER-trained and wearing appropriate respiratory equipment
and fire-resistant protective clothing during cleanup operations. In an urban area, cleanup spill as soon
as possible; in natural environments, cleanup on advice from specialists. Pick up free liquid for recycle
and/or disposal if it can be accomplished safety with explosion-proof equipment. Collect any excess mate-
rial with absorbent pads, sand, or other inert non-combustible absorbent materials. Place into appropriate
waste containers for later disposal. Comply with all applicable local, state and federal laws and regula-
tions.
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