MATERIAL SAFETY DATA SHEET
200000436/F/USA
Approval Date: 01/21/2004
Print Date: 07/11/2005
Page: 1/10
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: KODAK T-MAX RS Developer and Replenisher
Catalog Number(s): 844 6163 - To Make 1 gallon (U.S.)
825 4237 - To Make 10 gallon (U.S.)
Manufacturer/Supplier: EASTMAN KODAK COMPANY, Rochester, New York 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151
For other information or to request an MSDS, call (800) 242-2424.
Synonym(s): Part A: KAN 448049; PCD 5492; C-0144.040
Part B: KAN 448050; PCD 5506; C-0144.050
Working solution: KAN 471327; C-0144.055
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2. COMPOSITION/INFORMATION ON INGREDIENTS
Weight % - Component - (CAS Registry No.)
Part A:
50-55 Diethanolamine-sulfur dioxide complex (063149-47-3)
40-45 Water (007732-18-5)
5 Hydroquinone (000123-31-9)
1-5 Sodium bisulfite (007631-90-5)
<1 Pentetic acid, pentasodium salt (000140-01-2)
<1 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (013047-13-7)
Part B:
95-99 Diethylene glycol (000111-46-6)
1-5 Acetic acid (000064-19-7)
<1 1,4-diphenyl-3-(phenylamino)-1H-1,2,4-triazolium hydroxide
(002218-94-2)
Working solution:
80-90 Water (007732-18-5)
10-20 Diethanolamine-sulfur dioxide complex (063149-47-3)
1-5 Hydroquinone (000123-31-9)
<1 Sodium bisulfite (007631-90-5)
<1 Diethylene glycol (000111-46-6)
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3. HAZARDS IDENTIFICATION
Part A:
CONTAINS: Diethanolamine-sulfur dioxide complex (063149-47-3), Hydroquinone
(000123-31-9), Sodium bisulfite (007631-90-5),
4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (013047-13-7)
WARNING!
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HEAT SENSITIVE - CAN DECOMPOSE IF HEATED
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
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HMIS Hazard Ratings:
Health - * 2, Flammability - 1, Reactivity - 1, Personal Protection - B
NFPA Hazard Ratings:
Health - 1, Flammability - 1, Reactivity (Stability) - 1
Part B:
CONTAINS: Diethylene glycol (000111-46-6), Acetic acid (000064-19-7),
1,4-diphenyl-3-(phenylamino)-1H-1,2,4-triazolium hydroxide (002218-94-2)
WARNING!
HARMFUL IF SWALLOWED
CAN CAUSE KIDNEY DAMAGE AND CNS EFFECTS FOLLOWING INGESTION
CAUSES EYE IRRITATION
MAY FORM EXPLOSIVE PEROXIDES
HMIS Hazard Ratings:
Health - * 2, Flammability - 1, Reactivity - 0, Personal Protection - B
NFPA Hazard Ratings:
Health - 1, Flammability - 1, Reactivity (Stability) - 0
Working solution:
CONTAINS: Diethanolamine-sulfur dioxide complex (063149-47-3), Hydroquinone
(000123-31-9), Sodium bisulfite (007631-90-5)
WARNING!
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HMIS Hazard Ratings:
Health - * 2, Flammability - 1, Reactivity - 0, Personal Protection - B
NFPA Hazard Ratings:
Health - 1, Flammability - 1, Reactivity (Stability) - 0
NOTE: HMIS and NFPA hazard indexes involve data review and interpretation that
may vary among companies. They are intended only for rapid, general
identification of the magnitude of the potential hazards. The personal
protection index is only intended for general guidance on personal protection
equipment (PPE) that is suitable for the potential hazards of the material.
PPE (e.g., respirators) may not be needed if engineering controls (e.g., local
ventilation) are adequate. An asterisk (*), in the HMIS health field,
designates potential chronic or target organ hazards. To adequately address
safe handling, ALL information in this MSDS must be considered.
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4. FIRST-AID MEASURES
Inhalation: If symptomatic, move to fresh air. Treat symptomatically. Get
medical attention if symptoms persist.
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get
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Print Date: 07/11/2005
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medical attention if symptoms occur.
Skin:
Part A & Working solution: Immediately flush with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes. If skin
irritation or an allergic skin reaction develops, get medical attention.
Wash contaminated clothing before reuse. Destroy or thoroughly clean
contaminated shoes.
Part B: Wash with soap and water. Get medical attention if symptoms occur.
Wash contaminated clothing before reuse. Destroy or thoroughly clean
contaminated shoes.
Ingestion: Only induce vomiting at the instruction of medical personnel. Never
give anything by mouth to an unconscious person. Call a physician or poison
control center immediately.
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5. FIRE FIGHTING MEASURES
Extinguishing Media: Water spray, carbon dioxide (CO2), dry chemical, alcohol
foam
Special Fire-Fighting Procedures:
Part A: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products. Use
water spray to keep fire-exposed containers cool.
