MATERIAL SAFETY DATA SHEETS
MS 61207
For FUJIFILM Product Code: 61207
Description: ENVIRONEG DEVELOPER REPLENISHER LR AC
Carton Identification Code: Cat 990101
Covers 3 part/s:
Bottle Identification Code: Cat
Note: Material Safety Data Sheets must be kept on the premises where chemicals are stored and used.
They must be made readily available to all persons concerned with this chemistry. These may including
transport operators, store persons, workers, machine operators, retail / medical staff, store managers,
building owners and managers, emergency services, and government or industry inspectors.
AUSTRALIA: NEW ZEALAND:
Emergency Information: (02) 9466 2721 (09)414 0400.
FUJIFILM Australia Pty Ltd ABN 80 000 064 433
114 Old Pittwater Road
Brookvale, NSW 2100
Phone: (02) 9466 2600 Fax: (02) 9938 1975
Visit our website: http://www.fujifilm.com.au for the latest version of this MSDS.
Issue Date: April 2006
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 1 of 5
SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
FUJIFILM Australia Pty Ltd ABN 80 000 064 433 FUJIFILM (NZ) Limited
114 Old Pittwater Rd Cnr William Pickering Dr & Bush Rd
Brookvale NSW 2100 Albany, Auckland
Phone: 02 9466 2600 Fax: 02 9938 1975 Phone (09)414 0400
Emergency Information: (02)9466 2721 (Aust), (09)414 0400 (NZ) http://www.fujifilm.com.au/
Substance: Water solution of ingredients.
ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
Trade Name:
990101
Product Code: 61207
Product Use: Photographic reagent.
Creation Date: April, 2006
Revision Date: April, 2006
SECTION 2 - HAZARDS IDENTIFICATION
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R36/38. Irritating to eyes and skin.
Safety Phrases: S26, S37, S24/25. In case of contact with eyes, rinse immediately with plenty of water and contact
a doctor or Poisons Information Centre. Wear suitable gloves. Avoid contact with skin and eyes.
SUSDP Classification: S5
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Liquid - no other details available.
Odour: No data.
Major Health Hazards: irritating to eyes and skin.
Potential Health Effects
Inhalation
Short term exposure: Available data indicates that this product is not harmful. In addition product is unlikely to
cause any discomfort or irritation unless liquid is inhaled.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin.
Other symptoms may also become evident, but should disappear once exposure has ceased if treatment is prompt.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. This product is likely to cause irritation
even in the short or long term if swallowed.
Long Term exposure: No data for health effects associated with long term ingestion.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 2 of 5
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Potassium carbonate 584-08-7 20-40 not set not set
Diethylenetriaminepentaacetic acid, pentasodium salt 140-01-2 1-5 not set not set
Other non hazardous ingredients secret no data not set not set
Water 7732-18-5 to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer
than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the
STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
SECTION 4 - FIRST AID MEASURES
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat
flushing and seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some
water to drink. Contact a Poisons Information Centre or a doctor.
SECTION 5 - FIRE FIGHTING MEASURES
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Only small quantities of decomposition products are expected from this products at temperatures normally achieved in
a fire. This will only occur after heating to dryness.
Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: Does not burn.
Does not burn.
Upper Flammability Limit:
Lower Flammability Limit: Does not burn.
Autoignition temperature: Not applicable - does not burn.
Flammability Class: Does not burn.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 3 of 5
use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area
preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.
Contaminated area may be neutralised by washing with weak or dilute acid. Vinegar, citrus juice and most soft drinks
may be suitable. This material may be suitable for approved landfill. Ensure legality of disposal by consulting
regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature
of contamination when sending contaminated clothing to laundry.
SECTION 7 - HANDLING AND STORAGE
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Store packages of this product in a cool place. Keep containers dry and away from water.
Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10.
Check packaging - there may be further storage instructions on the label.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by NOHSC for any of the known significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:
Physical Description & colour: Liquid - no other details available.
Odour: No data.
