10076 - ILFOTEC LC29 REVISION DATE : 05/07/99
MATERIAL SAFETY DATA SHEET
ILFOTEC LC29
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
ILFOTEC LC29
TRADE NAME:
A12
SYNONYMS:
IP86LC
PART No.:
0
UN/NA (PIN) No.:
FOR MEDICAL EMERGENCY IN THE UNITED STATES AND CANADA CALL
EMERGENCY TELEPHONE:
1-800-842-9660 (PRODUCT MISUSE). FOR TRANSPORTATION EMERGENCY
CALL CHEMTREC 1-800-424-9300.
ILFORD Imaging USA Inc
SUPPLIER:
West 70 Century Road, Paramus, NJ 07653
Tel: 201-265-6000
Bryan Sammartino
CONTACT PERSON:
2. COMPOSITION, INFORMATION ON INGREDIENTS
INGREDIENT NAME: CAS No.: CONTENTS : EPA RQ: TPQ:
DIETHYLENEGLYCOL 111-46-6 5-10 %
HYDROQUINONE 123-31-9 5-10 %
DIETHANOLAMINE BISULFITE 63149-47-3 30-60 %
DIETHANOLAMINE 111-42-2 1-5 %
1-PHENYL-4-METHYL-3-PYRAZOLIDONE 2654-57-1 0-1 %
DIETHYLENETRIAMINE PENTAACETIC ACID- 67-43-6 1-5 %
NA5
DIETHANOLAMINE HYDROBROMIDE 1-5 %
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
Colorless or pale yellow, odorless, weakly alkaline, water-based, non-flammable liquid. Contains hydroquinone.
Harmful in contact with skin and if swallowed. Irritating to eyes and skin. May cause sensitisation by skin
contact.
ACUTE EFFECTS:
May cause irritation to the respiratory system.
INHALATION:
Harmful if swallowed. May cause discomfort if swallowed. Liquid irritates mucous membranes and may cause
INGESTION:
abdominal pain if swallowed.
Irritating to skin. May cause sensitisation by skin contact. May cause allergic contact eczema.
SKIN:
Irritation of eyes and mucous membranes. Repeated exposure may cause chronic eye irritation.
EYES:
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CHRONIC EFFECTS:
HEALTH WARNINGS:
Prolonged or repeated exposure may cause severe irritation. May cause sensitisation by skin contact. May cause
skin irritation/eczema.May cause allergy. May cause hypersensitivity.
ROUTE OF ENTRY:
Ingestion. Skin and/or eye contact.
MEDICAL INFORMATION:
May aggravate existing: Skin disorders and allergies.
4. FIRST AID MEASURES
Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Get medical attention if any
INHALATION:
discomfort continues.
DO NOT INDUCE VOMITING! Remove victim immediately from source of exposure. Rinse mouth thoroughly.
INGESTION:
Immediately give a couple of glasses of water, provided the victim is fully conscious. Get medical attention
immediately!
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin
SKIN:
immediately with soap and water. Get medical attention immediately.
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with lots of water
EYES:
while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA:
This material is not flammable. Use extinguishing media appropriate for surrounding fire.
HAZARDOUS COMBUSTION PRODUCTS:
Sulfur dioxide.
6. ACCIDENTAL RELEASE MEASURES
SPILL CLEAN-UP PROCEDURES:
Use appropriate protective clothing. Do not contaminate drainage or waterways. Absorb spill with non-reactive
absorbent and place in non-reactive containers for disposal. Contain Spill. Use large quantities of water to flush
small spills to sanitary sewer if local regulations permit. Do not flush to septic tank. See Section 13 for disposal
considerations. Flush with plenty of water to clean spillage area. Do not let washing down water contaminate
ponds or waterways. Inform Authorities if large amounts are involved.
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS:
Avoid spilling, skin and eye contact. Provide good ventilation. Individuals liable to allergic reactions should not
handle the product Read and follow manufacturer's recommendations.
STORAGE PRECAUTIONS:
Keep in cool, dry, ventilated storage and closed containers. Store below 75掳F. Keep in original container. Keep
containers closed tightly.
STORAGE CRITERIA:
Chemical storage.
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8. EXPOSURE CONTROLS, PERSONAL PROTECTION
OSHA PEL: ACGIH TLV: OTHER:
INGREDIENT NAME: CAS No.: TWA: STEL: TWA: STEL: TWA: STEL: UNITS:
DIETHANOLAMINE 111-42-2 2 mg/m3
mg/m3
PROTECTIVE EQUIPMENT:
ENGINEERING CONTROLS:
Provide eyewash station and safety shower.
Provide adequate general and local exhaust ventilation. Must not be handled in confined spaces without adequate
VENTILATION:
ventilation. General room ventilation should provide for 10 - 15 room air changes per hour.
RESPIRATORS: Respiratory protection must be used if air concentration exceeds acceptable level. An acid gas/organic vapor
cartridge should be used.
PROTECTIVE GLOVES:
Use protective gloves made of: Rubber (natural,latex). Neoprene. Polyethylene.
EYE PROTECTION:
Wear approved safety goggles.
PROTECTIVE CLOTHING:
Wear appropriate clothing to prevent any possibility of skin contact. Wear rubber apron.
9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid.
APPEARANCE/PHYSICAL STATE:
Yellowish.