Part B: Wear self-contained breathing apparatus and protective clothing.
Working solution: Wear self-contained breathing apparatus and protective
clothing. Fire or excessive heat may produce hazardous decomposition
products.
Hazardous Combustion Products:
Part A & Working solution: Carbon dioxide, carbon monoxide, oxides of
sulfur, oxides of nitrogen.
Part B: Carbon dioxide, carbon monoxide
Unusual Fire and Explosion Hazards:
Part A: Elevated temperature can cause decomposition.
Part B: Forms peroxides of unknown stability.
Working solution: None
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6. ACCIDENTAL RELEASE MEASURES
Flush to sewer with large amounts of water. Otherwise, absorb spill with
vermiculite or other inert material, then place in a container for chemical
waste. Clean surface thoroughly to remove residual contamination.
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MATERIAL SAFETY DATA SHEET
200000436/F/USA
Approval Date: 01/21/2004
Print Date: 07/11/2005
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7. HANDLING AND STORAGE
Personal Precautionary Measures:
Part A & Working solution: Avoid breathing mist or vapor. Avoid contact with
eyes, skin, and clothing. Use with adequate ventilation. Wash thoroughly
after handling.
Part B: Avoid prolonged or repeated breathing of mist or vapor. Avoid
contact with eyes and prolonged or repeated contact with skin. Use with
adequate ventilation. Wash thoroughly after handling.
Prevention of Fire and Explosion:
Part A: Keep from contact with oxidizing materials. Keep away from heat.
Part B: Keep from contact with oxidizing materials. Minimize exposure to
air. If peroxide formation is suspected, do not open or move container. Do
not distill or allow to evaporate to near dryness. After opening, purge
container with nitrogen before reclosing. Periodically test for peroxide
formation on long-term storage. Addition of water or appropriate reducing
materials will lessen peroxide formation.
Working solution: Keep from contact with oxidizing materials.
Storage:
Part A: Keep container closed. Store in a cool place.
Part B: Keep container closed. Store away from heat and light.
Working solution: Keep container closed.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits:
ACGIH Threshold Limit Value (TLV):
Acetic acid: 10 ppm TWA, 15 ppm STEL
Hydroquinone: 2 mg/m3 TWA
Sodium bisulfite: 5 mg/m3 TWA
OSHA (USA) Permissible Exposure Limit (PEL - 1971 Table Z-1 Values):
Acetic acid: 10 ppm TWA; 25 mg/m3 TWA
Hydroquinone: 2 mg/m3 TWA
AIHA Workplace Environmental Exposure Level (WEEL):
Diethylene glycol: 10 mg/m3
Ventilation: Good general ventilation (typically 10 air changes per hour)
should be used. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory
protection may be needed in special circumstances such as poorly ventilated
spaces, evaporation from large surfaces, spraying, heating, etc.
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Respiratory Protection:
Part A & Working solution: None should be needed. A respirator should be
worn if hazardous decomposition products are likely to be or have been
released. Respirator type: Acid gas. See Stability and Reactivity Section.
If respirators are used, a program should be instituted to assure compliance
with OSHA Standard 29 CFR 1910.134.
Part B: None should be needed. If engineering controls do not maintain
airborne concentrations below recommended exposure limits, an approved
respirator must be worn. Respirator type: full-face organic vapor cartridge
If respirators are used, a program should be instituted to assure compliance
with OSHA Standard 29 CFR 1910.134.
Eye Protection: Wear safety glasses with side shields (or goggles).
Skin Protection:
Part A, B & Working solution: Wear impervious gloves and protective clothing
appropriate for the risk of exposure.
Recommended Decontamination Facilities: Eye bath, safety shower, washing
facilities
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9. PHYSICAL AND CHEMICAL PROPERTIES
Part A Part B Working solution
Physical Form: liquid liquid liquid
Color: tan amber colorless
Odor: amine vinegar amine
Specific Gravity (water 1.21 1.12 1.04
= 1):
Vapor Pressure at 20掳C 24 mbar 24 mbar 24 mbar
(68掳F): (18 mm Hg) (18 mm Hg) (18 mm Hg)
Vapor Density (Air = 0.6 0.6 0.6
1):
Volatile Fraction by > 40% < 5% > 80%
Weight:
Boiling Point: >100掳C (>212掳F) >100掳C (>212掳F) >100掳C (>212掳F)
Solubility in Water: complete complete complete
pH: 8.9 not available 8.4-8.6
Flash Point: none >93掳C (>200掳F) none
(estimated)
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10. STABILITY AND REACTIVITY
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200000436/F/USA
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Print Date: 07/11/2005
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Stability:
Part A: Stable. Safe handling temperatures are dependent on specific
conditions of use and are typically substantially below the onset
temperature. Consult your technical safety experts. Materials containing
similar structural groups can decompose if heated above 145掳C (293掳F).
