MATERIAL SAFETY DATA SHEETS
MS61020
For FUJIFILM Product Code: 61020
Description: CD 161 DEVELOPER REPLENISHER P1R
Carton Identification Code: Cat 822565, 822575, 822520
Covers 3 part/s:
Bottle Identification Code: Cat 722565, 722575, 722566, 722576,
722567, 722577
Note: Material Safety Data Sheets must be kept on the premises where chemicals are stored and used.
They must be made readily available to all persons concerned with this chemistry. These may including
transport operators, store persons, workers, machine operators, retail / medical staff, store managers,
building owners and managers, emergency services, and government or industry inspectors.
AUSTRALIA: NEW ZEALAND:
Emergency Information: (02) 9466 2721 (09)414 0400.
FUJIFILM Australia Pty Ltd ABN 80 000 064 433
114 Old Pittwater Road
Brookvale, NSW 2100
Phone: (02) 9466 2600 Fax: (02) 9938 1975
Visit our website: http://www.fujifilm.com.au for the latest version of this MSDS.
Issue Date: August 2004
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART A
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 1 of 5
SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
FUJIFILM Australia Pty Ltd ABN 80 000 064 433 FUJIFILM (NZ) Limited
114 Old Pittwater Rd Cnr William Pickering Dr & Bush Rd
Brookvale NSW 2100 Albany, Auckland
Phone: 02 9466 2600 Fax: 02 9938 1975 Phone (09)414 0400
Emergency Information: (02)9466 2721 (Aust), (09)414 0400 (NZ) http://www.fujifilm.com.au/
Water solution of ingredients.
Substance:
CD 161 DEVELOPER REPLENISHER P1R PART A
Trade Name:
61020
Product Code:
Photographic developer replenisher for colour print paper in mini labs. Part A of a
Product Use:
three part system.
Creation Date: August, 2004
Revision Date: August, 2004
SECTION 2 - HAZARDS IDENTIFICATION
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R36/37/38. Irritating to eyes, respiratory system and skin.
Safety Phrases: S23, S38, S24/25. Do not breathe vapours or mists. In case of insufficient ventilation, wear
suitable respiratory equipment. Avoid contact with skin and eyes.
SUSDP Classification: S5
ADG Classification: None allocated. Not a Dangerous Good.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Clear, light amber liquid.
Odour: Mild amine odour.
Major Health Hazards: irritating to eyes, respiratory system and skin.
Potential Health Effects
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this
product is not harmful. However product is an inhalation irritant. Symptoms may include headache, irritation of nose
and throat and increased secretion of mucous in the nose and throat. Other symptoms may also become evident, but
they should disappear after exposure has ceased.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. However product is a skin irritant.
Symptoms may include itchiness and reddening of contacted skin. Other symptoms may also become evident, but all
should disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: Exposure via eyes is considered to be unlikely. This product is an eye irritant. Symptoms
may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also
become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy
exposure or delayed treatment may cause permanent damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. This product, while believed to be not
harmful, is likely to cause headache and gastric disturbance such as nausea and vomiting if ingested in significant
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART A
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 2 of 5
quantities. This product is an oral irritant. Symptoms may include burning sensation and reddening of skin in mouth
and throat. Other symptoms may also become evident, but all should disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: Triethanolamine is Class 3 - unclassifiable as to carcinogenicity to humans.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3 3
Ingredients CAS No Conc,% TWA (mg/m ) STEL (mg/m )
Triethanolamine 102-71-6 20-25 5 not set
Diethanesulfonic acid 133986-51-3 5-10 not set not set
Bis triazinylamino stilbene acid derivative 82640-05-9 1-5 not set not set
Other non hazardous ingredients secret <10 not set not set
Water 7732-18-5 to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
SECTION 4 - FIRST AID MEASURES
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: If irritation occurs, contact a Poisons Information Centre, or call a doctor. Remove source of
contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained
personnel, preferably on a doctor's advice. In severe cases, symptoms of pulmonary oedema can be delayed up to 48
hours after exposure.
