TIDE WITH BLEACH GRANULAR LAUNDRY DETERGENT MSDS (Continued) Page 5 of 5
SECTION XVI - OTHER INFORMATION
*N/A. - Not Applicable *N/K. - Not Known
The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company鈥檚 knowledge. The information relates to the specific
material designated herein, and does not relate to the use in combination with any other material or any other
process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage
to any property resulting from misuse of the controlled product.
5
TIDE WITH BLEACH GRANULAR LAUNDRY DETERGENT MSDS (Continued) Page 4 of 5
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: Open flame
Materials to Avoid: None
Hazardous Decomposition Products: None known
Other Recommendations: None
SECTION XI - TOXICOLOGICAL INFORMATION
LD50 (rats oral): 2.8 - 7.1 g/kg
ED50 approx. 15-119 mg/kg
SECTION XII - ECOLOGICAL INFORMATION
No concerns at relevant environmental concentrations.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE AND LOCAL REGULATIONS. Small (household) solutions may be disposed of in sewer. Dry product
may be landfilled. Do not reuse empty container except with Tide with Bleach Refill. Discard empty container in
trash.
SECTION XIV - TRANSPORT INFORMATION
The finished product is non-hazardous under DOT.
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All intentionally-present components of Tide with Bleach are listed on the US TSCA Inventory. No components
are affected by Significant New Use Rules (SNURs) under TSCA 搂5.
Tide with Bleach is not subject to labeling under California Proposition 65.
Sodium carbonate (497-19-8) is listed on the Canadian WHMIS Ingredient Disclosure List (IDL) as item number
1431, with a threshold of 1%.
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified
with Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information
required by the Canadian Products Regulation.
4
TIDE WITH BLEACH GRANULAR LAUNDRY DETERGENT MSDS (Continued) Page 3 of 5
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: Minimize dust levels while collecting product (see "Inhalation" health effects). Prevent
exposure to dust with NIOSH approved respirators with HEPA filters. Use gloves to minimize skin contact.
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE AND LOCAL REGULATIONS. Small (household) solutions may be disposed of in sewer. Dry product
may be landfilled if permitted by local regulations. Do not reuse container except with Tide with Bleach Refill.
Discard empty container in trash.
Steps To Be Taken in Case Material is Released or Spilled: Flush small (household) quantities down acceptable
sanitary/process sewer. Wipe up small spills with a damp cloth. Dispose of according to local regulations.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Avoid skin contact and breathing product dust. Store in a
cool, dry place. Keep product dry to maintain free-flowing granules.
Other Precautions: None
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): None required with normal consumer use. Industrial use may require a
NIOSH approved respirator with HEPA filters.
Ventilation Local Exhaust: None required with normal consumer use. Special: None
Industrial use may require LEV.
Mechanical (General): General dilution ventilation is adequate Other: None
with normal consumer use.
Eye Protection: None required with normal consumer use.
Industrial setting: If a splash of product in solution is likely, chemical goggles may be needed.
Protective Gloves: None required with normal consumer use.
Industrial setting: Protective gloves (rubber, neoprene) should be used for any prolonged direct contact.
Other Protective Equipment: None required with normal consumer use.
Industrial setting: Protective disposable suits may be required under heavy industrial dust conditions.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point 掳 F: N/A Specific Gravity (H2O=1): N/A
Vapor Pressure (mm Hg): N/A Percent Volatile by Volume (%): N/A
Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): N/A
Odor Threshold: N/A Freezing Point: N/A
Coefficient of Water/Oil Distribution: N/A pH (1% solution): ~10.6
Scooped Density: ~667 g/L Solubility in Water: Mostly
Appearance and Odor: White granular agglomerate Reserve Alkalinity: ~3.05
with blue speckles. Product is perfumed.
3
TIDE WITH BLEACH GRANULAR LAUNDRY DETERGENT MSDS (Continued) Page 2 of 5
SECTION III - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: May cause transient gastrointestinal irritation.