Part B: Stable; however, forms peroxides of unknown stability.
Working solution: Stable
Incompatibility: Strong oxidizing agents.
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Effects of Exposure:
General:
Part A & Working solution:
Contains hydroquinone. There is insufficient evidence for classifying
hydroquinone as a suspected carcinogenic or mutagenic substance in humans. No
increases in cancer rates were observed in an epidemiology study which looked at
mortality among more than 800 persons employed primarily in the manufacture of
hydroquinone. Carcinogenicity studies in animals were inconclusive. Rats and
mice were given hydroquinone by stomach tube or at high concentrations in the
diet. Responses were not consistent across route of exposure, species or sex.
The International Agency for Research on Cancer (IARC) has classified
hydroquinone in Group 3, i.e., "not classifiable" as a carcinogen. Hydroquinone
is generally negative in bacterial mutagenicity tests; there is evidence for the
clastogenicity (chromosome breakage) of hydroquinone in vivo and in vitro. The
relevance of chromosomal effects in test animals in predicting human risk is
unclear.
Contains diethanolamine-sulfur dioxide complex. May cause kidney damage
based on animal data. May cause liver damage based on animal data.
Part B:
Contains diethylene glycol. Can cause kidney damage and CNS effects
following ingestion.
Contains 1,4-diphenyl-3-(phenylamino)-1H-1,2,4-triazolium hydroxide.
This material is a quaternary ammonium salt. On the basis of human
experience and toxicology testing, some quaternary ammonium salts are
potential skin irritants and skin sensitizers. Toxicology testing may
not always be predictive of skin sensitization potential with this
chemical class.
Inhalation:
Part A & Working solution: Expected to be a low hazard for recommended
handling. In contact with strong acids or if heated, sulfites may liberate
sulfur dioxide gas. Sulfur dioxide gas is irritating to the respiratory
tract. Some asthmatics or hypersensitive individuals may experience
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difficult breathing.
Part B: Low hazard for recommended handling.
Eyes:
Part A & Working solution: Causes irritation.
Part B: Causes irritation. However, immediate flushing of the eyes with
water will minimize any irritative effect.
Skin:
Part A & Working solution: May cause allergic skin reaction based on human
experience. May cause skin depigmentation. Prolonged or repeated contact
with aqueous solutions may cause irritation.
Part B: Low hazard for recommended handling.
Ingestion:
Part A & Working solution: Harmful if swallowed. Some asthmatics or
sulfite-sensitive individuals may experience wheezing, chest tightness,
stomach upset, hives, faintness, weakness and diarrhea.
Part B: Harmful if swallowed.
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12. ECOLOGICAL INFORMATION
The following properties are ESTIMATED from the components of the
preparations.
Part A Part B Working Solution
Potential Toxicity
Fish LC50 mg/l: 1-10 >100 1-10
Daphnid EC50 mg/l: 1-10 >100 1-10
Algal IC50 mg/l: 10-100 >100 10-100
Organics Readily Yes (7 days) Yes (14 days) Yes (7 days)
Degradable (>70%):
Potential Log Pow <1 Log Pow <1 Log Pow <1
Bioaccumulation:
COD (approximate 738 1731 162
g/l):
BOD5 (approximate 624 206 131
g/l):
Potential Toxicity
Waste treatment >100 >100 >100
microorganisms EC50
(mg/l):
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13. DISPOSAL CONSIDERATIONS
MATERIAL SAFETY DATA SHEET
200000436/F/USA
Approval Date: 01/21/2004
Print Date: 07/11/2005
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Discharge, treatment, or disposal may be subject to national, state, or local
laws. Consult state or local regulatory authorities before flushing to sewer
with large amounts of water. Since emptied containers retain product residue,
follow label warnings even after container is emptied.
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14. TRANSPORT INFORMATION
For transportation information regarding this product call the Kodak Worldwide
Transportation Hazmat Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m.
(Eastern Standard Time), Monday through Friday.
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15. REGULATORY INFORMATION
- Material(s) known to the State of California to cause cancer: None
- Material(s) known to the State of California to cause adverse reproductive
effects: None
Carcinogenicity Classification (components present at 0.1% or more):
- International Agency for Research on Cancer (IARC):
- Hydroquinone, Group 3; Not classifiable.
- Sulfur dioxide, some sulfites, bisulfites and metasulfites, Group 3; Not
classifiable.
- American Conference of Governmental Industrial Hygienists (ACGIH):
- Hydroquinone, A3; Confirmed animal carcinogen with unknown relevance to
humans
- Sodium bisulfite, A4; Not classifiable as a human carcinogen.