Boiling Point: Approximately 100掳 at 100kPa.
C
Freezing/Melting Point: Approximately 0掳 C.
Volatiles: Water component.
Vapour Pressure: 2.37 kPa at 20掳 (water vapour pressure).
C
Vapour Density: No data.
Specific Gravity: 1.407
Water Solubility: Completely soluble in water.
pH: 11.6
Volatility: No data.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 4 of 5
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: Not applicable - does not burn.
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Containers should be
kept dry.
Incompatibilities: acids, zinc, tin, aluminium and their alloys.
Fire Decomposition: Only small quantities of decomposition products are expected from this products at
temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if
combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some
circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur dioxide is a respiratory
hazard) and other sulfur compounds. Most will have a foul odour. Water, potassium compounds, sodium compounds.
Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision,
disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Local Effects:
Target Organs: skin, eyes
Classification of Hazardous Ingredients
Ingredient Risk Phrases
No ingredient mentioned in the List of Designated Hazardous Substances is present in this product at hazardous
concentrations.
SECTION 12 - ECOLOGICAL INFORMATION
This product is unlikely to adversely effect the environment. Salts, acids and bases are typically diluted and
neutralised when released to the environment in small quantities.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. This
product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.
If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these
options is suitable, consider landfill.
SECTION 14 - TRANSPORT INFORMATION
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
SECTION 15 - REGULATORY INFORMATION
AICS: We are unable to verify that all of the ingredients in this product are complaint with NICNAS regulations. There
are several possible reasons why this may occur. If you have any reason to be concerned about this, we suggest you
call us on the number below.
The following ingredient: Potassium carbonate, (an alkaline salt) is mentioned in the SUSDP.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 5 of 5
SECTION 16 - OTHER INFORMATION
This MSDS contains only safety-related information. For other data see product literature.
A more recent version of this MSDS might be found at http://www.fujifilm.com.au/
Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail
ADG Code
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NOS Not otherwise specified
National Toxicology Program (USA)
NTP
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND
HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, April, 2006.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 1 of 5
SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
FUJIFILM Australia Pty Ltd ABN 80 000 064 433 FUJIFILM (NZ) Limited
114 Old Pittwater Rd Cnr William Pickering Dr & Bush Rd
Brookvale NSW 2100 Albany, Auckland
Phone: 02 9466 2600 Fax: 02 9938 1975 Phone (09)414 0400
Emergency Information: (02)9466 2721 (Aust), (09)414 0400 (NZ) http://www.fujifilm.com.au/
Substance: Water solution of ingredients.
ENVIRONEG DEVELOPER REPLENISHER LR AC PART B
Trade Name:
Product Code: 61207 990101
Product Use: Photographic reagent.
Creation Date: April, 2006
Revision Date: April, 2006
SECTION 2 - HAZARDS IDENTIFICATION
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R22, R48/22, R43, R50, R36/38. Harmful if swallowed. Harmful: danger of serious damage to health
by prolonged exposure if swallowed. May cause sensitisation by skin contact. Very toxic to aquatic organisms.
Irritating to eyes and skin.
Safety Phrases: S2, S20, S23, S28, S37, S45, S61, S24/25. Keep out of reach of children. When using, do not eat
or drink. Do not breathe mists. After contact with skin, wash immediately with plenty of soap and water. Wear suitable
gloves. In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre immediately (show the
label where possible). Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Avoid
contact with skin and eyes.
SUSDP Classification: None allocated.
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Liquid. No further details available.
Odour: No data.
Major Health Hazards: may cause serious damage to health by prolonged exposure, irritating to eyes and skin,
harmful if swallowed, possible skin sensitiser.
Potential Health Effects
Inhalation
Short term exposure: Available data indicates that this product is not harmful. However product may be mildly
irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once
sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can
be severe. In addition product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin.