Skin Contact: Quickly and gently, blot or brush away excess chemical. Wash gently and thoroughly with water (use
non-abrasive soap if necessary) for 20 minutes or until product is removed. Under running water, remove
contaminated clothing, shoes and leather goods (e.g. watchbands and belts). Completely decontaminate clothing,
shoes and leather goods before reuse or discard. If irritation persists, repeat flushing and obtain medical advice.
Eye Contact: Quickly and gently blot or brush away product. Immediately flush the contaminated eye(s) with
lukewarm, gently flowing water until the product is removed or until a few minutes after irritation has ceased, while
holding the eyelid(s) open. Take care not to rinse contaminated water into the unaffected eye or onto the face. Obtain
medical advice if irritation becomes painful or lasts more than a few minutes.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
SECTION 5 - FIRE FIGHTING MEASURES
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
This product is likely to decompose only after heating to dryness, followed by further strong heating.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Does not burn.
Flash point:
Does not burn.
Upper Flammability Limit:
Does not burn.
Lower Flammability Limit:
Does not burn.
Autoignition temperature:
Does not burn.
Flammability Class:
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART A
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 3 of 5
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC, Viton, Nitrile. Eye/face protective equipment should comprise as a minimum, protective
glasses and, preferably, goggles. If there is a significant chance that vapours or mists are likely to build up in the
cleanup area, we recommend that you use a respirator. It should be fitted with a type A cartridge, suitable for organic
vapours.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area
preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.
This material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to
disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination
when sending contaminated clothing to laundry.
SECTION 7 - HANDLING AND STORAGE
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this class of poison. Protect this product from light. Store in the closed original container in a dry, cool, well-
ventilated area out of direct sunlight. Make sure that the product does not come into contact with substances listed
under "Materials to avoid" in Section 10. Some liquid preparations settle or separate on standing and may require
stirring before use. Check packaging - there may be further storage instructions on the label.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Triethanolamine 5 not set
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC, nitrile.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:
Clear, light amber liquid.
Physical Description & colour:
Mild amine odour.
Odour:
Approximately 100掳C at 100kPa.
Boiling Point:
Approximately 0掳C.
Freezing/Melting Point:
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART A
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 4 of 5
Water component.
Volatiles:
2.37 kPa at 20掳C (water vapour pressure).
Vapour Pressure:
No data.
Vapour Density:
1.1 approx
Specific Gravity:
Completely soluble in water.
Water Solubility:
8.8 approx
pH:
No data.
Volatility:
No data.
Odour Threshold:
No data.
Evaporation Rate:
No data
Coeff Oil/water distribution:
Does not burn.
Autoignition temp:
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-
ventilated area out of direct sunlight.
Incompatibilities: No particular Incompatibilities.
Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong
heating. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds,
and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur
dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide
poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment,
and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Local Effects:
There is no data to hand indicating any particular target organs.
Target Organs:
Classification of Hazardous Ingredients
Ingredient Risk Phrases
No ingredient mentioned in the List of Designated Hazardous Substances is present in this product at hazardous
concentrations.
SECTION 12 - ECOLOGICAL INFORMATION
Insufficient data to be sure of status.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal: Containers should be emptied as completely as practical before disposal. If possible, recycle containers
either in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. This
product should be suitable for landfill. However, check with local Waste Disposal Authority before sending there. Note
that product properties may have been changed in use, significantly altering it's suitability for landfill. Please do NOT
dispose into sewers or waterways. The use of a commercial waste disposal service is recommended for photographic
wastes as they may contain reclaimable silver or other ingredients which are not desirable in waste water streams.
SECTION 14 - TRANSPORT INFORMATION
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
SECTION 15 - REGULATORY INFORMATION
AICS: We are unable to verify the presence of all of the ingredients in this product on the public AICS database.
There are several possible reasons why this may occur. If you have any reason to be concerned about this, we
suggest you call us on the number below.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART A
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 5 of 5
The following ingredients: Triethanolamine, are mentioned in the SUSDP.