COLOR:
No characteristic odor.
ODOR:
Soluble in water.
SOLUBILITY DESCRIPTION:
212 PRESSURE: 760mmHg
BOILING POINT (掳F, interval):
1.07 TEMPERATURE (掳F): 68
DENSITY/SPECIFIC GRAVITY (g/ml):
9.4
pH-VALUE, CONC. SOLUTION:
10. STABILITY AND REACTIVITY
Normally stable.
STABILITY:
CONDITIONS TO AVOID:
Avoid contact with acids and alkalis. Avoid excessive heat for prolonged periods of time.
HAZARDOUS POLYMERIZATION:
Will not polymerize.
MATERIALS TO AVOID:
Avoid contact with other photographic solutions and/or cleaning compounds.
HAZARDOUS DECOMPOSITION PRODUCTS:
Irritating gases/vapors/fumes of: Ammonia or amines. Sulfur dioxide.
11. TOXICOLOGICAL INFORMATION
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10076 - ILFOTEC LC29 REVISION DATE : 05/07/99
hydroquinone 320; diethanolamine bisulphite 1900; diethanolamine 710;
TOXIC DOSE - LD 50:
1-phenyl-4-methyl-3-pyrazolidone 512; diethylene glycol 5500 mg/kg (oral rat)
TOXICOLOGICAL INFORMATION:
This chemical formulation has not been tested for health effects. Exposure effects listed are based on existing
health data for the individual components which comprise the mixture.
12. ECOLOGICAL INFORMATION
0.1 hydroquinone; 1480 diethanolamine; DTPA >300
LC 50, 96 HRS, FISH, mg/l:
55 diethanolamine; DTPA >10
EC 50, 48 HRS, DAPHNIA, mg/l:
1.0 hydroquinone
IC 50, 72 HRS, ALGAE, mg/l:
ECOLOGICAL INFORMATION:
Not regarded as dangerous for the environment.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS:
Unused and spent solutions may be allowed to be discharged to sanitary sewer by permit IF allowed by local
regulations. Consult your local authority for advice. Waste may have to be pretreated before discharge. Consult
local authorities before discharging any waste to sewer. Do not discharge to septic system. Waste that cannot be
discharged to sewer may have to handled by a licensed hazardous waste contractor.
14. TRANSPORT INFORMATION
To obtain additional information on packaging for shipment refer to the Code of
GENERAL:
Federal Regulations - CFR 49 and your carrier.
U.S. DOT:
0
UN/NA No.:
No DOT label requirement noted
U.S. DOT HAZARD LABEL:
No classification noted.
U.S. DOT CLASS:
Not classified for road transport
INFORMATION ON ROAD TRANSPORT:
SEA TRANSPORT:
Not classified for sea transport
INFORMATION ON SEA TRANSPORT:
AIR TRANSPORT:
Not classified for air transport
INFORMATION ON AIR TRANSPORT:
15. REGULATORY INFORMATION
REGULATORY STATUS OF INGREDIENTS:
NAME: CAS No: TSCA: CERCLA: SARA 302: SARA 313: DSL(CAN):
DIETHYLENEGLYCOL 111-46-6 Yes No No No Yes
DIETHANOLAMINE BISULFITE 63149-47-3 Yes No No No Yes
DIETHANOLAMINE 111-42-2 Yes Yes No Yes Yes
1-PHENYL-4-METHYL-3-PYRAZOLIDONE 2654-57-1 Yes No No No Yes
DIETHYLENETRIAMINE PENTAACETIC 67-43-6 Yes No No No Yes
ACID-
NA5
US FEDERAL REGULATIONS:
TSCA: The ingredients of this product are on the TSCA Inventory.
REGULATORY STATUS:
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Hydroquinone: Clean Air Act, S.111 (40 CFR 60-EPA). DOT Hazardous Mat.
ENVIRONMENTAL LISTING:
Transp. Act (49 CFR). NTP-Annual Plan (DHHS). NIOSH Criteria Documents.
IRPTC-International Register of Potentially Toxic Chemicals (UNEP). OSHA
Chemical Hazard Communic. Std. - Air Contaminants (29CFR1910). ACGIH
Threshold Limit Values. EPA Reportable & Threshold Quantities. SARA Section
302, Extremely Hazardous Substances. SARA Section 313, Toxic Chemicals. SARA
Title III Consolidated Chemical List (302, CERCLA, 313, RCRA).
STATE REGULATIONS:
Florida Hazardous Substance List Massachusetts Extraordinarily Hazardous
STATE REGULATORY STATUS:
Substances List Massachusetts Right-to-Know. New Jersey Right-to-Know. NJ
Environmental Hazardous Substances List NJ Special Hazardous Substances List
Pennsylvania Right-to-Know.
16. OTHER INFORMATION
European Photographic Chemical Industry Code of Practice For Classification And
INFORMATION SOURCES:
Labelling Material Safety Data Sheet, Misc. manufacturers. Safeware Quasar Ltd
USA Regulatory Information ANSI Z400.1-1998 Material Safety Data Sheets -
Preparation
Dr D W Butcher, ILFORD IMAGING Limited, Mobberley, Knutsford, Cheshire,
PREPARED BY:
WA16 7JL. ENGLAND.
16/5/97
REVISION No./Repl. MSDS of:
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