Other symptoms may also become evident, but all should disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 2 of 5
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product
is harmful, but symptoms are not available. However, this product may be irritating to mucous membranes but is
unlikely to cause anything more than transient discomfort.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
bis(hydroxylammonium) sulphate 10039-54-0 15-30 not set not set
Water 7732-18-5 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer
than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the
STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
SECTION 4 - FIRST AID MEASURES
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has
developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about
30 minutes, seek medical advice.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat
flushing and seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
SECTION 5 - FIRE FIGHTING MEASURES
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Only small quantities of decomposition products are expected from this products at temperatures normally achieved in
a fire. This will only occur after heating to dryness.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: Does not burn.
Does not burn.
Upper Flammability Limit:
Lower Flammability Limit: Does not burn.
Autoignition temperature: Not applicable - does not burn.
Flammability Class: Does not burn.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 3 of 5
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include Nitrile, neoprene. Eye/face protective equipment should comprise as a minimum, protective goggles.
If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned below (section 8). Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area
preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.
This material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to
disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination
when sending contaminated clothing to laundry.
SECTION 7 - HANDLING AND STORAGE
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Store packages of this product in a cool place. Make sure that containers of this product are kept tightly
closed. Keep containers dry and away from water. Keep containers of this product in a well ventilated area. Make
sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. Check
packaging - there may be further storage instructions on the label.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: If you believe you may have a sensitisation to this product or any of its declared ingredients, you
should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin
areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: nitrile,
neoprene.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above. Otherwise, not normally necessary.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:
Physical Description & colour: Liquid. No further details available.
Odour: No data.
Boiling Point: Approximately 100掳 at 100kPa.
C
Freezing/Melting Point: Approximately 0掳 C.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 4 of 5
Volatiles: Water component.
Vapour Pressure: 2.37 kPa at 20掳 (water vapour pressure).
C
Vapour Density: No data.
Specific Gravity: 1.156
Water Solubility: Completely soluble in water.
pH: 3.20
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: Not applicable - does not burn.
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Keep containers tightly
closed. Containers should be kept dry. Keep containers and surrounding areas well ventilated.
Incompatibilities: oxidising agents.
Fire Decomposition: Only small quantities of decomposition products are expected from this products at
temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if
combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some
circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur dioxide is a respiratory
hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces
headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and
unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.
Bis(hydroxylammonium) Sulphate is Classed by NOHSC as a potential sensitiser by skin contact.
Classification of Hazardous Ingredients
Ingredient Risk Phrases
Bis(hydroxylammonium) Sulphate Conc>=25%: Xn; R22; R48/22; R36/38; R43.
SECTION 12 - ECOLOGICAL INFORMATION
This product is very toxic to aquatic organisms. No further details available.
Daphnia: EC50 1.6mg/L LC50 (Pimephales promelas, 96h) = 7,2 mg/L
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. This
product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.
If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these
options is suitable, consider landfill.
SECTION 14 - TRANSPORT INFORMATION
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 5 of 5
SECTION 15 - REGULATORY INFORMATION
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
SECTION 16 - OTHER INFORMATION
This MSDS contains only safety-related information. For other data see product literature.
A more recent version of this MSDS might be found at http://www.fujifilm.com.au/
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
Chemical Abstracts Service Registry Number
CAS number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
National Occupational Health and Safety Commission
NOHSC
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
Standard for the Uniform Scheduling of Drugs & Poisons
SUSDP
UN Number United Nations Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND
HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, April, 2006.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 1 of 6
SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
FUJIFILM Australia Pty Ltd ABN 80 000 064 433 FUJIFILM (NZ) Limited
114 Old Pittwater Rd Cnr William Pickering Dr & Bush Rd
Brookvale NSW 2100 Albany, Auckland
Phone: 02 9466 2600 Fax: 02 9938 1975 Phone (09)414 0400
Emergency Information: (02)9466 2721 (Aust), (09)414 0400 (NZ) http://www.fujifilm.com.au/
Substance: Water solution of ingredients.