SECTION 16 - OTHER INFORMATION
This MSDS contains only safety-related information. For other data see product literature.
A more recent version of this MSDS might be found at http://www.fujifilm.com.au/
Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail
ADG Code
Australian Inventory of Chemical Substances
AICS
Chemical Abstracts Service Registry Number
CAS number
Emergency action code of numbers and letters that provide information to
Hazchem Number
emergency services especially firefighters
International Agency for Research on Cancer
IARC
National Occupational Health and Safety Commission
NOHSC
Not otherwise specified
NOS
National Toxicology Program (USA)
NTP
Risk Phrase
R-Phrase
Standard for the Uniform Scheduling of Drugs & Poisons
SUSDP
United Nations Number
UN Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND
HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, August, 2004.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART B
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 1 of 5
SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
FUJIFILM Australia Pty Ltd ABN 80 000 064 433 FUJIFILM (NZ) Limited
114 Old Pittwater Rd Cnr William Pickering Dr & Bush Rd
Brookvale NSW 2100 Albany, Auckland
Phone: 02 9466 2600 Fax: 02 9938 1975 Phone (09)414 0400
Emergency Information: (02)9466 2721 (Aust), (09)414 0400 (NZ) http://www.fujifilm.com.au/
Water solution of ingredients.
Substance:
CD 161 DEVELOPER REPLENISHER P1R PART B
Trade Name:
61020
Product Code:
Photographic developer replenisher for colour print paper in mini labs. Part B of a
Product Use:
three part system.
Creation Date: August, 2004
Revision Date: August, 2004
SECTION 2 - HAZARDS IDENTIFICATION
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R34, R38, R40, R41. Causes burns. Irritating to skin. Possible risk of irreversible effects. Risk of
serious damage to eyes.
Safety Phrases: S20, S23, S24, S26, S28, S38, S36/39. When using, do not eat or drink. Do not breathe vapours
or mists. Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and contact a
doctor or Poisons Information Centre. After contact with skin, wash immediately with plenty of soap and water. In case
of insufficient ventilation, wear suitable respiratory equipment. Wear suitable protective clothing and eye/face
protection.
SUSDP Classification: S6
ADG Classification: Class 8 (CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.)
UN Number: 3265
Emergency Overview
Physical Description & colour: Clear amber liquid.
Odour: Sulfurous odour.
Major Health Hazards: causes burns, may cause irreversible effects, may cause serious damage to eyes, skin
irritant.
Potential Health Effects
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this
product is not harmful. However product may be mildly irritating, although unlikely to cause anything more than mild
transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. However product is a severe skin
irritant. Symptoms may include extreme itchiness and reddening of contacted skin. Other symptoms such as blisters
may also become evident, and may last long after exposure has ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: Exposure via eyes is considered to be unlikely. This product is corrosive to eyes. It will
cause severe pain, and corrosion of the eye and surrounding facial tissues. Unless exposure is quickly treated,
permanent blindness and facial scarring is likely.
Long Term exposure: No data for health effects associated with long term eye exposure.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART B
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 2 of 5
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. However, this product is a severe oral
irritant. Symptoms may include extreme pain and reddening of skin in mouth and throat. Other symptoms such as
blisters may also become evident, and may last long after exposure has ceased.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3 3
Ingredients CAS No Conc,% TWA (mg/m ) STEL (mg/m )
P-phenylenediamine derivative 25646-71-3 25-30 not set not set
catechol derivative 149-45-1 1-3 not set not set
Water 7732-18-5 to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
SECTION 4 - FIRST AID MEASURES
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has
developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about
30 minutes, seek medical advice.
Skin Contact: Quickly and gently, blot or brush away excess chemical. Wash gently and thoroughly with water (use
non-abrasive soap if necessary) for 20 minutes or until product is removed. Under running water, remove
contaminated clothing, shoes and leather goods (e.g. watchbands and belts). Completely decontaminate clothing,
shoes and leather goods before reuse or discard. If irritation persists, repeat flushing and obtain medical advice.