- National Toxicology Program (NTP): None
- Occupational Safety and Health Administration (OSHA): None
- Chemical(s) subject to the reporting requirements of Section 313 or Title
III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and
40 CFR Part 372: Hydroquinone
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16. OTHER INFORMATION
US/Canadian Label Statements:
Part A:
CONTAINS: Diethanolamine-sulfur dioxide complex (063149-47-3), Sodium
bisulfite (007631-90-5), Hydroquinone (000123-31-9),
4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (013047-13-7)
WARNING!
HEAT SENSITIVE - CAN DECOMPOSE IF HEATED
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
Store in a cool place.
Avoid contact with eyes, skin, and clothing.
Avoid breathing mist or vapor.
Use with adequate ventilation.
MATERIAL SAFETY DATA SHEET
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Approval Date: 01/21/2004
Print Date: 07/11/2005
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Wash thoroughly after handling.
FIRST AID: If swallowed, only induce vomiting as directed by medical
personnel. Never give anything by mouth to an unconscious person. Call a
physician or poison control center immediately. In case of contact,
immediately flush eyes and skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical
attention if symptoms occur. Wash contaminated clothing before reuse.
Destroy or thoroughly clean contaminated shoes.
Keep out of reach of children.
Do not handle or use until safety precautions in Material Safety Data
Sheet (MSDS) have been read and understood
Additional hazard precautions for containers greater than 1 gallon of
liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings
even after container is emptied.
IN CASE OF FIRE: Use water spray, carbon dioxide (CO2), dry chemical,
alcohol foam. Use water spray to keep fire-exposed containers cool.
Part B:
CONTAINS: Diethylene glycol (000111-46-6), Acetic acid (000064-19-7),
1,4-diphenyl-3-(phenylamino)-1H-1,2,4-triazolium hydroxide (002218-94-2)
WARNING!
HARMFUL IF SWALLOWED
CAN CAUSE KIDNEY DAMAGE AND CNS EFFECTS FOLLOWING INGESTION
CAUSES EYE IRRITATION
MAY FORM EXPLOSIVE PEROXIDES
Keep container tightly closed.
Store away from heat and light.
Do not allow to evaporate to near dryness.
Avoid prolonged or repeated breathing of mist or vapor.
Avoid contact with eyes and prolonged or repeated contact with skin.
Use with adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If swallowed, only induce vomiting as directed by medical
personnel. Never give anything by mouth to an unconscious person. Call a
physician or poison control center immediately. In case of eye contact,
immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention if symptoms occur.
Keep out of reach of children.
For additional information, see Material Safety Data Sheet (MSDS) for this
material.
Additional hazard precautions for containers greater than 1 gallon of
liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings
even after container is emptied.
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IN CASE OF FIRE: Use water spray, carbon dioxide (CO2), dry chemical,
alcohol foam.
IN CASE OF SPILL: Absorb spill with inert material, then place in a
chemical waste container. Flush residual spill or area with water. For
large spills, dike for later disposal. Prevent runoff from entering
drains, sewers, and streams.
Working solution:
CONTAINS: Diethanolamine-sulfur dioxide complex (063149-47-3),
Hydroquinone (000123-31-9), Sodium bisulfite (007631-90-5)
WARNING!
CAUSES EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
HARMFUL IF SWALLOWED
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
Avoid breathing mist or vapor.
Avoid contact with eyes, skin, and clothing.
Use with adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If swallowed, only induce vomiting as directed by medical
personnel. Never give anything by mouth to an unconscious person. Call a
physician or poison control center immediately. In case of contact,
immediately flush eyes and skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical
attention if symptoms occur. Wash contaminated clothing before reuse.
Destroy or thoroughly clean contaminated shoes.
Keep out of reach of children.
For additional information, see Material Safety Data Sheet (MSDS) for this
material.
Additional hazard precautions for containers greater than 1 gallon of
liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings
even after container is emptied.
IN CASE OF FIRE: Use water spray, carbon dioxide (CO2), dry chemical,
alcohol foam
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The information contained herein is furnished without warranty of any kind.
Users should consider these data only as a supplement to other information
gathered by them and must make independent determinations of suitability and
completeness of information from all sources to assure proper use and disposal
of these materials and the safety and health of employees and customers and
the protection of the environment.
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A:R-1, S-2, F-1, C-1HT
B:R-1, S-2, F-1, C-1E
WS:R-1, S-2, F-1, C-0
Material Safety Data Sheet
Revision Date: 12/29/2006
Z17000000414/Version: 1.0
Print Date: 02/05/2007
Page: 1/8
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK T-MAX RS Developer and Replenisher, Part A
Product code: 8446163 - Part A
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 5492
Product Use: photographic processing chemical, For industrial use only.
2. Hazards identification
CONTAINS: Diethanolamine-sulphur dioxide complex (63149-47-3), Hydroquinone (123-31-9), Sodium
bisulphite (7631-90-5), 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (13047-13-7)
WARNING!
