Vantico A&T US Inc.
4917 Dawn Avenue
East Lansing, MI 48823-5691
8am to 4:30pm Phone: (517) 351-5900
24-Hour Health/Environmental Emergency Phone: 1-888-354-3323
MSDS No: 30977
Effective Date: 9/4/02 Material Safety Data Sheet
Health 3
1. PRODUCT IDENTIFICATION 1
Flammability 1
3 0
Reactivity 0
Trade Name: Hardener HW 8685
Protective Equipment
Chemical Family: Polyol
HMIS RATING
NFPA RATING
Synonyms:
LSA 623-93 Hardener
Intended Use or Product Type:
Polyurethane Adhesive Hardener.
2. COMPOSITION / INFORMATION ON INGREDIENTS
O CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN
S STATUS
H ACGIH OSHA MFR. IARC NTP OSHA
A TWA STEL PEL STEL
* 1333-86-4 Carbon Black 3.5 NE 3.5 NE NE Yes NR NR
mg/m3 mg/m3
Common Carbon black
Name:
* 3077-13-2 2-Propanol-1,1'-(phenylamino)bis NE NE NE NE NE NR NR NR
Common 2-Hydroxypropyl aniline
Name:
* 694-83-7 1,2-Cyclohexanediamine NE NE NE NE NE NR NR NR
Common 1,2-Diaminocyclohexane
Name:
94-96-2 2-Ethyl-1,3-hexanediol NE NE NE NE NE NR NR NR
Common 2-Ethyl-1,3-hexanediol
Name:
* = OSHA Hazardous Ingredient
3. HAZARDS IDENTIFICATION
Emergency Overview: Corrosive - Causes eye burns and skin irritation.
Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.
Printed: 2/19/2003 Page 1 of 5
Hardener HW 8685 Vantico A&T US Inc.
Effective Date: 9/4/02
Carcinogenicity (NTP, IARC, OSHA): This product contains carbon black which is classified as a carcinogen by IARC (2B,
possibly carcinogenic to humans) and NIOSH.
4. FIRST AID MEASURES
Ingestion: If conscious, give 2 - 4 glasses of water to drink. Do not induce vomiting. Call a physician.
Skin: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy contaminated
shoes.
Inhalation: Remove to fresh air. Call a physician.
Eyes: Immediately flush eyes with water for at least 15 minutes. Call a physician.
Overexposure Effects: Corrosive - causes eye burns. Causes skin irritation.
Medical Conditions Aggravated by Exposure: Skin and eye conditions.
Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.
5. FIRE FIGHTING MEASURES
205掳F (96 掳C)
Flash Point:
PMCC
Flash Point Method Used:
Not established
Flammable Limits in Air (Lower - % by volume):
Not established
Flammable Limits in Air (Upper - % by volume):
Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
Fire Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
6. ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Remove spillage by absorbing in absorbent material.
7. HANDLING AND STORAGE
Signal Word: Danger!
Precautions: Corrosive - causes eye burns. Can cause skin irritation. Do not get in eyes. Avoid breathing vapor or mist. Avoid
contact with skin and clothing. Keep container closed when not in use. Use with adequate ventilation. Wash thoroughly after
handling.
Other Handling Information: Nuisance dust may be generated when sanding or sawing cured material.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Printed: 2/19/2003 Page 2 of 5
Hardener HW 8685 Vantico A&T US Inc.
Effective Date: 9/4/02
Skin Protection: Wear impermeable gloves.
Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.
Eye Protection: Wear splash-proof chemical goggles.
Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.
9. PHYSICAL AND CHEMICAL PROPERTIES
Black
Color:
Mild
Odor:
Liquid
Physical State:
Slight
Solubility in Water:
psi Not Determined
Vapor Pressure:
1.3 (water = 1)
Specific Gravity:
Not Determined
Boiling Point:
Not Determined
Evaporation Rate:
Not Determined
Vapor Density:
Not Determined
pH:
Percent Volatile: Negligible.
10. STABILITY AND REACTIVITY
Conditions to Avoid: Excessive heat for prolonged periods of time.
Stability: Stable.
Incompatibility: Strong oxidizers, acids and bases.
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Carcinogenicity: This product contains carbon black which is classified as a carcinogen by IARC (2B, possibly carcinogenic to
humans) and NIOSH.
Skin Irritation: Irritant.
Eye Irritation: Corrosive. Causes burns.
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
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Hardener HW 8685 Vantico A&T US Inc.
Effective Date: 9/4/02
Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.
Additional Information: Disposal of Cured Product: This product when cured may contain very small quantities of organic
mercury compounds. It is the responsibility of the user to determine if the selected disposal method complies with applicable
regulations.
14. TRANSPORT INFORMATION
DOT: Non-Bulk
Resin compounds, N.O.I.
Proper Shipping Name:
Department of Transportation: Not regulated as a hazardous material by the U.S. Dept. of Transportation (DOT) 49 CFR
172.101 hazardous materials table.
15. REGULATORY INFORMATION
US Federal Regulations:
Occupational Safety and Health Act (OSHA): This product is considered to be a hazardous chemical under the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
Resource Conservation and Recovery Act (RCRA): D 009 contains mercury.
SARA Title III: Section 313 Toxic Chemical List (TCL): This product does not contain any chemicals for routine annual toxic
chemical release reporting under Section 313 (40 CFR 372).
TSCA Section 8(b) - Inventory Status: Chemical components listed on TSCA Inventory.
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification.
State Regulations:
Pennsylvania Right-to-Know: The following is required composition information:
Chemical Name: Homopolymer, hydroxy terminated 1,3-butadiene
Common Name: Polybutadiene polyol
CAS Number: 69102-90-5
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Limestone
Common Name: Calcium Carbonate
CAS Number: 1317-65-3
Comment: Hazardous Substance
Chemical Name: Calcium Metasilicate
Common Name: Wollastonite
CAS Number: 13983-17-0
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Hardener HW 8685 Vantico A&T US Inc.
Effective Date: 9/4/02
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 2-Propanol-1,1'-(phenylamino)bis
Common Name: 2-Hydroxypropyl aniline
CAS Number: 3077-13-2
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: 2-Ethyl-1,3-hexanediol
Common Name: 2-Ethyl-1,3-hexanediol
CAS Number: 94-96-2
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Terphenyl, Hydrogenated
Common Name: Plasticizer
CAS Number: 61788-32-7
Comment: Hazardous Substance
16. OTHER INFORMATION
30977
MSDS No:
Kenneth L. Payne
Approved By:
E,H&S Manager
Title:
Disclaimer: The following supercedes Buyer鈥檚 documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESS OR IMPLIED, INCLUDING OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No
statements herein are to be construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be liable
for incidental, consequential or indirect damages for alleged negligence, breach of warranty, strict liability, tort or contract arising
in connection with the product(s). Buyer鈥檚 sole remedy and Seller鈥檚 sole liability for any claims shall be Buyer鈥檚 purchase price.
Data and results are based on controlled or lab work and must be confirmed by Buyer by testing for its intended conditions of use.
The product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged contact with mucous
membranes, abraded skin, or blood is intended; or for uses for which implantation within the human body is intended.
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