MSDS Material Safety Data Sheet


File Name: gadiv_com---Fumaric.asp
              SAFETY DATA SHEET

Trade Name: FUMARIC ACID Page 1 of 4

1: Identification
Commercial Product Name: Fumaric Acid
Manufacturer: Gadiv Petrochemical Industries LtD.
P.O.B 32 Haifa
Israel 31000
Tel: +972-4-8788020
Fax: +972-4-8788018
Tel: +972-4-8788955
Fax: +972-4-8788034

2: Composition/Information on Ingredients

Chemical characterization: Colorless, odorless powder.
Hazardous ingredients:

Chemical name CAS-No EINECS-No Concentration % Classification
Fumaric acid 110-17-8 203-743-0 100 R36, Xi
(See full text of R-phrases in chapter 16.)

3: Hazards Identification

Human health hazard:
Irritating to eyes.

4: First Aid Measures
Symptoms Irritating to skin, eyes and respiratory tract.
In high concentrations, may cause coughing, sneezing and labored breathing.
Ingestion may cause nausea, vomiting, cramps and diarrhea.

Skin contact: Immediately remove contaminated clothing and shoes. Rinse with large amounts of
water for at least 10 minutes. Refer for medical attention as necessary. Do NOT use
solvents or thinners.

Eyes contact: Rinse open eyes under running water for at least 15 minutes. Refer for medical
attention. Never give anything by mouth to an unconscious person.

Ingestion: Do NOT induce vomiting. If victim is conscious, give three cups of water. Refer for
medical attention as necessary. Do not administer liquids to unconscious persons.

Inhalation: Using protective gear, evacuate victim from site of exposure. Have victim lie or sit

2917/002 Produced by Haz-Mat Ltd.

Trade Name: FUMARIC ACID Page 2 of 4

comfortably. If he has difficulty breathing, have him sit with back straight and
administer oxygen, if possible. If victim is unconscious, perform resuscitation and then
immediately transfer to medical personnel.

5: Fire-Fighting Measures

Suitable extinguishing media: For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
Use supplier-air breathing equipment for enclosed or confined spaces or as otherwise needed.

Wear full protective cloths and self-contained breathing apparatus.

6: Accidental Release Measures

Wear full protective clothing . Evacuate personnel. Avoid generating dusty conditions. Provide ventilation.
Sweep up, and then place into a suitable container for later disposal. Prevent the product from spreading
into the environment

7: Handling and Storage

Keep away from incompatible materials (see section 10).

Safety phrases
Keep out of reach of children.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Avoid contact with skin and eyes.
Do not breathe dust.

Storage: Store in a cool, dry, well-ventilated area.
Store separately from oxidizing agents.

8: Exposure Control and Personal Protection

Threshold values: Not available

IDLH: (Immediately Dangerous to Life and Health): Not available

Personal Protective equipment: Generally, personal protection is a function of exposure. It is
recommended to use working shoes, working clothes or lab coat. Working should be done in a well-
ventilated area. In addition: mask and filter for organic compounds type A, gloves, safety goggles.
Respiratory protection: Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Wear appropriate respirator when ventilation is inadequate.
Skin protection: Rubber, neoprene or vinyl gloves and protective clothing.
In case of an emergency: Full protective gear and a self contained breathing apparatus should be used,
according to the severity.

2917/002 Produced by Haz-Mat Ltd.

Trade Name: FUMARIC ACID Page 3 of 4

9: Physical and Chemical Properties:

General information:
Form: Solid
Color: White
Odour: Not available

Important health, safety and environmental information:
Boiling point 掳C: 165
Freezing point 掳C: 287
Molecular weight: 116.02
Density g/cm3 (20掳C): 1.63
Vapor density (air=1): 4.03
Vapor pressure (mmHg)(135掳C): 1. 7
Solubility (in water): Slightly soluble in water.
pH: 2.6
Flash point 掳C: Not applicable
Auto-ignition temperature 掳C: 740
Viscosity (20掳C): N/A

10: Stability and Reactivity

Hazardous polymerization: Will not occur.

Chemical reactivity: Stable under ordinary use. Keep away from strong oxidizers and nitric acid.

Hazardous decomposition products: On fire emits toxic and irritating fumes.

11: Toxicological Information

Fumaric acid
LD50 (oral rat) 9,300 mg/kg

Carcinogenicity: No data available

12: Ecological Information

Environmental hazards: No data available
Biodegrability: Readily biodegradable

2917/002 Produced by Haz-Mat Ltd.

Trade Name: FUMARIC ACID Page 4 of 4

13: Disposal Considerations

Not regulated as a hazardous material

14: Transport Information

UN recommendations: Not regulated as a hazardous material

Sea transport: Not regulated as a hazardous material

Air transport: Not regulated as a hazardous material

Estimated NFPA: H: 1 F: 1 R: 0

15: Regulatory Information
Labeling in accordance with EC directives

Symbol and indicating of hazard: Xi

R36: Irritating to eyes

S02: Keep out of reach of children.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24/25: Avoid contact with skin and eyes.
S22: Do not breathe dust.
According to local regulations.

16: Other Information

Full text of R-phrases with No. appearing in section 2:
R36: Irritating to eyes

Date of issue: 31TH May 2006

The information herein is based on the present state of our knowledge. It is believed to be correct but is not necessarily all
inclusive and shall be used only as a guide. BAZAN Ltd, and Haz-Mat Ltd. shall not be held liable for any damage resulting from
handling or from contact with the above product. For further information, contact BAZAN Ltd or contact Haz-Mat at

2917/002 Produced by Haz-Mat Ltd.

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