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MSDS Material Safety Data Sheet
CAS

99-87-6

File Name: gadiv_com---SOLGAD_150_03_07_06.asp
             SAFETY DATA SHEET


Trade Name: SOLGAD 150 Page 1 of 5


1: Identification
Commercial Product Name: SOLGAD 150
Manufacturer: Gadiv Petrochemical Industries LtD.
P.O.B 32 Haifa
Israel 31000
Management
Tel: +972-4-8788020
Fax: +972-4-8788018
Marketing
Tel: +972-4-8788955
Fax: +972-4-8788034



2: Composition/Information on Ingredients

Chemical characterization: Liquid, colorless, aromatic odor.
Hazardous ingredients:

Chemical name CAS-No EINECS-No Concentration % Classification
C3-C4 Alkyl benzenes - - 72.8% R10, R37, R51/53,
R65 Xn, N
C5-C8 Alkyl benzenes - - 4.1% N/A
p-Isopropyl toluene 99-87-6 - 3.4% R10, R36/37/38 Xn
(See full text of R-phrases in chapter 16.)



3: Hazards Identification

Human health hazard:
R36/37/38 : Irritating to eyes, respiratory system and skin.
R65: Harmful: may cause lung damage if swallowed.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.




4: First Aid Measures

Symptoms: Harmful if swallowed, danger of aspiration of material into the lungs. Irritating to
eyes, respiratory system and skin. High concentrations may cause headache,
dizziness, drowsiness, confusion and loss of consciousness.

Skin contact: Immediately remove contaminated clothing and shoes. Rinse with large amounts of
water for at least 10 minutes. Get medical attention as necessary. Do NOT use
solvents or thinners.



2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 150 Page 2 of 5

Eyes contact: Rinse open eyes under running water for at least 15 minutes. Get medical attention.


Ingestion: Do NOT induce vomiting. If victim is conscious, give three cups of water. Get medical
attention as necessary. Never give anything by mouth to an unconscious person.


Inhalation: Using protective gear, evacuate victim from site of exposure. Have victim lie or sit
comfortably. If he has difficulty breathing, have him sit with back straight and
administer oxygen, if possible. If victim is unconscious, perform resuscitation and then
immediately transfer to medical personnel.



5: Fire-Fighting Measures

Flammability: Combustible.
Suitable extinguishing media: foam, dry chemicals.
Water may be ineffective. Use water spray to cool fire-exposed containers, to dilute liquid, and control
vapor.
Use supplier-air breathing equipment for enclosed or confined spaces or as otherwise needed.
Wear full protective cloths and self-contained breathing apparatus.



6: Accidental Release Measures


Wear full protective clothing . Evacuate personnel.
Eliminate all sources of ignition. Stop the leakage if you can do so without risk. Absorb the chemical onto
sand, vermiculite, or any other non-combustible absorbent. Scoop into containers for later disposal.
Check local regulations before dumping waste or disposing of liquids in drainage system. Prevent the
product from spreading into the environment.



7: Handling and Storage
Keep away from incompatible materials (see section 10).

Keep away from flame, sparks, static electricity, friction or any other heat source that may cause
ignition. Keep in well-ventilated area.

Safety phrases
Avoid contact with skin and eyes.
Do not breathe vapour.
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Avoid release to the environment. Refer to special instructions/Safety data sheets.

Storage: Store in a cool, dry, well-ventilated area.
Store separately from strong oxidizing agents.




2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 150 Page 3 of 5


8: Exposure Control and Personal Protection

Threshold values:
Isopropyl benzene
ACGIH-TLV 50 ppm (TWA)
NIOSH-REL 50 ppm (TWA) skin
OSHA-PEL 50 ppm (TWA) skin

Personal Protective equipment: Generally, personal protection is a function of exposure. It is
recommended to use working shoes, working clothes or lab coat. Working should be done in a well-
ventilated area. In addition: mask and filter for organic compounds type A, gloves, safety goggles.
Respiratory protection: Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Wear appropriate respirator when ventilation is inadequate.
In case of an emergency: Full protective gear and a self-contained breathing apparatus should be used,
according to the severity.



9: Physical and Chemical Properties:
General information:
Form: liquid
Color: colorless
Odour: aromatic


Important health, safety and environmental information:
Boiling point 掳C: 180-210
Freezing point 掳C: -18
Molecular weight: 135 averages
Density g/cm3 (20掳C): 0.886
Vapor density (air=1): 6.07
Vapor pressure (mmHg)(20掳C) : 0.78
Solubility (in water): Insoluble in water
pH: N/A
Flash point 掳C: 66
Auto-ignition temperature 掳C: >420
LEL: 0.6% UEL: 7.0%
Viscosity (25掳C): 0.92 Pa/s



10: Stability and Reactivity

Hazardous polymerization: Will not occur.

Chemical reactivity: Stable under ordinary use. Keep away from strong oxidizers, heat and open flame.

Hazardous decomposition products: On fire emits toxic and irritating fumes.


2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 150 Page 4 of 5




11: Toxicological Information

Isopropyl benzenel
LD50 (oral rat) 1400 mg/kg
LC50 (Inhalation rat) 39000 mg/m3/4H

p-Isopropyltoluene
LD50 (oral rat) 4750 mg/kg
LC50 (Inhalation mouse) 19500 mg/m3

n-Propylbenzene
LD50 (oral rat) 6040 mg/kg
LC50 (Inhalation rat) 65000 ppm/2H




12: Ecological Information

Environmental hazards: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
Biodegrability: this product does not biodegrade rapidly but is 鈥渋nherently鈥? biodegradable according to
OECD guidelines.



13: Disposal Considerations


According to the Israeli regulations, a holder of this waste must evacuate it as soon as possible and not
later than 6 months after the production of the waste, to the Ramat-Hovav waste site. The waste should
be packed and transported according to the regulations. For packing group and transport classification of
the waste refer to section 14.



14: Transport Information

UN recommendations: UN 3082
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Class: 9
Packing group: III
LABEL: 鈥楳ISCELLANEOUS DANGEROUS SUBSTANCES and ARTICLES鈥?: 3Z

Sea transport:

IMDG: UN 3082
Class: 9
Proper technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.


2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 150 Page 5 of 5

Packing group: III

Air transport:
ICAO/IATA: UN 3082
Class: 9
Proper technical name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Packing group: III



Estimated NFPA: H: 2 F: 2 R: 0


15: Regulatory Information
Labeling in accordance with EC directives




Symbol and indicating of hazard: Xn, N

R-phrases:
R36/37/38 : Irritating to eyes, respiratory system and skin.
R65: Harmful: may cause lung damage if swallowed.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment..

S-phrases:
S24/25: Avoid contact with skin and eyes.
S23: Do not breathe vapour.
S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container
or label.
S61: Avoid release to the environment. Refer to special instructions/Safety data sheets.



16: Other Information


Full text of R-phrases with No. appearing in section 2:
R10: flammable
R36/37/38 : Irritating to eyes, respiratory system and skin.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65: Harmful: may cause lung damage if swallowed.



Date of issue: 3TH July 2006

The information herein is based on the present state of our knowledge. It is believed to be correct but is not necessarily all
inclusive and shall be used only as a guide. BAZAN Ltd, and Haz-Mat Ltd. shall not be held liable for any damage resulting from
handling or from contact with the above product. For further information, contact BAZAN Ltd or contact Haz-Mat at
hazmat@hazmat.co.il.




2917/002 Produced by Haz-Mat Ltd.
SAFETY DATA SHEET


Trade Name: SOLGAD 150 Page 6 of 5




2917/002 Produced by Haz-Mat Ltd.

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