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MSDS Material Safety Data Sheet
CAS

542-16-5

File Name: gfschemicals_com---1113msds.asp
 
                                              GFS CHEMICALS, INC.

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                                     MATERIAL SAFETY DATA SHEET

                                                                                                                        1113

                                                   ANILINE SULFATE



CHEMICAL NAME & SYNONYMS                                                             DOT CLASS         SARA TITLE 313

Aniline sulfate; Aniline hemisulfate;                                                6.1/III           Yes

Benzeneamine, sulfate                                                                TSCA listed - Yes



FORMULA                    REPORTABLE QUANTITY                                       F.W.                CAS#

(C6H5NH2)2.H2SO4                       N/A                                           284.34              542-16-5



PHYSICAL DATA

Decomposes before melting; Specific gravity 1.38; Water soluble 6 g/100 ml.



APPEARANCE & ODOR

Colorless to white crystalline powder. Darkens on exposure to light or air. Characteristic odor.

REACTIVITY & CONDITIONS TO AVOID

Stable. No hazardous self-reactivity. Incompatible with oxidizers, strong acids. Spontaneous ignition with red fuming

nitric acid and with sodium.



FIRE HAZARDS

Will be consumed in a general fire. Emits toxic smoke. Firefighters wear SCBA.

EXTINGUISHER                                                                   FLASHPOINT                LEL     UEL

Water Spray, CO2, dry chemical.                                                N/A                       N/A     N/A



HEALTH HAZARDS

Skin and eye irritant. Limited data found for sulfate salt. Consider poisonous via all routes from comparison with parent

compound (aniline) and hydrochloride analog. Aniline affects ability of blood to carry oxygen. Symptoms of exposure

include bluish lips, headache, nausea, confusion, dizziness, shock, respiratory paralysis and death. LD50 (oral-rat aniline)

250 mg/kg. LC50 (inhl-mouse aniline) 175 ppm (7 hr). OSHA PEL (aniline): TWA 5 ppm; ACGIH TLV (aniline): TWA 2

ppm. Warning: while aniline sulfate is not specifically listed, aniline and aniline hydrochloride are known to the state of

California to cause cancer.



SPECIAL PRECAUTIONS

Wear goggles, rubber gloves and protective clothing. Use only in well ventilated area or use suitable respirator. Eyewash

and shower nearby. Store in cool, well ventilated area away from fire hazards and oxidizers. Protect from light.



FIRST AID

Wash skin and eyes thoroughly with water. Wash clothing before reuse, discard shoes if contaminated. Get medical

attention. If swallowed, give water or milk and induce vomiting. Call a physician. For inhalation, remove to fresh air. If

breathing is difficult, give oxygen. Use artificial respiration as needed. Get immediate medical assistance.



SPILLS & LEAKS

Ventilate area. Remove sources of ignition. Use protective clothing and respirators. Contain spill and take up in absorbent.

Disposal to incinerator or other suitable hazardous waste.



CATALOG #                                                            PREPARED BY                                DATE

1113                                                                            MDM                      February 7, 2000
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