Material Safety Data Sheet
Freeman 701 Hardener
Date of Preparation: January 3, 2007 Revision:
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Freeman 701 Hardener HMIS
Chemical Family: Amine 3
H
CAS Number: N/A 1
F
Other Designations: N/A 0
R
Intended Use or Product Type: Amine Hardener PPE鈥?
Manufacturer: Freeman Manufacturing and Supply Company, 1101 Moore Road, Avon, OH 44011, 鈥燬ec. 8
Phone (440)934-1902, FAX (440)934-7200, Hours of Operation 8-5, Emergency Phone Number 800-424-9300.
Emergency Overview
Corrosive 鈥? causes skin and eye burns. Causes severe irritation if inhaled and can cause allergic respiratory reaction
and allergic skin reaction. Can be harmful if absorbed through skin and may be harmful if swallowed.
Section 2 - Composition / Information on Ingredients
Ingredient Name CAS Number
*Diethylenetriamine 111-40-0
* Triethylenetetramine 112-24-3
* Tetraethylenepentamine 112-57-2
*Butyl glycidyl ether 2426-08-6
* Pentaethylenehexamine 4067-16-7
* Bisphenol A 80-05-7
* Polyethylene Polyamine Epoxy Adduct Proprietary
* = OSHA Hazardous Ingredient
Ingredient OSHA ACGIH MFR
PEL STEL TWA STEL
none estab. none estab. 1 ppm none estab. none estab.
Diethylenetriamine
none estab. none estab. none estab. none estab. none estab.
Triethylenetetramine
none estab. none estab. none estab. none estab. none estab.
Tetraethylenepentamine
50 ppm none estab. 25 ppm none estab. 25 ppm
Butyl glycidyl ether
none estab. none estab. none estab. none estab. none estab.
Pentaethylenehexamine
none estab. none estab. none estab. none estab. TLV
Bisphenol A
5 mg/m3
none estab. none estab. none estab. none estab. none estab.
Polyethylene Polyamine
Epoxy Adduct
Section 3 - Physical and Chemical Properties
Physical State: Liquid Water Solubility: Partially soluble
Appearance and Odor: Clear amber liquid Boiling Point: >400掳 F (>204掳 C)
Vapor Pressure: Not Determined % Volatile: Negligible
Vapor Density (Air=1): Not Determined VOC: Not Determined
Specific Gravity (H2O=1, at 4 掳C): 1.006
Section 4 - Fire-Fighting Measures
NFPA
Flash Point: >200 掳F (>93 掳C)
Flash Point Method: Estimated
1
LEL: N/E
0
3
UEL: N/E
鈥?
Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
Fire-Fighting Equipment: Use self-contained breathing apparatus.
Freeman 701 Hardener Revision:
Fire or Explosion Hazards: Decomposition and combustion products may be toxic.
Section 5 - Stability and Reactivity
Stability: Stable.
Conditions to Avoid: Excessive heat for prolonged periods of time.
Incompatibility: Strong oxidizers, acids, and bases
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.
Hazardous Polymerization: Will not occur.
Section 6 - Health Hazard Information
Potential Health Effects
Primary Entry Routes: Dermal; heated product may produce inhalable vapors
Acute Effects: Corrosive. Causes skin and eye burns.
Chronic Effects: Overexposure may have effects on developing fetus, lung, kidney, and liver. Possible mutagen.
Overexposure Effects: Corrosive 鈥? causes skin and eye burns. Causes severe irritation if inhaled and can cause allergic
respiratory reaction and allergic skin reaction. Can be harmful if absorbed through skin and may be harmful if swallowed.
Medical Conditions Aggravated by Exposure: Skin, eye and pulmonary conditions.
Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.
Emergency and First Aid Procedures
Inhalation: Remove to fresh air. Call a physician.
Eye Contact: Immediately flush eyes with water for at least 15 minutes. Call a physician.
Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy
contaminated shoes.
Ingestion: If conscious, give 2-4 glasses of water to drink. Do not induce vomiting. Call a physician.
Section 7 - Spill, Leak, and Disposal Procedures
Accidental Release Measures: Remove spillage by absorbing in absorbent material.
Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.
Ecological Information: N/A
Toxicological Information:
Acute Oral Effects (LD50):
Diethylenetriamine = 1080 鈥? 2330 mg/kg (rat)
Triethylenetetramine = 2500 鈥? 4340 mg/kg (rat)
Acute Dermal Toxicity (LD50):
Diethylenetriamine = 672 鈥? 1240 mg/kg (rabbit)
Triethylenetetramine = 550 鈥? 800 mg/kg (rabbit)
Acute Inhalation Exposure Effects: Severe respiratory irritant.
Sensitization: May cause allergic skin reaction and respiratory sensitivity in some people.
Skin Irritation: Corrosive. Causes burns.
Eye Irritation: Corrosive. Causes burns.
Regulatory Information:
US Federal Regulations:
Occupational Safety and Health Act (OSHA): This material Safety Data Sheet (MSDS) has been prepared in compliance with
the federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous chemical
under that standard.
Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CFR 261) but handle with care
due to corrosive effect on skin and eyes.
SARA Title III Section 313 Toxic Chemical List (TCL): This product contains a toxic chemical(s) for routine annual toxic
chemical release reporting under Section 313 (40 CFR 372). This information must be included in all MSDS鈥檚 copied or
distributed for this material.
Chemical Name: Phenol, 4,4`-(1-methylethylidene)bis-
Common Name: Bisphenol A
Percent in Composition: 2.4994% by weight
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Revision: Freeman 701 Hardener
TSCA Section 8(b) - Inventory Status: All chemical components of this product are in compliance with TSCA inventory
requirements.
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification
State Regulations:
California Proposition 65: This product does not contain any chemicals currently on the California list of Known Carcinogens
and Reproductive Toxins.
*Diethylenetriamine (CAS # 111-40-0) is on the New Jersey and Pennsylvania Right to Know Lists.
Triethylenetetramine (CAS # 112-24-3) is on the New Jersey and Pennsylvania Right to Know Lists.
Tetraethylenepentamine(CAS # 112-57-2) is on the New Jersey Right to Know List.
Butyl glycidyl ether (CAS # 2426-08-6) is on the New Jersey Right to Know List.
Bisphenol A (CAS # 80-05-7) is on the New Jersey Right to Know List
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.
Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.
Eye Protection: Wear splash-proof chemical goggles.
Skin protection: Wear impermeable gloves.
Section 9 - Special Precautions and Comments
Handling and Storage:
Signal Word: Danger!
Precautions: Corrosive-causes skin and eye burns. Causes irritation if inhaled and can cause allergic respiratory reaction and
allergic skin reaction. Can be harmful if absorbed through skin and may be harmful if swallowed. Do not breathe vapor or
mist. Do not get in eyes, on skin, or on clothing. Avoid tasting or swallowing. Keep containers closed when not in use. Use
with adequate ventilation. Wash thoroughly after handling. Notice! Overexposure may have effects on developing fetus, lung,
kidney, and liver. Possible mutagen.
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Corrosive liquid, Packaging Authorizations Quantity Limitations
Basic, Organic, N.O.S. a) Exceptions: a) Passenger, Aircraft, or Railcar:
b) Non-bulk Packaging: Non-Bulk
Technical Shipping Name: b) Cargo Aircraft Only:
Tetraethylenepentamine, c) Bulk Packaging:
Triethylenetetramine Vessel Stowage Requirements
Shipping Symbols: a) Vessel Stowage:
Hazard Class: 8 b) Other:
ID No.: UN 3267
Packing Group: PG II
Label: Corrosive
Prepared By:
Revision Notes:
Disclaimer: The following supersedes Buyer鈥檚 documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no
circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty,
strict of liability arising in connection with the product(s). Buyer鈥檚 sole remedy and Seller鈥檚 sole liability for any claims shall be
Buyer鈥檚 purchase price. Data and results are based on controlled lab work and must be confirmed by Buyer by testing for its
intended conditions of use. The product(s) has not been tested for, and is therefore not recommended for, uses for which
prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the
human body is intended.
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