Huntsman Advanced Materials Americas Inc.
Distributed by Freeman Mfg & Supply Co.
800.321.8511 www.freemansupply.com
24-Hour Emergency Phone: (800) 328-8501
MSDS No: 5657
Effective Date: 5/17/07 Material Safety Data Sheet
Health: 3
1. PRODUCT IDENTIFICATION 1
Flammability: 1
3 2
Reactivity: 2
Trade Name: Hardener HV 1258
Personal Protection:
Chemical Family: Amine
HMIS RATING
NFPA RATING
Synonyms:
RP 1258 HARDENER
Intended Use or Product Type: Adhesive hardener
2. COMPOSITION / INFORMATION ON INGREDIENTS
O CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN
S STATUS
H ACGIH OSHA MFR. IARC NTP OSHA
A TWA STEL PEL STEL
* 111-40-0 1,2-Ethanediamine, N-(2- 1 ppm NE NE NE NE NR NR NR
aminoethyl)-
Common Diethylenetriamine
Name:
Concentration 3.00 - 7.00 % by wt
* 112-24-3 1,2-Ethanediamine, N,N'-bis(2- NE NE NE NE NE NR NR NR
aminoethyl)-
Common Triethylenetetramine
Name:
Concentration 0.50 - 1.50 % by wt
* 1333-86-4 Carbon Black 3.5 NE 3.5 NE NE Yes NR NR
mg/m3 mg/m3
Common Carbon black
Name:
Concentration 0.10 - 1.00 % by wt
* 14808-60-7 Quartz (SiO2) 0.05 NE 0.1 NE NE Yes Yes NR
mg/m3 mg/m3
Common Crystalline silica
Name:
Concentration 0.10 - 1.00 % by wt
* 25154-52-3 Phenol, Nonyl- NE NE NE NE NE NR NR NR
Common Nonyl Phenol
Name:
Concentration 7.00 - 13.00 % by wt
* 68410-23-1 Fatty acids, C18-unsatd., dimers, NE NE NE NE NE NR NR NR
reaction products with
polyethylenepolyamines
Printed: 6/15/2007 Page 1 of 7
Hardener HV 1258 Huntsman Advanced Materials
Effective Date: 5/17/07 Americas Inc. (EL)
Common Polyamide Resin
Name:
Concentration 7.00 - 13.00 % by wt
* 80-05-7 Phenol, 4,4'-(1- NE NE NE NE NR NR NR
TLV 5
methylethylidene)bis- mg/m3
Common Bisphenol A
Name:
Concentration 1.00 - 5.00 % by wt
* = OSHA Hazardous Ingredient
3. HAZARDS IDENTIFICATION
Emergency Overview: Corrosive - Causes skin and eye burns. Harmful if absorbed through skin. May cause allergic skin and
respiratory reactions.
Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.
Carcinogenicity (NTP, IARC, OSHA): This product contains carbon black which is classified as a carcinogen by IARC (2B,
possibly carcinogenic to humans) and NIOSH.
Chronic: Contains crystalline silica. Breathing dust may cause cancer and delayed lung injury. Overexposure may have effects on
developing fetus, kidney, liver, and brain.
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Seek immediate medical attention.
Skin: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy contaminated
shoes. Seek immediate medical attention.
Inhalation: Remove to fresh air. Seek immediate medical attention.
Eyes: Immediately flush eyes with water for at least 15 minutes. Seek immediate medical attention.
Overexposure Effects: Corrosive - causes eye burns. Causes severe skin irritation and may cause skin burns. Can cause allergic
respiratory reaction and allergic skin reaction. Harmful if absorbed through skin.
Medical Conditions Aggravated by Exposure: Skin, eye and pulmonary conditions.
Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.
5. FIRE FIGHTING MEASURES
239掳F ( 115 掳C)
Flash Point:
PMCC
Flash Point Method Used:
Not established
Flammable Limits in Air (Lower - % by volume):
Printed: 6/15/2007 Page 2 of 7
Hardener HV 1258 Huntsman Advanced Materials
Effective Date: 5/17/07 Americas Inc. (EL)
Not established
Flammable Limits in Air (Upper - % by volume):
Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
Fire Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
6. ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Remove spillage by absorbing in absorbent material.
