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MSDS Material Safety Data Sheet
CAS

64742-95-6
25551-13-7
25550-14-5
99-87-6
1330-20-7

File Name: gadiv_com---Solgad_100.asp
              SAFETY DATA SHEET


Trade Name: SOLGAD 100 Page 1 of 6

1: Identification
Commercial Product Name: SOLGAD 100
Proper Shipping Name: Alkyl (C3-C 4) Benzenes
Manufacturer: Gadiv Petrochemical Industries LtD.
P.O.B 32 Haifa
Israel 31000
Management
Tel: +972-4-8788020
Fax: +972-4-8788018
Marketing
Tel: +972-4-8788955
Fax: +972-4-8788034



2: Composition/Information on Ingredients

Chemical characterization: Liquid, colorless, aromatic odor.
Material formal name: Light Solvent Naphtha (aromatic).
CAS Number: 64742-95-6
EINECS Number: 265-199-0
Hazardous ingredients:

Chemical name CAS-No EINECS-No Concentration % Classification
Benzene trimethyl isomers 25551-13-7 247-099-9 55% R10, R20,
R36/37/38, R51/53
Xn, N
Benzene ethyl methyl 25550-14-5 247-093-6 9%
isomers
Benzene propyl isomers - - 11% R10, R37, R51/53,
R65 Xn, N
p-isopropyltoluene 99-87-6 202-796-7 0.6% R10, R36/37/38
Xylenes 1330-20-7 215-535-7 0.2% R10, R20/21, R38
Xn
(See full text of R-phrases in chapter 16.)



3: Hazards Identification


R10: flammable.
Human health hazard:
R20 : Harmful by inhalation.
R36/37/38 : Irritating to eyes, respiratory system and skin.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.



2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 100 Page 2 of 6


4: First Aid Measures

Symptoms: Harmful by inhalation. Irritating to eyes, respiratory system and skin.
High concentrations may cause headache, dizziness, drowsiness, confusion and loss
of consciousness.

Skin contact: Immediately remove contaminated clothing and shoes. Rinse with large amounts of
water for at least 10 minutes. Get medical attention as necessary. Do NOT use
solvents or thinners.


Eyes contact: Rinse open eyes under running water for at least 15 minutes. Get medical attention.


Ingestion: Do NOT induce vomiting. If victim is conscious, give three cups of water. Get medical
attention as necessary. Never give anything by mouth to an unconscious person.


Inhalation: Using protective gear, evacuate victim from site of exposure. Have victim lie or sit
comfortably. If he has difficulty breathing, have him sit with back straight and
administer oxygen, if possible. If victim is unconscious, perform resuscitation and then
immediately transfer to medical personnel.


5: Fire-Fighting Measures


Flammability: Flammable.
Suitable extinguishing media: foam, dry chemicals.
Water may be ineffective. Use water spray to cool fire-exposed containers, to dilute liquid, and control
vapor
Vapors can flow along surfaces to distant ignition source and flash back.
Use supplier-air breathing equipment for enclosed or confined spaces or as otherwise needed.
Wear full protective cloths and self-contained breathing apparatus.


6: Accidental Release Measures


Wear full protective clothing . Evacuate personnel.
Flammable liquid. Eliminate all sources of ignition. Stop the leakage if you can do so without risk. Absorb
the chemical onto sand, vermiculite, or any other non-combustible absorbent. Scoop into containers for
later disposal. Check local regulations before dumping waste or disposing of liquids in drainage system.
Prevent the product from spreading into the environment.



7: Handling and Storage
Keep away from incompatible materials (see section 10).

Flammable liquid. Keep away from flame, sparks, static electricity, friction or any other heat source
that may cause ignition. Keep in well-ventilated area. In areas of storage and use, it is advisable that
the electrical system will be adjusted to working in an explosive atmosphere.




2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 100 Page 3 of 6

Safety phrases
Avoid contact with skin and eyes.
Do not breathe vapour.
Avoid release to the environment. Refer to special instructions/Safety data sheets.

Storage: Store in a cool, dry, well-ventilated area.
Store separately from strong oxidizing agents.



