MSDS4063
Page 1 of 4
Nickel Cadmium Batteries
08/12/04
The information contained within is provided for your information only. This battery is an article pursuant to 29 CFR 1910.1200 and,
as such, is not subject to the OSHA Hazard Communication Standard requirement for preparation of a material safety data sheet. The
information and recommendations set forth herein are made in good faith and are believed to be accurate as of the date of
preparation. However, EVEREADY BATTERY COMPANY, INC., MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT
TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FROM RELIANCE ON IT.
PRODUCT SAFETY DATA SHEET
PRODUCT NAME: ENERGIZER ACCU Rechargeable Battery Type No.: Volts:
TRADE NAME: Nickel Cadmium Battery Approximate Weight:
CHEMICAL SYSTEM: Nickel-Cadmium Designed for Recharge: Yes
SECTION I 鈥? MANUFACTURER INFORMATION:
Manufactured for: Telephone Numbers for Information:
Eveready Battery Company, Inc. 440-835-7368
25225 Detroit Road. 800-383-7323 (USA)
Westlake, OH 44145
Date Prepared: August 12, 2004
SECTION II - HAZARDOUS INGREDIENTS
IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion
products could be harmful.
MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.
3
3
Cadmium 0.01 mg/m TWA (as Cd) 13-22
5 g/m TWA (as Cd)
as cadmium metal
3
(CAS# 7440-43-9) 0.002 mg/m TWA (as Cd
as cadmium oxide respirable fraction)
(CAS# 1306-19-0)
as cadmium hydroxide
(CAS# 21041-95-2)
3 3
Cobalt 0.1 mg/m TWA (as Co) 0.02 mg/m TWA (as Co) 0.5-2
as cobalt metal
(CAS# 7440-48-4)
as cobalt oxide
(CAS# 1307-96-6)
as cobalt hydroxide
(CAS# 21041-93-0)
MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.
Lithium Hydroxide None established None established 0-4
(CAS# 1310-65-2)
3 3
Nickel 1 mg/m TWA (as Ni) 1.5 mg/m TWA (as inhalable Ni) 20-32
as nickel metal
(CAS# 7440-02-0)
as nickel oxide 0.2 mg/m3 TWA (as inhalable Ni,
(CAS# 1313-99-1) insoluble compounds)
as nickel hydroxide
(CAS# 12054-48-7)
3
Potassium Hydroxide None established 2 mg/m Ceiling 0-4
(CAS# 1310-58-3)
漏2004 Eveready Battery Company, Inc.
Page 2 of 4
Nickel Cadmium Batteries
08/12/04
3 3
Sodium Hydroxide 2 mg/m TWA 2 mg/m Ceiling 0-4
(CAS# 1310-73-2)
SECTION III - FIRE AND EXPLOSION HAZARD DATA
If fire or explosion occurs when batteries are on charge, shut off power to charger.
In case of fire, it is permissible to use any class of extinguishing medium on these batteries or their packing materials. Cool
exterior of batteries if exposed to fire to prevent rupture.
Fire fighters should wear self-contained breathing apparatus. Nickel-cadmium batteries involved in a fire can vent and produce
toxic fumes including nickel, nickel oxides, cadmium, cadmium oxides, and cobalt oxides.
SECTION IV - HEALTH HAZARD DATA
Under normal conditions of use, the battery is hermetically sealed.
Ingestion: Swallowing a battery can be harmful.
Contents of an open battery can cause serious chemical burns of mouth, esophagus, and gastrointestinal tract. Contents
include toxic cadmium and cadmium compounds which can cause excessive salivation, choking, nausea, persistent vomiting,
diarrhea, abdominal pain, dizziness, faintness, unconsciousness, and possible liver and kidney injury.
If battery or open battery is ingested, do not induce vomiting or give food or drink. Seek medical attention immediately.
CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up (202-625-3333) collect, day or night.
Inhalation: Contents of an open battery can cause respiratory irritation. Cadmium oxide fumes can cause metal fume fever.
Hypersensitivity to nickel can cause allergic pulmonary asthma. Provide fresh air and seek medical attention.
Skin Contact: Contents of an open battery can cause skin irritation and/or chemical burns. Cobalt, cobalt compounds, nickel, and
nickel compounds can cause skin sensitization and an allergic contact dermatitis. Remove contaminated clothing and wash
skin with soap and water. If a chemical burn occurs or if irritation persists, seek medical attention.
Eye Contact: Contents of an open battery can cause severe irritation and chemical burns. Immediately flush eyes thoroughly with
water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention.
Note: Nickel, nickel compounds, cadmium, cadmium compounds, cobalt, and cobalt compounds are listed as possible carcinogens
by International Agency for Research on Cancer (IARC) or National Toxicology Program (NTP).
SECTION V - PRECAUTIONS FOR SAFE HANDLING AND USE
Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life.
Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Eveready
Battery Company representative for precautionary suggestions. Batteries normally evolve hydrogen which, when combined
with oxygen from the air, can produce a combustible or explosive mixture unless vented. If such a mixture is present, short
circuits, high temperature, or static sparks can cause an ignition.
Do not obstruct safety release vents on batteries. Encapsulation (potting) of batteries will not allow cell venting and can cause
high pressure rupture.