Eye Contact: Quickly and gently, blot or brush away chemical. Immediately flush the contaminated eye(s) with
lukewarm, gently flowing water for at least 20-30 minutes, by the clock, while holding the eyelid(s) open. Neutral
saline solution may be used as soon as it is available. DO NOT INTERRUPT FLUSHING. If necessary, keep
emergency vehicle waiting (show paramedics this MSDS and take their advice). Take care not to rinse contaminated
water into the unaffected eye or onto face. If irritation persists, repeat flushing. Call a Poisons Information Centre or a
doctor urgently.
Ingestion: If swallowed, rinse mouth thoroughly with water and contact a Poisons Information Centre, or call a
doctor at once. Give activated charcoal if instructed.
SECTION 5 - FIRE FIGHTING MEASURES
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Only small quantities of decomposition products are expected from this products at temperatures normally achieved in
a fire. This will only occur after heating to dryness.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Water fog or fine
spray is the preferred medium for large fires. Ensure that no spillage enters drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Does not burn.
Flash point:
Does not burn.
Upper Flammability Limit:
Does not burn.
Lower Flammability Limit:
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART B
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 3 of 5
Does not burn.
Autoignition temperature:
Does not burn.
Flammability Class:
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate
the spill area and deny entry to unnecessary and unprotected personnel. Wear full protective chemically resistant
clothing including eye/face protection, gauntlets and self contained breathing apparatus. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
use a respirator. It should be fitted with a type A cartridge, suitable for organic vapours. Otherwise, not normally
necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Because of the corrosiveness of this product, special personal care should be taken in any cleanup
operation. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and
dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing
runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. This material
may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to disposal.
Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when
sending contaminated clothing to laundry.
SECTION 7 - HANDLING AND STORAGE
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Store in a cool, well ventilated area. Check containers periodically for corrosion and leaks. Containers
should be kept closed in order to minimise contamination. Make sure that the product does not come into contact with
substances listed under "Materials to avoid" in Section 10. If you keep more than 1000kg or 1000L of Corrosive
Substances of Packaging Group III, you will require a license to do so. If you have any doubts, we suggest you
contact your licensing authority in order to clarify your obligations. Check packaging - there may be further storage
instructions on the label.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Your eyes must be completely protected from this product by splash resistant goggles with face
shield. All surrounding skin areas must be covered. Emergency eye wash facilities must also be available in an area
close to where this product is being used.
Skin Protection: It is essential that all skin areas are adequately covered by impermeable gloves, overalls, hair
covering, apron and face shield. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above. Otherwise, not normally necessary.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART B
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 4 of 5
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:
Clear amber liquid.
Physical Description & colour:
Sulfurous odour.
Odour:
Approximately 100掳C at 100kPa.
Boiling Point:
Approximately 0掳C.
Freezing/Melting Point:
Water component.
Volatiles:
2.37 kPa at 20掳C (water vapour pressure).
Vapour Pressure:
No data.
Vapour Density:
1.12 approx
Specific Gravity:
Completely soluble in water.
Water Solubility:
<1
pH:
No data.
Volatility:
No data.
Odour Threshold:
No data.
Evaporation Rate:
No data
Coeff Oil/water distribution:
Does not burn.
Autoignition temp:
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: Most strong acids react with inorganic and organic bases such as amines to form salts. They also react
with many metals liberating hydrogen gas. These reactions are often rapid and sometimes liberate much heat. They
can also decompose many organic materials such as esters, in a reaction called hydrolysis.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Under no circumstances
should the container be sealed. Keep isolated from combustible materials.
Incompatibilities: bases, zinc, tin, aluminium and their alloys.
Fire Decomposition: Only small quantities of decomposition products are expected from this products at
temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if
combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some
circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur dioxide is a respiratory
hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces
headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and
unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Local Effects:
There is no data to hand indicating any particular target organs.