HEAT SENSITIVE - CAN DECOMPOSE IF HEATED
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
NFPA Hazard Ratings: Health - 3, Flammability - 1, Instability - 1
NOTE: NFPA 704 (2007) hazard indexes involves data review and interpretation that may vary among
companies. It is intended only for rapid, general identification of the magnitude of the potential hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
50 - 55 Diethanolamine-sulphur dioxide complex (63149-47-3)
40 - 45 Water (7732-18-5)
1- 5 Hydroquinone (123-31-9)
1- 5 Sodium bisulphite (7631-90-5)
<1 Pentetic acid, pentasodium salt (140-01-2)
<1 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (13047-13-7)
4. First aid measures
Material Safety Data Sheet
Revision Date: 12/29/2006
Z17000000414/Version: 1.0
Print Date: 02/05/2007
Page: 2/8
Inhalation: If symptomatic, move to fresh air. Get medical attention if symptoms occur.
Eyes: Rinse immediately with plenty of water for at least 15 minutes. Get medical attention if symptoms
occur.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention. Wash contaminated clothing before re-
use. Destroy or thoroughly clean contaminated shoes.
Ingestion: If swallowed, do NOT induce vomiting. Give victim a glass of water. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
5. Fire-fighting measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products. Use water spray to keep fire-
exposed containers cool.
Hazardous Combustion Products: Carbon oxides, nitrogen oxides (NOx), sulphur oxides, (see also
Hazardous Decomposition Products section).
Unusual Fire and Explosion Hazards: Elevated temperature can cause decomposition.
6. Accidental release measures
Methods for cleaning up: Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste. Clean surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Wash thoroughly
after handling.
Prevention of Fire and Explosion: Keep away from heat and sources of ignition. Keep from contact
with oxidizing materials.
Storage: Store in cool place. Keep container tightly closed. Keep away from incompatible substances
(see Incompatibility section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Hydroquinone ACGIH time weighted average 2 mg/m3
OSHA Z1 Permissible exposure limit 2 mg/m3
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Print Date: 02/05/2007
Page: 3/8
Sodium bisulphite ACGIH time weighted average 5 mg/m3
4-hydroxymethyl-4- EK HPG Time Weighted Average (TWA): 0.2 mg/m3
methyl-1-phenyl-3-
pyrazolidinone
Sulphur dioxide ACGIH time weighted average 2 ppm
ACGIH Short term exposure limit 5 ppm
OSHA Z1 Permissible exposure limit 5 ppm 13 mg/m3
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: None should be needed. If engineering controls do not maintain airborne
concentrations below recommended exposure limits, an approved respirator must be worn. A respirator
should be worn if hazardous decomposition products are likely to be or have been released. Respirator
type: Acid gas. If respirators are used, a program should be instituted to assure compliance with
applicable federal, state, commonwealth, provincial, or local laws and regulations.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: tan
Odour: amine
Specific gravity: 1.21
Vapour pressure (at 20.0 掳C (68.0 掳F)) : 24 mbar (18.0 mm Hg)
Vapour density: 0.6
Volatile fraction by weight: 40 - 45 %
Boiling point/range: > 100.0 掳C (> 212.0 掳F)
Water solubility: complete
pH: 8.9
Flash point: does not flash
10. Stability and reactivity
Material Safety Data Sheet
Revision Date: 12/29/2006
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Print Date: 02/05/2007
Page: 4/8
Stability: Stable under normal conditions. Safe handling temperatures are dependent on specific conditions of use
and are typically substantially below the onset temperature. Consult your technical safety experts.
Incompatibility: Strong oxidizing agents, Acids. Contact with strong acids liberates sulphur dioxide.
Hazardous decomposition products: sulphur oxides, nitrogen oxides (NOx).
Hazardous Polymerization: Hazardous polymerization does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: Hydroquinone. There is insufficient evidence for classifying hydroquinone as a
suspected carcinogenic or mutagenic substance in humans. No increases in cancer rates were
observed in an epidemiology study which looked at mortality among more than 800 persons
employed primarily in the manufacture of hydroquinone. Carcinogenicity studies in animals
were inconclusive. Rats and mice were given hydroquinone by stomach tube or at high
concentrations in the diet. Responses were not consistent across route of exposure, species or
sex. The International Agency for Research on Cancer (IARC) has classified hydroquinone in
Group 3, i.e., "not classifiable" as a carcinogen. Hydroquinone is generally negative in bacterial
mutagenicity tests; there is evidence for the clastogenicity (chromosome breakage) of
hydroquinone in vivo and in vitro. The relevance of chromosomal effects in test animals in
predicting human risk is unclear.
Contains: Diethanolamine-sulphur dioxide complex. May cause liver damage based on animal
data. May cause kidney damage based on animal data.
Contains: 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone. May cause adverse
reproductive effects such as infertility based on animal data. Based on repeated-dose ingestion
studies in animals, this chemical may cause blood, testicular, and adverse reproductive effects.
