Huntsman Advanced Materials Americas Inc.
DISTRIBUTED BY FREEMAN MFG & SUPPLY CO. 800-321-8511
24-Hour Emergency Phone: 1-888-354-3323
MSDS No: 6145
Effective Date: 1/20/04 Material Safety Data Sheet
Health: 3
1. PRODUCT IDENTIFICATION 1
Flammability: 1
3 0
Reactivity: 0
Trade Name: RenPIM 6454 Polyol
Personal Protection:
Chemical Family: Polyol
HMIS RATING
NFPA RATING
Synonyms:
78-593 Hardener
RP 6454 Hardener
Intended Use or Product Type: Polyurethane hardener
2. COMPOSITION / INFORMATION ON INGREDIENTS
O CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN
S STATUS
H ACGIH OSHA MFR. IARC NTP OSHA
A TWA STEL PEL STEL
* 102-60-3 2-Propanol, NE NE NE NE NE NR NR NR
1,1',1'',1'''-(1,2-ethanediyldinitrilo)t
etrakis-
Common Amine based tetrol
Name:
* 9046-10-0 Poly[Oxy(Methyl-1,2-Ethanediyl)], NE NE NE NE NE NR NR NR
.alpha.-(2-Aminomethylethyl)-.ome
ga.-(2-Aminomethylethoxy)-
Common Polyoxypropylenediamine
Name:
* 105-59-9 Ethanol, 2,2'-(methylimino)bis- NE NE NE NE NE NR NR NR
Common N-methyldiethanolamine
Name:
* = OSHA Hazardous Ingredient
3. HAZARDS IDENTIFICATION
Emergency Overview: Corrosive - Causes skin burns. Causes eye irritation. Harmful if absorbed through skin.
Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.
Printed: 04/03/2004 Page 1 of 5
RenPIM 6454 Polyol Huntsman Advanced Materials
Effective Date: 1/20/04 Americas Inc.
4. FIRST AID MEASURES
Ingestion: If conscious, give 2 - 4 glasses of water to drink. Do not induce vomiting. Call a physician.
Skin: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy contaminated
shoes.
Inhalation: Remove to fresh air. Call a physician.
Eyes: Immediately flush eyes with water for at least 15 minutes. Call a physician.
Overexposure Effects: Corrosive - causes skin burns. Causes eye irritation. Harmful if absorbed through skin.
Medical Conditions Aggravated by Exposure: Skin and eye conditions.
Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.
5. FIRE FIGHTING MEASURES
> 200掳F (> 93 掳C)
Flash Point:
Estimated
Flash Point Method Used:
Not established
Flammable Limits in Air (Lower - % by volume):
Not established
Flammable Limits in Air (Upper - % by volume):
Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
Fire Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.
6. ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Remove spillage by absorbing in absorbent material.
7. HANDLING AND STORAGE
Signal Word: Danger!
Precautions: Corrosive - causes skin burns. Can cause eye irritation. Can be harmful if absorbed through skin. Do not get on skin
or on clothing. Avoid contact with eyes. Wash thoroughly after handling.
Other Handling Information: Nuisance dust may be generated when sanding or sawing cured material.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Skin Protection: Wear impermeable gloves.
Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.
Printed: 04/03/2004 Page 2 of 5
RenPIM 6454 Polyol Huntsman Advanced Materials
Effective Date: 1/20/04 Americas Inc.
Eye Protection: Wear splash-proof chemical goggles.
Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.
9. PHYSICAL AND CHEMICAL PROPERTIES
Cloudy, Off White
Color:
Liquid
Physical State:
Slight
Solubility in Water:
1.079 (water = 1)
Specific Gravity:
Not Determined
Boiling Point:
Not Determined
Evaporation Rate:
Not Determined
Vapor Density:
Not Determined
pH:
Percent Volatile: Negligible.
10. STABILITY AND REACTIVITY
Conditions to Avoid: Excessive heat for prolonged periods of time.
Stability: Stable.
Incompatibility: Strong oxidizers, acids and bases.
Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Dermal Toxicity (LD50): Component(s) are toxic, 200 - 1000 mg/kg (rabbit).
Skin Irritation: Corrosive. Causes burns.
Eye Irritation: Irritant.
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.
14. TRANSPORT INFORMATION
DOT: Non-Bulk
Polyamines, liquid, corrosive, N.O.S.
Proper Shipping Name:
Printed: 04/03/2004 Page 3 of 5
RenPIM 6454 Polyol Huntsman Advanced Materials
Effective Date: 1/20/04 Americas Inc.
Polyoxypropylenediamine
Technical Shipping Name (If n.o.s.):
8
Hazard Class:
UN 2735
ID Number:
PG II
Packing Group:
Corrosive
Label:
15. REGULATORY INFORMATION
US Federal Regulations:
Occupational Safety and Health Act (OSHA): This Material Safety Data Sheet (MSDS) has been prepared in compliance with the
federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous chemical under
that standard.
Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CFR 261).
SARA Title III: Section 313 Toxic Chemical List (TCL): This product contains a toxic chemical(s) for routine annual toxic
chemical release reporting under section 313 (40 CFR 372). This information must be included in all MSDS's copied or distributed for
this material.
Chemical Name: Aluminum Oxide (Al2O3)
Common Name: Alumina
Percent in Composition: 1.5714 % by wt
Comment:
TSCA Section 8(b) - Inventory Status: All chemical components of this product are in compliance with TSCA inventory
requirements.
TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b) export
notification.
State Regulations:
Pennsylvania Right-to-Know: The following is required composition information:
Chemical Name: Oxirane, methyl-, polymer with oxirane, ether with 1,2,3-propanetriol
Common Name: Polyether triol
CAS Number: 9082-00-2
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Poly[oxy(methyl-1,2-ethanediyl)], .alpha.,.alpha.',.alpha.''-1,2,3-propanetriyltris[.omega.-hydroxy-
Common Name: Polyether triol
CAS Number: 25791-96-2
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Poly[Oxy(Methyl-1,2-Ethanediyl)], .alpha.-Hydro-.omega.-Hydroxy-, Ether with B-D-Fructofuranosyl
.alpha.-D-Glucopyranoside
Common Name: Sucrose based polyether polyol
CAS Number: 9049-71-2
Comment: Not on Pennsylvania Hazardous Substance List
Printed: 04/03/2004 Page 4 of 5
RenPIM 6454 Polyol Huntsman Advanced Materials
Effective Date: 1/20/04 Americas Inc.
Chemical Name: 2-Propanol, 1,1',1'',1'''-(1,2-ethanediyldinitrilo)tetrakis-
Common Name: Amine based tetrol
CAS Number: 102-60-3
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-
Common Name: Polypropylene Glycol
CAS Number: 25322-69-4
Comment: Not on Pennsylvania Hazardous Substance List
Chemical Name: Silica
Common Name: Fumed Silica
CAS Number: 7631-86-9
Comment: Hazardous Substance
Chemical Name: Aluminum Oxide (Al2O3)
Common Name: Alumina
CAS Number: 1344-28-1
Comment: Environmental Hazardous Substance
16. OTHER INFORMATION
6145
MSDS No:
Dianne Blessing
Approved By:
EH&S Specialist
Title:
Disclaimer: The following supercedes Buyer鈥檚 documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESS OR IMPLIED, INCLUDING OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No
statements herein are to be construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be liable for
incidental, consequential or indirect damages for alleged negligence, breach of warranty, strict liability, tort or contract arising in
connection with the product(s). Buyer鈥檚 sole remedy and Seller鈥檚 sole liability for any claims shall be Buyer鈥檚 purchase price. Data
and results are based on controlled or lab work and must be confirmed by Buyer by testing for its intended conditions of use. The
product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes,
abraded skin, or blood is intended; or for uses for which implantation within the human body is intended.
Printed: 04/03/2004 Page 5 of 5
|