ENVIRONEG DEVELOPER REPLENISHER LR AC C
Trade Name:
Other Names: This Part C of a 3 part System
Product Code: 61207 990101
Product Use: Photographic reagent.
Creation Date: April, 2006
Revision Date: April, 2006
SECTION 2 - HAZARDS IDENTIFICATION
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R25, R48/22, R34, R43, R36/37/38, R50/53. Toxic if swallowed. Danger of serious damage to health
by prolonged exposure if swallowed. Causes burns. May cause sensitisation by skin contact. Irritating to eyes,
respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic
environment.
Safety Phrases: S20, S23, S28, S36, S38, S60, S61, S1/2, S24/25. When using, do not eat or drink. Do not
breathe mists. After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective
clothing. In case of insufficient ventilation, wear suitable respiratory equipment. This material and its container must
be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data
Sheets. Keep locked up and out of reach of children. Avoid contact with skin and eyes.
SUSDP Classification: S6
ADG Classification: Class 8, Sub risk 6.1 (CORROSIVE LIQUID, TOXIC, N.O.S.)
UN Number: 2922
Emergency Overview
Physical Description & colour: Liquid - no other data available.
Odour: No data.
Major Health Hazards: toxic if swallowed, causes burns, irritating to eyes, respiratory system and skin, possible
skin sensitiser.
Potential Health Effects
Inhalation
Short term exposure: product is an inhalation irritant. Symptoms may include headache, irritation of nose and
throat and increased secretion of mucous in the nose and throat. Other symptoms may also become evident, but they
should disappear after exposure has ceased.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once
sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can
be severe. In addition product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin.
Other symptoms may also become evident, but all should disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 2 of 6
Eye Contact:
Short term exposure: In addition product is an eye irritant. Symptoms may include stinging and reddening of eyes
and watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product
is toxic, but further symptoms are not available. However, this product is an oral irritant. Symptoms may include
burning sensation and reddening of skin in mouth and throat. Other symptoms may also become evident, but all
should disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
2-((4-amino-3-methylphenyl)ethylamino)ethanol sulphate
25646-77-9 30-50 not set not set
Water 7732-18-5 to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer
than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the
STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
SECTION 4 - FIRST AID MEASURES
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: If irritation occurs, contact a Poisons Information Centre, or call a doctor. Remove source of
contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained
personnel, preferably on a doctor's advice. In severe cases, symptoms of pulmonary oedema can be delayed up to 48
hours after exposure.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat
flushing and seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting; rinse mouth thoroughly with water and contact a Poisons
Information Centre, or call a doctor at once. Give activated charcoal if instructed.
SECTION 5 - FIRE FIGHTING MEASURES
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
This product is likely to decompose only after heating to dryness, followed by further strong heating.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. water fog. Water fog
or fine spray is the preferred medium for large fires. Ensure that no spillage enters drains or water courses.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 3 of 6
Fire Fighting: Immediately evacuate the area of unnecessary personnel.
Flash point: Does not burn.
Upper Flammability Limit: Does not burn.
Lower Flammability Limit: Does not burn.
Autoignition temperature: Not applicable - does not burn.
Does not burn.
Flammability Class:
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate
the spill area and deny entry to unnecessary and unprotected personnel. Immediately call the Fire Brigade. Wear full
protective chemically resistant clothing including eye/face protection, gauntlets and self contained breathing
apparatus. See below under Personal Protection regarding Australian Standards relating to personal protective
equipment. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should
comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely to build up
in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this
product. However, if you have any doubts consult the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Because of the toxicity of this product, special personal care should be taken in any cleanup operation.
Because of the corrosiveness of this product, special personal care should be taken in any cleanup operation. Sweep
up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly.
Recycle containers wherever possible after careful cleaning. After spills, wash area preventing runoff from entering
drains. If a significant quantity of material enters drains, advise emergency services. Contaminated area may be
neutralised by washing with weak or dilute alkali. Baking soda, washing soda and limestone are suitable. This
material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to disposal.
Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when
sending contaminated clothing to laundry.