Handling: Accidental short circuit for a few seconds will not seriously affect the battery. However, this battery is capable of
delivering very high short circuit currents. Prolonged short circuits will cause high cell temperatures which can cause skin
burns. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, and metal covered tables or metal
belts used for assembly of batteries into devices.
漏2004 Eveready Battery Company, Inc.
Page 3 of 4
Nickel Cadmium Batteries
08/12/04
If soldering or welding to the battery is required, use of tabbed batteries is recommended. If this cannot be done, consult your
Eveready Battery Company representative for proper precautions to prevent seal damage or short circuit.
Do not open battery. The negative electrode material may be pyrophoric. Should an individual cell from a battery become
disassembled, spontaneous combustion of the negative electrode is possible. This is much more likely to happen if the
electrode is removed from its metal container. There can be a delay between exposure to air and spontaneous combustion.
Charging: This battery is made to be charged many times. Because it gradually loses its charge over a few months, it is good
practice to charge battery before use. Use recommended charger. Improper charging can cause heat damage or even high
pressure rupture. Observe proper charging polarity.
Labeling: If the Eveready label or package warnings are not visible, it is important to provide a package and/or device label stating:
Nickel Cadmium Consumer Round Cells
AA and larger
WARNING: CHARGE ONLY WITH STANDARD HOUSEHOLD NICKEL CADMIUM BATTERY CHARGERS. DO NOT OPEN
BATTERY, DISPOSE OF IN FIRE, PUT IN BACKWARDS, MIX WITH OTHER BATTERY TYPES OR SHORT CIRCUIT - MAY
EXPLODE, LEAK OR GET HOT CAUSING PERSONAL INJURY.
AAA and smaller
WARNING: (1) KEEP AWAY FROM SMALL CHILDREN. IF SWALLOWED, PROMPTLY SEE DOCTOR; HAVE DOCTOR
PHONE (202) 625-3333 COLLECT. (2) CHARGE ONLY WITH STANDARD HOUSEHOLD NICKEL CADMIUM BATTERY
CHARGERS. DO NOT OPEN BATTERY, DISPOSE OF IN FIRE, PUT IN BACKWARDS, MIX WITH OTHER BATTERY TYPES
OR SHORT CIRCUIT - MAY EXPLODE, LEAK OR GET HOT CAUSING PERSONAL INJURY.
Nickel Cadmium Industrial Round Cells
(where charge rate is indicated on label)
WARNING: CHARGE ONLY AT SPECIFIED CHARGE RATE. DO NOT OPEN BATTERY, DISPOSE OF IN FIRE, PUT IN
BACKWARDS, MIX WITH OTHER BATTERY TYPES OR SHORT CIRCUIT - MAY EXPLODE, LEAK OR GET HOT CAUSING
PERSONAL INJURY.
All Nickel Cadmium Packs (OEM and Branded)
and Nickel Cadmium OEM Round Cells
WARNING: USE ONLY WITH SPECIFIED CHARGERS ACCORDING TO CHARGER MANUFACTURER'S INSTRUCTIONS. DO
NOT OPEN BATTERY, DISPOSE OF IN FIRE OR SHORT CIRCUIT - MAY EXPLODE, LEAK OR GET HOT CAUSING
PERSONAL INJURY.
Disposal: Dispose in accordance with all applicable federal, state, and local regulations.
When generated as a waste, these batteries may be regulated by the Resource Conservation and Recovery Act (RCRA) as a
D006 (cadmium) hazardous waste.
Note: Recycling of this product may be available. Contact your local recycling office or call toll free at 1-800-8-BATTERY for
information about how and where you can recycle used nickel cadmium batteries.
The Federal Universal Waste Rule cited at 40 CFR Part 273 governs nickel cadmium battery recycling and may be applicable in
your state.
漏2004 Eveready Battery Company, Inc.
Page 4 of 4
Nickel Cadmium Batteries
08/12/04
SECTION VI - SPECIAL PROTECTION INFORMATION
Ventilation Requirements: Not necessary under normal conditions.
Respiratory Protection: Not necessary under normal conditions.
Eye Protection: Not necessary under normal conditions. Wear safety glasses with side shields if handling an open or leaking
battery.
Gloves: Not necessary under normal conditions. Use neoprene or natural rubber gloves if handling an open or leaking battery.
Open Battery Storage: Battery should not be opened. Should a cell become disassembled, the electrode should be stored in a
fireproof cabinet, away from combustibles.
SECTION VII - REGULATORY INFORMATION
The transportation of dry cell batteries manufactured or sold by Eveready Battery Company is not regulated by the U.S. Department
of Transportation or the major international regulatory bodies.
SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and
Community Right-To-Know Act.
漏2004 Eveready Battery Company, Inc.
IS145
RECHARGEABLE BATTERY RECYCLE NOTICE
Some states and cities have enacted laws related to the proper disposal of
Rechargeable batteries. In an effort to reduce the amount of rechargeable batteries
being disposed of as solid waste we are required to notify you of recycling
opportunities where there is no cost to you.
The Rechargeable Battery Recycling Corporation (RBRC) is an organization funded
by rechargeable battery manufacturers whose mission is to implement programs to
collect rechargeable batteries for recycling. For more information on how to recycle
your rechargeable batteries, at no cost to you, please visit the web site listed below.
This Rechargeable Battery law does not apply to household alkaline batteries, watch
or hearing aid button batteries or automobile batteries.
www.call2recycle.org
|