Inhalation: Expected to be a low hazard for recommended handling. In contact with strong acids or if
heated, sulphites may liberate sulphur dioxide gas. Sulphur dioxide gas is irritating to the respiratory
tract. Some asthmatics or hypersensitive individuals may experience difficult breathing.
Eyes: Causes eye irritation. Airborne dust/mist/vapor irritating.
Skin: May cause allergic skin reaction based on human experience. May cause skin depigmentation.
Prolonged or repeated contact with aqueous solutions may cause irritation.
Ingestion: Harmful if swallowed. Some asthmatics or sulfite-sensitive individuals may experience
wheezing, chest tightness, stomach upset, hives, faintness, weakness and diarrhea.
Data for Diethanolamine-sulphur dioxide complex (CAS 63149-47-3):
Acute Toxicity Data:
鈥? Oral LD50 (male rat): 1,903 mg/kg
Material Safety Data Sheet
Revision Date: 12/29/2006
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Print Date: 02/05/2007
Page: 5/8
鈥? Oral LD50 (female rat): 1,131 mg/kg
鈥? Dermal LD50: >20 ml/kg
鈥? Dermal LD50 (guinea pig): >20 ml/kg
鈥? Skin irritation: slight
鈥? Skin irritation: no exacerbation (repeated skin application)
鈥? Skin Sensitization: none
鈥? Skin Sensitization (guinea pig): none
鈥? Eye irritation: slight
Data for Hydroquinone (CAS 123-31-9):
Acute Toxicity Data:
鈥? Oral LD50 (rat): 400 mg/kg
鈥? Oral LD50 (male rat): 400 mg/kg
鈥? Oral LD50 (male mouse): 100 - 200 mg/kg
鈥? Dermal LD50 (guinea pig): > 1,000 mg/kg
鈥? Dermal absorption rate: 1.1 micrograms (s) / cm 2 / hour
鈥? Skin irritation: slight
鈥? Skin Sensitization: positive
鈥? Eye irritation: moderate
Mutagenicity/Genotoxicity Data:
鈥? Salmonella typhimurium assay (Ames test): negative (in presence and absence of
activation)
鈥? Chromosomal aberration assay: negative (in absence of activation)
鈥? Chromosomal aberration assay: positive (in presence of activation)
鈥? Sister chromatid exchange (SCE) assay: positive (in presence and absence of activation)
Definitions for the following section(s): LOEL =lowest-observed-effect level, LOAEL = lowest-
observed-adverse-effect, NOAEL = no observed-adverse-effect level, NOEL =no-observed-effect
level.
Repeated dose toxicity:
鈥? Dermal (17-day, rat): NOEL; 3800 mg/kg/day
鈥? Dermal (17-day): LOEL (Lowest observable effect level); 4800 mg/kg/day
Developmental Toxicity Data:
鈥? Oral (female rabbit): NOEL for developmental toxicity; 25mg/kg/day
Data for Sodium bisulphite (CAS 7631-90-5):
Acute Toxicity Data:
鈥? Oral LD50 (rat): > 1,600 mg/kg
Data for Pentetic acid, pentasodium salt (CAS 140-01-2):
Acute Toxicity Data:
鈥? Oral LD50 (male rat): 3,200 mg/kg
Material Safety Data Sheet
Revision Date: 12/29/2006
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Print Date: 02/05/2007
Page: 6/8
鈥? Oral LD50 (female rat): 2,263 mg/kg
鈥? Skin Sensitization: none
Definitions for the following section(s): LOEL =lowest-observed-effect level, LOAEL = lowest-
observed-adverse-effect, NOAEL = no observed-adverse-effect level, NOEL =no-observed-effect
level.
Repeated dose toxicity:
鈥? Oral (11 days, male rat): NOEL; 100 mg/kg/day
Data for 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (CAS 13047-13-7):
Acute Toxicity Data:
鈥? Oral LD50 (rat): 566 mg/kg
鈥? Oral LD50: 283 mg/kg
鈥? Dermal LD50: > 1,000 mg/kg
鈥? Skin irritation: slight
鈥? Skin irritation: slight exacerbation (repeated skin application)
鈥? Skin Sensitization: slight
鈥? Eye irritation: strong irritation
Definitions for the following section(s): LOEL =lowest-observed-effect level, LOAEL = lowest-
observed-adverse-effect, NOAEL = no observed-adverse-effect level, NOEL =no-observed-effect
level.