SECTION 7 - HANDLING AND STORAGE
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Store in a cool, well ventilated area. Check containers periodically for corrosion and leaks.
Containers should be kept closed in order to minimise contamination. Make sure that the product does not come into
contact with substances listed under "Incompatibilities" in Section 10. If you keep more than 10000kg or L of
Dangerous Goods of Packaging Group III, you may be required to license the premises or notify your Dangerous
Goods authority. If you have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify
your obligations. Check packaging - there may be further storage instructions on the label.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 4 of 6
Skin Protection: If you believe you may have a sensitisation to this product or any of its declared ingredients, you
should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin
areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:
Physical Description & colour: Liquid - no other data available.
Odour: No data.
Boiling Point: Approximately 100掳 at 100kPa.
C
Freezing/Melting Point: Approximately 0掳 C.
Volatiles: Water component.
Vapour Pressure: 2.37 kPa at 20掳 (water vapour pressure).
C
Vapour Density: No data.
Specific Gravity: 1.19
Water Solubility: Completely soluble in water.
pH: Corrosive pH 2.2
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: Not applicable - does not burn.
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: Most strong acids react with inorganic and organic bases such as amines to form salts. They also react
with many metals liberating hydrogen gas. These reactions are often rapid and sometimes liberate much heat. They
can also decompose many organic materials such as esters, in a reaction called hydrolysis.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Keep containers tightly
closed.
Incompatibilities: bases, oxidising agents, zinc, tin, aluminium and their alloys.
Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong
heating. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds,
and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur
dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide
poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment,
and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.
2-((4-amino-3-methylphenyl)ethylamino)ethanol Sulphate is Classed by NOHSC as a potential sensitiser by skin
contact.
LD50 (Oral), Rat 2-((4-amino-3-methylphenyl)ethylamino)ethanol sulphate = 35/g/kg
Classification of Hazardous Ingredients
Ingredient Risk Phrases
2-((4-amino-3-methylphenyl)ethylamino)ethanol Sulphate Conc>=25%: T; R25; R48/22; R43
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 5 of 6
SECTION 12 - ECOLOGICAL INFORMATION
Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. Insufficient data to
be sure of biodegradation status of product as supplied.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. This
product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.
If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these
options is suitable, consider landfill.
SECTION 14 - TRANSPORT INFORMATION
ADG Code: 2922, CORROSIVE LIQUID, TOXIC, N.O.S.
Hazchem Code: 2X
Special Provisions: SP109, SP129, SP274
Dangerous Goods Class: Class 8, Corrosive Substances.
Sub Risk: Class 6.1, Toxic Substances.
Packaging Group: III
Packaging Method: 3.8.8
Class 8 Corrosive Substances shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6
(Toxic Substances where the Toxic Substances are cyanides and the Corrosives are acids), 7 (Radioactive
Substances), Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the
same freight container with Classes 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Poisonous
Gases), 3 (Flammable liquids), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 6 (Toxic
Substances except where the Toxic Substances are cyanides and the Corrosives are acids) and 9 (Miscellaneous
Dangerous Goods).
SECTION 15 - REGULATORY INFORMATION
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredient: 2-((4-amino-3-methylphenyl)ethylamino)ethanol sulphate, (a phenylenediamine derivative) is
mentioned in the SUSDP.
SECTION 16 - OTHER INFORMATION
This MSDS contains only safety-related information. For other data see product literature.
A more recent version of this MSDS might be found at http://www.fujifilm.com.au/
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
Emergency action code of numbers and letters that provide information to
Hazchem Code
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
Not otherwise specified
NOS
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
United Nations Number
UN Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND
HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: ENVIRONEG DEVELOPER REPLENISHER LR AC PART A
This revision issued: May, 2006
Emergency Information: 02 9466 2721 (Aust), (09)414 0400 (NZ)
Page: 6 of 6
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, April, 2006.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: 02 9466 2600
FUJIFILM (NZ) Limited Phone (09)414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
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