Target Organs:
Classification of Hazardous Ingredients
Ingredient Risk Phrases
No ingredient mentioned in the List of Designated Hazardous Substances is present in this product at hazardous
concentrations.
SECTION 12 - ECOLOGICAL INFORMATION
Insufficient data to be sure of status.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal: Containers should be emptied as completely as practical before disposal. If possible, recycle containers
either in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. Please
do NOT dispose into sewers or waterways. The use of a commercial waste disposal service is recommended for
photographic wastes as they may contain reclaimable silver or other ingredients which are not desirable in waste
water streams.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART B
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 5 of 5
SECTION 14 - TRANSPORT INFORMATION
ADG Code: 3265, CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazchem Code: 2X
Special Provisions: SP109, SP185, SP274
Dangerous Goods Class: Class 8, Corrosive Substances.
Packaging Group: III
Packaging Method: 3.8.8
Class 8 Corrosive Substances shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6
(Toxic Substances where the Toxic Substances are cyanides and the Corrosives are acids), 7 (Radioactive
Substances), Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the
same freight container with Classes 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Poisonous
Gases), 3 (Flammable liquids), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 6 (Toxic
Substances except where the Toxic Substances are cyanides and the Corrosives are acids) and 9 (Miscellaneous
Dangerous Goods).
SECTION 15 - REGULATORY INFORMATION
AICS: All of the significant ingredients in this formulation are to be found in the public AICS Database.
The following ingredient: P-phenylenediamine derivative is mentioned in the SUSDP.
SECTION 16 - OTHER INFORMATION
This MSDS contains only safety-related information. For other data see product literature.
A more recent version of this MSDS might be found at http://www.fujifilm.com.au/
Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail
ADG Code
Australian Inventory of Chemical Substances
AICS
Chemical Abstracts Service Registry Number
CAS number
Emergency action code of numbers and letters that provide information to
Hazchem Number
emergency services especially firefighters
International Agency for Research on Cancer
IARC
National Occupational Health and Safety Commission
NOHSC
Not otherwise specified
NOS
National Toxicology Program (USA)
NTP
Risk Phrase
R-Phrase
Standard for the Uniform Scheduling of Drugs & Poisons
SUSDP
United Nations Number
UN Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND
HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, August, 2004.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART C
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 1 of 5
SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
FUJIFILM Australia Pty Ltd ABN 80 000 064 433 FUJIFILM (NZ) Limited
114 Old Pittwater Rd Cnr William Pickering Dr & Bush Rd
Brookvale NSW 2100 Albany, Auckland
Phone: 02 9466 2600 Fax: 02 9938 1975 Phone (09)414 0400
Emergency Information: (02)9466 2721 (Aust), (09)414 0400 (NZ) http://www.fujifilm.com.au/
Water solution of ingredients.
Substance:
CD 161 DEVELOPER REPLENISHER P1R PART C
Trade Name:
61020
Product Code:
Photographic developer replenisher for colour print paper in mini labs. Part C of a
Product Use:
three part system.
Creation Date: August, 2004
Revision Date: August, 2004
SECTION 2 - HAZARDS IDENTIFICATION
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R34, R38, R41. Causes burns. Irritating to skin. Risk of serious damage to eyes.
Safety Phrases: S20, S24, S36, S46. When using, do not eat or drink. Avoid contact with skin. Wear suitable
protective clothing. If swallowed, contact a doctor or Poisons Information Centre immediately and show this container
or label.
SUSDP Classification: S5
ADG Classification: Class 8 (CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.)
UN Number: 3266
Emergency Overview
Physical Description & colour: Clear colourless liquid.
Odour: No odour.
Major Health Hazards: causes burns, may cause serious damage to eyes, skin irritant.