Repeated dose toxicity:
鈥? Oral (12-day, rat): NOEL; 88 mg/kg/day
鈥? Oral (12-day, rat): LOEL (Lowest observable effect level); 440 mg/kg/day (target organ
effects: blood, target organ effects: testes)
鈥? Oral (28-day, rat): NOEL; 10 mg/kg/day
鈥? Oral (28-day, rat): LOEL (Lowest observable effect level); 40 mg/kg/day (target organ effects:
blood, target organ effects: testes)
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: 1 - 10 mg/l
Daphnid EC50: 1 - 10 mg/l
Algal IC50: 10 - 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Material Safety Data Sheet
Revision Date: 12/29/2006
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Print Date: 02/05/2007
Page: 7/8
Potential Bioaccumulation: log Pow < 1
COD (approximate): 738 g/l
BOD (approximate): 624 g/l
13. Disposal considerations
Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local
laws. Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14. Transport information
Not regulated for all modes of transportation.
For more transportation information, go to: www.kodak.com/go/ship.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Hydroquinone: 3 (Classification not possible
from current data.), Sodium bisulphite: 3 (Classification not possible from current data.)
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: Hydroquinone
16. Other information
The data below reflects current legislative requirements whereas the product in your possession may
carry a different version of the label depending on the date of manufacture.
US/Canadian Label Statements:
CONTAINS: Diethanolamine-sulphur dioxide complex (63149-47-3), Hydroquinone (123-31-9),
Sodium bisulphite (7631-90-5), 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidinone (13047-
13-7)
WARNING!
HEAT SENSITIVE - CAN DECOMPOSE IF HEATED
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
Material Safety Data Sheet
Revision Date: 12/29/2006
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Print Date: 02/05/2007
Page: 8/8
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
Store in cool place.
Avoid breathing mist or vapour at concentrations greater than the exposure limits.
Avoid contact with eyes, skin, and clothing.
Use only with adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If symptomatic, move to fresh air. Get medical attention if symptoms occur. Rinse
immediately with plenty of water for at least 15 minutes. Get medical attention if symptoms occur. In
case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Get medical attention. Wash contaminated clothing before re-use.
Destroy or thoroughly clean contaminated shoes. If swallowed, do NOT induce vomiting. Give victim
a glass of water. Never give anything by mouth to an unconscious person. Get medical attention
immediately.
Keep out of reach of children.
Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read
and understood.
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
IN CASE OF SPILL: Absorb spill with vermiculite or other inert material, then place in a container for
chemical waste. Clean surface thoroughly to remove residual contamination.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-2, F-1, C-1HT
Material Safety Data Sheet
Revision Date: 12/29/2006
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Print Date: 02/05/2007
Page: 1/6
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK T-MAX RS Developer and Replenisher, Part B
Product code: 8446163 - Part B
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: None.
Product Use: photographic processing chemical, For industrial use only.
2. Hazards identification
CONTAINS: Diethylene glycol (111-46-6), Acetic acid (64-19-7), 1,4-diphenyl-3-(phenylammonio)-1H-
1,2,4-triazolium (2218-94-2)
WARNING!
MAY FORM EXPLOSIVE PEROXIDES
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
CAN CAUSE KIDNEY DAMAGE AND CNS EFFECTS FOLLOWING INGESTION
NFPA Hazard Ratings: Health - 2, Flammability - 1, Instability - 1
NOTE: NFPA 704 (2007) hazard indexes involves data review and interpretation that may vary among
companies. It is intended only for rapid, general identification of the magnitude of the potential hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
90 - 99 Diethylene glycol (111-46-6)
1- 5 Acetic acid (64-19-7)
0.1 - < 1 1,4-diphenyl-3-(phenylammonio)-1H-1,2,4-triazolium (2218-94-2)
4. First aid measures
Inhalation: If symptomatic, move to fresh air. Get medical attention if symptoms occur.
Eyes: Rinse immediately with plenty of water for at least 15 minutes. Get medical attention if symptoms
occur.
Material Safety Data Sheet
Revision Date: 12/29/2006
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Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash contaminated clothing before re-use. Destroy or
thoroughly clean contaminated shoes.
Ingestion: If swallowed, do NOT induce vomiting. Give victim a glass of water. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
5. Fire-fighting measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Hazardous Combustion Products: Carbon oxides, nitrogen oxides (NOx)
Unusual Fire and Explosion Hazards: Forms peroxides of unknown stability.
6. Accidental release measures
Methods for cleaning up: Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste. Clean surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Avoid contact with eyes, skin, and clothing. Use only with adequate ventilation. Wash thoroughly
after handling.
Prevention of Fire and Explosion: Keep from contact with oxidizing materials. If peroxide formation is
suspected, do not open or move container. Minimize exposure to air. After opening, purge container with
nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Do not distill or
allow to evaporate to near dryness. Keep material from heat, light, and flame.
Storage: Protect against light. Keep container tightly closed. Keep away from incompatible substances
(see Incompatibility section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Acetic acid ACGIH time weighted average 10 ppm
ACGIH Short term exposure limit 15 ppm
OSHA Z1 Permissible exposure limit 10 ppm 25 mg/m3
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Material Safety Data Sheet
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Respiratory protection: None should be needed. If engineering controls do not maintain airborne
concentrations below recommended exposure limits, an approved respirator must be worn. Respirator
type: full-face with organic vapour & P95 particulate filter. If respirators are used, a program should be
instituted to assure compliance with applicable federal, state, commonwealth, provincial, or local laws
and regulations.