8: Exposure Control and Personal Protection

Threshold values:
TtrimethylBenzene- isomers
ACGIH-TLV 25 ppm (TWA)
NIOSH-REL 25 ppm (TWA)
OSHA-PEL 25 ppm (TWA)

Isopropyl benzene
ACGIH-TLV 50 ppm (TWA)
NIOSH-REL 50 ppm (TWA)
OSHA-PEL 50 ppm (TWA)

Xylene
ACGIH-TLV 100 ppm (TWA) 150 ppm (STEL)
OSHA-PEL 100 ppm (TWA)
NIOSH-REL 100 ppm (TWA) 150 ppm (STEL)
MAK-GER 100 ppm (TWA)
TLV-ISRAEL 100 ppm (TWA) 150 ppm (STEL)


IDLH: (Immediately Dangerous to Life and Health):
900 ppm (Xylene)

Personal Protective equipment: Generally, personal protection is a function of exposure. It is
recommended to use working shoes, working clothes or lab coat. Working should be done in a well-
ventilated area. In addition: mask and filter for organic compounds type A, gloves, safety goggles.
Respiratory protection: Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Wear appropriate respirator when ventilation is inadequate.
In case of an emergency: Full protective gear and a self contained breathing apparatus should be used,
according to the severity.




2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 100 Page 4 of 6

9: Physical and Chemical Properties:
General information:
Form: liquid
Color: colorless
Odour: aromatic


Important health, safety and environmental information:
Boiling point 掳C: 155-181
Freezing point 掳C: -50
Molecular weight: 127
Density g/cm3 (5掳C): 0.877
Vapor density (air=1): 7.50
Vapor pressure (mmHg)(20掳C) : 1.358
Solubility (in water): Insoluble in water
pH: N/A
Flash point 掳C: 41.0
Auto-ignition temperature 掳C: above 450
LEL: 0.80% UEL: 7.00%
Viscosity (25掳C): 0.92 cSt.



10: Stability and Reactivity


Hazardous polymerization: Will not occur.

Chemical reactivity: Stable under ordinary use. Keep away from strong oxidizers, heat and open flame.

Hazardous decomposition products: On fire emits toxic and irritating fumes.



11: Toxicological Information

1,2,4-Trimethylbenzene
LD50 (oral rat) 5000 mg/kg
LD50 (Inhalation rat) 18000 mg/m3/4H

1,3,5-Trimethylbenzene
LD50 (oral rat) 5000 mg/kg
LD50 (Inhalation rat) 24000 mg/m3/4H

Isopropyl benzene
LD50 (oral rat) 1400 mg/kg
LD50 (Inhalation rat) 39000 mg/m3/4H




2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 100 Page 5 of 6

n-Propylbenzene
LD50 (oral rat) 6040 mg/kg
LD50 (Inhalation rat) 65000 ppm/2H


p-isopropyltoluene
LD50 (oral rat) 4750 mg/kg

Xylene
LD50 (oral rat) 4,300 mg/kg
LC50 (inhalation rat) 5000 ppm (4H)
LD50 (oral mouse) 2119 mg/kg

Carcinogenicity:
Xylene:
IARC-GROUP 3: Unclassifiable as to carcinogenic to humans.
EPA-GROUP D: Not classified.
ACGIH A4: Not classifiable as a Human Carcinogen.




12: Ecological Information

Environmental hazards: Toxic to aquatic organisms may cause long-term adverse effects in the aquatic
environment.
Biodegradability: No data available



13: Disposal Considerations


According to the Israeli regulations, a holder of this waste must evacuate it as soon as possible and not
later than 6 months after the production of the waste, to the Ramat-Hovav waste site. The waste should
be packed and transported according to the regulations. For packing group and transport classification of
the waste refer to section 14.




14: Transport Information

UN recommendations: UN 1268
Proper shipping name: PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.
Class 3
Packing group: III
LABEL: 'FLAMMABLE LIQUIDS鈥? : 3Y

Sea transport:

IMDG: UN 1268

2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 100 Page 6 of 6

Class: 3
Proper technical name: PETROLEUM DISTILLATES, N.O.S.
Packing group: III

Air transport:
ICAO/IATA: UN 1268
Class: : 3
Proper technical name: PETROLEUM DISTILLATES, N.O.S.
Packing group: III

Estimated NFPA: H: 2 F: 2 R: 0


15: Regulatory Information
Labeling in accordance with EC directives




Symbol and indicating of hazard: Xn, N

R-phrases:
R10: flammable.
R20 : Harmful by inhalation.
R36/37/38 : Irritating to eyes, respiratory system and skin.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrases:
S24/25: Avoid contact with skin and eyes.
S23: Do not breathe vapour.
S61: Avoid release to the environment. Refer to special instructions/Safety data sheets.



16: Other Information


Full text of R-phrases with No. appearing in section 2:
R10: flammable.
R20 : Harmful by inhalation.
R20/21: Harmful by inhalation and in contact with skin.
R36/37/38 : Irritating to eyes, respiratory system and skin.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65: Harmful: may cause lung damage if swallowed.

Updated on: 6th February 2008




2917/002 Produced by Haz-Mat Ltd.

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