Potential Health Effects
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this
product is not harmful. In addition product is likely to cause discomfort or irritation if inhaled.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. However product is a severe skin
irritant. Symptoms may include extreme itchiness and reddening of contacted skin. Other symptoms such as blisters
may also become evident, and may last long after exposure has ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: Exposure via eyes is considered to be unlikely. This product is corrosive to eyes. It will
cause severe pain, and corrosion of the eye and surrounding facial tissues. Unless exposure is quickly treated,
permanent blindness and facial scarring is likely.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. However, this product is corrosive to
the gastrointestinal tract. Capable of causing moderate to severe burns with ulceration. Can penetrate to deeper
layers of skin, resulting in third degree burns. Corrosion will continue until product is removed or neutralised. Severity
depends on concentration and duration of exposure.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART C
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 2 of 5
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3 3
Ingredients CAS No Conc,% TWA (mg/m ) STEL (mg/m )
Potassium carbonate 584-08-7 30-35 not set not set
Potassium hydroxide 1310-58-3 1-5 2 Peak
Aminopolycarboxylic acid derivative 7379-27-3 5-10 not set not set
Water 7732-18-5 to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
SECTION 4 - FIRST AID MEASURES
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Quickly and gently, blot or brush away excess chemical. Wash gently and thoroughly with water (use
non-abrasive soap if necessary) for 20 minutes or until product is removed. Under running water, remove
contaminated clothing, shoes and leather goods (e.g. watchbands and belts). Completely decontaminate clothing,
shoes and leather goods before reuse or discard. If irritation persists, repeat flushing and obtain medical advice.
Eye Contact: Quickly and gently, blot or brush away chemical. Immediately flush the contaminated eye(s) with
lukewarm, gently flowing water for at least 20-30 minutes, by the clock, while holding the eyelid(s) open. Neutral
saline solution may be used as soon as it is available. DO NOT INTERRUPT FLUSHING. If necessary, keep
emergency vehicle waiting (show paramedics this MSDS and take their advice). Take care not to rinse contaminated
water into the unaffected eye or onto face. If irritation persists, repeat flushing. Call a Poisons Information Centre or a
doctor urgently.
Ingestion: If swallowed, rinse mouth thoroughly with water and contact a Poisons Information Centre. Urgent
hospital treatment is likely to be needed. Give activated charcoal if instructed.
SECTION 5 - FIRE FIGHTING MEASURES
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
This product is likely to decompose only after heating to dryness, followed by further strong heating.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Water fog or fine
spray is the preferred medium for large fires. Ensure that no spillage enters drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Does not burn.
Flash point:
Does not burn.
Upper Flammability Limit:
Does not burn.
Lower Flammability Limit:
Does not burn.
Autoignition temperature:
Does not burn.
Flammability Class:
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate
the spill area and deny entry to unnecessary and unprotected personnel. Wear full protective chemically resistant
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART C
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 3 of 5
clothing including eye/face protection, gauntlets and self contained breathing apparatus. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, Viton, Nitrile, butyl rubber, Barricade, neoprene, Teflon, polyethylene, PE/EVAL, Saranex,
Responder. Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant
chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator.
Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian
Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Because of the corrosiveness of this product, special personal care should be taken in any cleanup
operation. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and
dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing
runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.
Contaminated area may be neutralised by washing with weak or dilute acid. Vinegar, citrus juice and most soft drinks
may be suitable. This material may be suitable for approved landfill. Ensure legality of disposal by consulting
regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature
of contamination when sending contaminated clothing to laundry.
SECTION 7 - HANDLING AND STORAGE
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this class of poison. Store in a cool, well ventilated area. Check containers periodically for corrosion and leaks.
Containers should be kept closed in order to minimise contamination. Make sure that the product does not come into
contact with substances listed under "Materials to avoid" in Section 10. If you keep more than 1000kg or 1000L of
Corrosive Substances of Packaging Group III, you will require a license to do so. If you have any doubts, we suggest
you contact your licensing authority in order to clarify your obligations. Check packaging - there may be further
storage instructions on the label.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Potassium hydroxide 2 Peak
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Your eyes must be completely protected from this product by splash resistant goggles with face
shield. All surrounding skin areas must be covered. Emergency eye wash facilities must also be available in an area
close to where this product is being used.