7. HANDLING AND STORAGE
Signal Word: Danger!
Precautions: Corrosive - causes eye burns. Causes severe skin irritation and may cause skin burns. Can cause allergic respiratory
reaction and allergic skin reaction. Can be harmful if absorbed through skin and may be harmful if swallowed. Do not get in eyes,
on skin, or on clothing. Avoid breathing vapor or mist. Avoid tasting or swallowing. Keep container closed when not in use. Use
with adequate ventilation. Wash thoroughly after handling. Notice! Contains crystalline silica. Breathing dust may cause cancer
and delayed lung injury. Overexposure may have effects on developing fetus, kidney, liver, and brain.
Other Handling Information: Crystalline silica may be generated when machining cured products. Overexposure may create
possible cancer and silicosis hazard.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Skin Protection: Wear impermeable gloves.
Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.
Eye Protection: Wear splash-proof chemical goggles.
Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.
9. PHYSICAL AND CHEMICAL PROPERTIES
Dark Grey
Color:
Slight Ammoniacal
Odor:
Paste
Physical State:
Slight
Solubility in Water:
1.13 mm Hg at 52掳C (126 掳F)
Vapor Pressure:
1.6 - 1.66 (water = 1)
Specific Gravity:
> 450掳F (> 232 掳C)
Boiling Point:
Not Determined
Evaporation Rate:
Not Determined
Vapor Density:
108.721 g/L
VOC:
Not Determined
pH:
Printed: 6/15/2007 Page 3 of 7
Hardener HV 1258 Huntsman Advanced Materials
Effective Date: 5/17/07 Americas Inc. (EL)
Percent Volatile: Not determined.
10. STABILITY AND REACTIVITY
Conditions to Avoid: Excessive heat for prolonged periods of time.
Stability: Stable.
Incompatibility: Strong oxidizers, acids and bases.
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Oral Effects (LD50): Component(s) are slightly toxic, 500 - 5000 mg/kg (rat).
Diethylenetriamine= 1080 - 2330 mg/kg (rat)
Acute Dermal Toxicity (LD50): Component(s) are toxic, 200 - 1000 mg/kg (rabbit).
Diethylenetriamine= 672 - 1240 mg/kg (rabbit)
Sensitization: Causes allergic skin and respiratory sensitivity in some people.
Carcinogenicity: This product contains crystalline silica. Repeated inhalation of respirable free crystalline silica dust may cause
delayed lung injury (silicosis) and cancer. This product contains carbon black which is classified as a carcinogen by IARC (2B,
possibly carcinogenic to humans) and NIOSH.
Skin Irritation: Severe skin irritant.
Eye Irritation: Corrosive. Causes burns.
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.
14. TRANSPORT INFORMATION
DOT: Non-Bulk
Not Regulated
Proper Shipping Name:
IATA: Non-Bulk
Not Regulated
Proper Shipping Name:
IMDG: Non-Bulk
Not Regulated
Proper Shipping Name:
TDG: Non-Bulk
Not Regulated
Proper Shipping Name:
Printed: 6/15/2007 Page 4 of 7
Hardener HV 1258 Huntsman Advanced Materials
Effective Date: 5/17/07 Americas Inc. (EL)
15. REGULATORY INFORMATION
US Federal Regulations:
Occupational Safety and Health Act (OSHA): This Material Safety Data Sheet (MSDS) has been prepared in compliance with
the federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous chemical
under that standard.
Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CFR 261).
SARA Title III: Section 313 Toxic Chemical List (TCL): This product contains a toxic chemical(s) for routine annual toxic
chemical release reporting under section 313 (40 CFR 372). This information must be included in all MSDS's copied or distributed
for this material.
Chemical Name: Aluminum
Percent in Composition: 30 % by wt
Comment:
Chemical Name: Phenol, 4,4'-(1-methylethylidene)bis-
Common Name: Bisphenol A
Percent in Composition: 1 - 5 % by wt
Comment:
TSCA Section 8(b) - Inventory Status: All chemical components of this product are in compliance with TSCA inventory
requirements.
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b)
export notification.
International Regulations:
Canadian Inventory Status: This product contains components which are included on the Domestic Substances List (DSL) and
the Non-Domestic Substances List (NDSL).