Eye protection: If a full-face respirator is not worn, wear vapour-tight chemical goggle and a face shield.
Skin and body protection: For operations where prolonged or repeated skin contact may occur,
impervious gloves should be worn.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: amber
Odour: vinegar
Specific gravity: 1.12
Vapour pressure (at 20.0 掳C (68.0 掳F)) : 24 mbar (18.0 mm Hg)
Vapour density: 0.6
Volatile fraction by weight: < 5 %
Boiling point/range: > 100.0 掳C (> 212.0 掳F)
Water solubility: complete
pH: No data available
Flash point: > 93.3 掳C (> 200.0 掳F) estimated
10. Stability and reactivity
Stability: Stable; however, forms peroxides of unknown stability.
Incompatibility: Strong oxidizing agents.
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerization does not occur.
11. Toxicological information
Material Safety Data Sheet
Revision Date: 12/29/2006
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Page: 4/6
Effects of Exposure
General advice:
Contains: Diethylene glycol. Can cause kidney damage and CNS effects following ingestion.
Repeated oral exposure to high doses can cause liver damage.
Contains: 1,4-diphenyl-3-(phenylammonio)-1H-1,2,4-triazolium. The toxicological properties of
this material have not been fully investigated and its handling and use may present additional
hazards.
Inhalation: Expected to be a low hazard for recommended handling.
Eyes: Causes eye irritation. However, immediate flushing of the eyes with water will minimize any
irritative effect. Airborne dust/mist/vapor irritating.
Skin: May cause allergic skin reaction.
Ingestion: Harmful if swallowed.
Data for Diethylene glycol (CAS 111-46-6):
Acute Toxicity Data:
鈥? Oral LD50 (rat): > 3,200 mg/kg
鈥? Dermal LD50: > 10,000 mg/kg
鈥? Skin irritation: slight to moderate
鈥? Eye irritation: slight
Data for Acetic acid (CAS 64-19-7):
Acute Toxicity Data:
鈥? Oral LD50 (rat): 3,310 - 3,530 mg/kg
鈥? Oral LD50: 4,960 mg/kg
鈥? Inhalation LC50: 5620 ppm / 1.00 hr
鈥? Dermal LD50: 1,060 mg/kg
鈥? Skin irritation: severe
鈥? Eye irritation: severe
Data for 1,4-diphenyl-3-(phenylammonio)-1H-1,2,4-triazolium (CAS 2218-94-2):
Acute Toxicity Data:
鈥? Oral LD50 (rat): 50 - 400 mg/kg
鈥? Dermal LD50 (guinea pig): > 2,200 mg/kg
鈥? Skin irritation: very slight
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Material Safety Data Sheet
Revision Date: 12/29/2006
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Print Date: 02/05/2007
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Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: > 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 1731 g/l
BOD (approximate): 206 g/l
13. Disposal considerations
Discharge, treatment, or disposal may be subject to federal, state, commonwealth, provincial, or local
laws. Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14. Transport information
Not regulated for all modes of transportation.
For more transportation information, go to: www.kodak.com/go/ship.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): none
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
The data below reflects current legislative requirements whereas the product in your possession may
carry a different version of the label depending on the date of manufacture.
US/Canadian Label Statements:
Material Safety Data Sheet
Revision Date: 12/29/2006
000000020852/Version: 1.0
Print Date: 02/05/2007
Page: 6/6
CONTAINS: Diethylene glycol (111-46-6), Acetic acid (64-19-7), 1,4-diphenyl-3-
(phenylammonio)-1H-1,2,4-triazolium (2218-94-2)
WARNING!
MAY FORM EXPLOSIVE PEROXIDES
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
CAN CAUSE KIDNEY DAMAGE AND CNS EFFECTS FOLLOWING INGESTION
Keep container tightly closed.
Store away from heat and light.
Do not allow to evaporate to near dryness.
Avoid breathing mist or vapour at concentrations greater than the exposure limits.
Avoid contact with eyes, skin, and clothing.
Use only with adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If symptomatic, move to fresh air. Get medical attention if symptoms occur. Rinse
immediately with plenty of water for at least 15 minutes. Get medical attention if symptoms occur. In
case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash contaminated clothing before re-use. Destroy or thoroughly
clean contaminated shoes. If swallowed, do NOT induce vomiting. Give victim a glass of water.
Never give anything by mouth to an unconscious person. Get medical attention immediately.
Keep out of reach of children.
Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read
and understood.
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
IN CASE OF SPILL: Absorb spill with vermiculite or other inert material, then place in a container for
chemical waste. Clean surface thoroughly to remove residual contamination.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-2, F-1, C-1E
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