Eye Contact: May cause mild, transient irritation.
Inhalation: Heavy exposure to dust may cause transient respiratory tract irritation. Prolonged heavy
exposure to dust may cause respiratory sensitization.
Signs and Symptoms of Exposure:
Ingestion: Possible mild gastrointestinal irritation with nausea, vomiting, and/or diarrhea.
Eye Contact: Eye contact with the product or its aqueous solution may produce transient superficial irritation.
Skin: N/A
Inhalation: N/A
SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Inhalation: Leave dusty area. In rare cases a respiratory reaction can occur which may include
tightness of chest and difficulty breathing. If this occurs, seek medical attention
immediately.
Ingestion: Give a large glassful of water or milk.
Eye Contact: Flush thoroughly with water for 15 minutes.
Skin: Rinse skin thoroughly with water.
Other: Consumer product packages have a caution statement: 鈥淜EEP OUT OF REACH OF CHILDREN.
CAUTION: CAUSES MODERATE EYE IRRITATION. AVOID CONTACT WITH EYES. HARMFUL IF
SWALLOWED. FIRST AID: IF SWALLOWED: DRINK 1 OR 2 GLASSES OF WATER. CALL A
PHYSICIAN OR POISON CONTROL CENTER. IF IN EYES: IN CASE OF CONTACT IMMEDIATELY
FLUSH EYES WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.鈥?
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): N/A Explosive Limits: LEL: N/A UEL: N/A
Extinguishing Media: N/A
Special Fire Fighting Procedures:. CO2, water or dry chemical may be used.
Unusual Fire Hazards: N/A
Conditions to Avoid: Open flame
Stability Unstable:
Stable: X
Incompatibility (Materials to Avoid): None known
Hazardous Decomposition/By Products: None known
Conditions to Avoid: Open flame
Hazardous Polymerization: May Occur:
Will Not Occur: X
2
Page 1 of 5
Procter & Gamble
Fabric and Home Care Division
Ivorydale Technical Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS #: L98031M Issue Date: 11/1/99
Supersedes: N/A Issue Date: N/A
SECTION I - CHEMICAL PRODUCT
Identity: Granular Laundry Detergent
Brands: TIDE WITH BLEACH (All variations)
鈥淜ILLS 99.9% OF BACTERIA鈥?
Hazard Rating: 1 Health: 1 4=EXTREME
Flammability: 0 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
Emergency Telephone Number: 24hr P&G Operator - 1-800-879-8433 or call Local Poison Control Center
SECTION II - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Sodium nonanoyloxybenzenesulfonate; perboric acid, sodium salt; surfactants
(anionic and nonionic) and enzymes.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Common CAS No. Recommended Composition Range LD50/LC50
Chemical
Name Limits
Name
Sodium Soda Ash 497-19-8 N/A 15-40% LD50=1.86 g/kg
carbonate LC50=N/A
LD50=0.65-1.26 g/kg
Linear alkyl C12.3 LAS 68081-81-2 N/A 7-13%
LC50=N/A
benzene
sulfonate
Subtilisin Protealytic 9014-01-1 NIOSH/ 0.1-1% LD50=3.7 g/kg
enzyme ACGIH STEL: LC50=N/A
0.00006
mg/m3
Under normal consumer use, this product would not constitute a hazardous product under US OSHA
Hazard Communication. With increased exposure (compared with consumer use) this mixture, when
tested as a whole, is considered an inhalation hazard (enzymes) and an eye irritant within the meaning of
the OSHA Hazard Communication Standard.
*Subtilisin is listed on Table Z-1-A (1989 Air Contaminants Rule - 29 CFR 1910.1000). Though Table Z-1-A was
revoked on 6/30/93, the following U.S. states continue to enforce Table Z-1-A limits: Alaska, California,
Connecticut, Maryland, Minnesota, New Mexico, Vermont, Washington, and Virgin Islands. The OSHA STEL (as
listed on Table Z-1-A) is 0.00006 mg/m3.
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