Skin Protection: It is essential that all skin areas are adequately covered by impermeable gloves, overalls, hair
covering, apron and face shield. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
Viton, nitrile, butyl rubber, Barricade, neoprene, Teflon, polyethylene, PE/EVAL, Saranex, Responder.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:
Clear colourless liquid.
Physical Description & colour:
No odour.
Odour:
Approximately 100掳C at 100kPa.
Boiling Point:
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART C
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 4 of 5
Approximately 0掳C.
Freezing/Melting Point:
Water component.
Volatiles:
2.37 kPa at 20掳C (water vapour pressure).
Vapour Pressure:
No data.
Vapour Density:
1.43
Specific Gravity:
Completely soluble in water.
Water Solubility:
Corrosive. pH about 14
pH:
No data.
Volatility:
No data.
Odour Threshold:
No data.
Evaporation Rate:
No data
Coeff Oil/water distribution:
Does not burn.
Autoignition temp:
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: Most strong alkalis and bases react with inorganic and organic acids to form salts. They can also react
with some metals liberating hydrogen gas. These reactions may be rapid and sometimes liberate much heat. They
can also decompose many organic materials such as esters, in a reaction called hydrolysis.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Under no circumstances
should the container be sealed. Keep isolated from combustible materials. Store in the closed original container in a
dry, cool, well-ventilated area out of direct sunlight.
Incompatibilities: acids, zinc, tin, aluminium and their alloys.
Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong
heating. Carbon dioxide, usually without carbon monoxide and smoke. potassium compounds.
Polymerisation: This product will not undergo polymerisation reactions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Local Effects:
There is no data to hand indicating any particular target organs.
Target Organs:
Classification of Hazardous Ingredients
Ingredient Risk Phrases
Potassium Hydroxide 鈮?0.5%Conc鈮?2%: Xi; R36/38
SECTION 12 - ECOLOGICAL INFORMATION
Insufficient data to be sure of status.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal: Containers should be emptied as completely as practical before disposal. If possible, recycle containers
either in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. Please
do NOT dispose into sewers or waterways. The use of a commercial waste disposal service is recommended for
photographic wastes as they may contain reclaimable silver or other ingredients which are not desirable in waste
water streams.
SECTION 14 - TRANSPORT INFORMATION
ADG Code: 3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
Hazchem Code: 2X
Special Provisions: SP109, SP185, SP274
Dangerous Goods Class: Class 8, Corrosive Substances.
Packaging Group: III
Packaging Method: 3.8.8
Class 8 Corrosive Substances shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6
(Toxic Substances where the Toxic Substances are cyanides and the Corrosives are acids), 7 (Radioactive
Substances), Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Product Name: CD 161 DEVELOPER REPLENISHER P1R PART C
This revision issued: August, 2004
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 5 of 5
same freight container with Classes 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Poisonous
Gases), 3 (Flammable liquids), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 6 (Toxic
Substances except where the Toxic Substances are cyanides and the Corrosives are acids) and 9 (Miscellaneous
Dangerous Goods).
SECTION 15 - REGULATORY INFORMATION
AICS: All of the significant ingredients in this formulation are to be found in the public AICS Database.
The following ingredients: Potassium carbonate, Potassium hydroxide, are mentioned in the SUSDP.
SECTION 16 - OTHER INFORMATION
This MSDS contains only safety-related information. For other data see product literature.
A more recent version of this MSDS might be found at http://www.fujifilm.com.au/
Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail
ADG Code
Australian Inventory of Chemical Substances
AICS
Chemical Abstracts Service Registry Number
CAS number
Emergency action code of numbers and letters that provide information to
Hazchem Number
emergency services especially firefighters
International Agency for Research on Cancer
IARC
National Occupational Health and Safety Commission
NOHSC
Not otherwise specified
NOS
National Toxicology Program (USA)
NTP
Risk Phrase
R-Phrase
Standard for the Uniform Scheduling of Drugs & Poisons
SUSDP
United Nations Number
UN Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND
HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, August, 2004.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
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