Canadian WHMIS: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations. D1B D2A D2B
State Regulations:
California Proposition 65: The following is required composition information. This product contains the following chemical(s)
which are currently listed on the California list of Known Carcinogens and Reproductive Toxins:
Chemical Name: Quartz (SiO2)
Common Name: Crystalline silica
CAS Number: 14808-60-7
Percent in Composition: 0.1 - 1 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Chemical Name: Formaldehyde
Common Name: Formaldehyde
Printed: 6/15/2007 Page 5 of 7
Hardener HV 1258 Huntsman Advanced Materials
Effective Date: 5/17/07 Americas Inc. (EL)
CAS Number: 50-00-0
Percent in Composition: 0.0001 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer.
Chemical Name: Arsenic
CAS Number: 7440-38-2
Percent in Composition: 0 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer and birth defects or other reproductive
harm.
Chemical Name: Lead
CAS Number: 7439-92-1
Percent in Composition: 0 % by wt
Comment: Warning! This chemical is known to the State of California to cause cancer and birth defects or other reproductive
harm.
Pennsylvania Right-to-Know: The following is required composition information:
Chemical Name: Aluminum
CAS Number: 7429-90-5
Comment: Environmental Hazardous Substance
Chemical Name: Limestone
Common Name: Calcium carbonate
CAS Number: 1317-65-3
Comment: Hazardous Substance
Chemical Name: Aluminum hydroxide
Common Name: Hydrated Alumina
CAS Number: 21645-51-2
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines
Common Name: Polyamide Resin
CAS Number: 68410-23-1
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Phenol, Nonyl-
Common Name: Nonyl Phenol
CAS Number: 25154-52-3
Comment: Hazardous Substance
Chemical Name: 1,2-Ethanediamine, N-(2-aminoethyl)-
Common Name: Diethylenetriamine
CAS Number: 111-40-0
Comment: Hazardous Substance
Chemical Name: Phenol, 4,4'-(1-methylethylidene)bis-
Common Name: Bisphenol A
CAS Number: 80-05-7
Comment: Environmental Hazardous Substance
Chemical Name: Silica
Common Name: Fumed Silica
Printed: 6/15/2007 Page 6 of 7
Hardener HV 1258 Huntsman Advanced Materials
Effective Date: 5/17/07 Americas Inc. (EL)
CAS Number: 7631-86-9
Comment: Hazardous Substance
16. OTHER INFORMATION
5657
MSDS No:
Dianne Blessing
Approved By:
EH&S Specialist
Title:
Disclaimer: The information and recommendations contained herein are based upon tests in controlled laboratory conditions, are
believed to be correct, and are provided for the sole purpose of hazard communication as part of Huntsman's product safety
program. This product has not been tested for, and therefore is not recommended or suitable for, uses for which prolonged contact
with mucous membranes, abraded skin, or blood is intended or likely, or for uses for which implantation within the human body is
intended, and Huntsman assumes no liability for any such uses.
The information and recommendations contained herein are not intended to constitute performance information concerning the
product, which is available in separate technical data sheets available from Huntsman upon request. Users are urged, and are urged
to urge others who may come in contact with the product, to obtain and consult data sheets prior to purchase, use, transportation or
storage of the product.
HUNTSMAN MAKES NO REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY, QUALITY, OR FITNESS FOR A PARTICULAR PURPOSE. HUNTSMAN'S LIABILITY IS
STRICTLY LIMITED TO REIMBURSEMENT OF BUYER'S PURCHASE PRICE, OR IN HUNTSMAN'S DISCRETION
REPLACEMENT, OF THE PRODUCT IN RESPECT OF WHICH SUCH CLAIM IS MADE. HUNTSMAN'S LIABILITY IS
STRICTLY LIMITED BY LEGAL NOTICES IN TECHNICAL DATA SHEETS, PRODUCT LITERATURE, AND/OR SALE
DOCUMENTS. The foregoing DISCLAIMERS and LIMITATION OF LIABILITY supercede inconsistent or contradictory
provisions in Buyer's documents.
USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENTAL AGENCY TO DETERMINE
THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT. HUNTSMAN
DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO
PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM
UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO
PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS,
WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE
MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT
THE ABOVE ADDRESS.
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