Antiwear Hydraulic Oils
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SUPROTEK ADVANTAGE HYDRAULIC OIL AW
Includes ISO viscosity grades 15, 22, 32, 46, 68, 100, 150, and 220.
SYNONYMS: Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant.
PRODUCT CODE: Prefix 31
PRODUCT USE: For lubricating hydraulic systems. If these products are used in combination with other
products, refer to the Material Safety Data Sheets for those products.
This number is for emergency use only. If 24-HOUR EMERGENCY PHONE NUMBER
you desire non-Emergency product MEDICAL AND TRANSPORTATION (SPILL):
information, please call a phone number
listed below. CHEMTREC: (800) 424-9300
SUPPLIER: Dixie Gas & Oil Corporation
229 Lee Highway
Verona, VA 24482
www.dixiegas.com
800-403-4943
TECHNICAL
INFORMATION: 540-248-6273
Page 1 of 8
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
OSHA PEL ACGIH TLV庐
WT% NAME SYNONYM CAS NO. TWA STEL TWA STEL Lda LCb
25-99 Librication oils, petroleum Hydrotreated 6472-58-1 5c N.Av. 5c 10c >2000 N.Av
hydrotreated spent paraffinic .
a
base oil >4480
d
0- Lubricating oils (petroleum), Bright stock 72623-83-7 5c N. Av. 5c 10c >5000 N.
75**** C>25, hydrotreated bright Av.
a
stock
0- Residual oils (petroleum), Bright stock 64742-62-7 5c N. Av. 5c 10c >5000
75**** solvent dewaxed 2.18
a
>2000 mg/L
/4H
d
0- Residual oils (petroleum), Bright stock 64742-01-4 5c N. Av. 5c 10c >5000 2.18
75**** solvent refined mg/L
a
>2000 /4H
d
0-8* Additive containing mineral *** *** N. N. Av. N. N. Av. N. Av. N.
oil*** Av. Av. Av.
0- Mineral oil*** *** *** N. N. Av. N. N. Av. N. Av. N.
1.5** Av. Av. Av.
0-1* Zinc *** *** N. N. Av. N. N. Av. N. Av. N.
dialkyldithiophosphates*** Av. Av. Av.
*Even though the concentration range does not fall under the ranges prescribed by WHMIS, this is the actual range which varies
with each batch of the product.
**Supplier advises that the concentration is a trade secret; however, it will fall within this range.
***Supplier advises that this is a trade secret.
****Only one of the above listed Bright Stocks will be present in the product at anytime at the indicated WT%
N. Av. = Not Available aOral-Rat LD50 (mg/kg) cBased on Oil mist, mineral
bInhalation-Rat LC50 dSkin-Rabbit LD50 (mg/kg)
SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW APPEARANCE
EMERGENCY OVERVIEW
APPERANCE: Amber, red, green, or blue; liquid; petroleum odor.
CAUTION!
HEALTH May be harmful if swallowed. May irritate the respiratory tract (nose, throat, and lungs),
HAZARDS: eyes, skin.
POTENTIAL HEALTH EFFECTS
INHALATION
(BREATHING): These products are not likely to present an inhalation hazard at normal temperatures and
pressures. However, when aerosolizing, misting, or heating these products, high
concentrations of generated vapor or mist may irritate the respiratory tract (nose, throat, and
lungs).
INGESTION
Page 2 of 8
(SWALLOWING): May be harmful if swallowed. May cause throat irritation, nausea, vomiting, and diarrhea.
Breathing product into the lungs during ingestion or vomiting may cause lung injury and
possible death.
MEDICAL CONDITIONS
AGGRAVATED BY
EXPOSURE: Individuals with pre-existing respiratory tract (nose, throat, and lungs), eye, and/or skin
disorders may have increased susceptibility to the effects of exposure.
CHRONIC: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue
inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may cause
inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis).
Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or
swelling (dermatitis).
CANCER
INFORMATION: No known carcinogenicity. For more information, see SECTION 11: CARCINOGENICITY.
Also see SECTION 15: CALIFORNIA.
POTENTIAL ENVIRONMENTAL
EFFECTS: Not available. Also see SECTION 12: ECOLOGICAL INFORMATION.
SECTION 4: FIRST AID MEASURES
INHALATION
(BREATHING): Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Only qualified personnel should only administer oxygen. Someone should stay with
victim. Get medical attention if breathing difficulty persists.
EYES: If irritation or redness from exposure to vapor develops, move away from exposure into fresh
air. Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart,
for 15 minutes. Get medical attention.
SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical
attention if irritation or pain develops or persists. If product is injected under pressure into or
under the skin, or into any part of the body, regardless of the appearance of the wound or its
size, a physician should immediately evaluate the individual as a medical emergency.
INGESTION
(SWALLOWING): Do NOT induce vomiting. Immediately get medical attention. Call 800-424-9300 for additional
information. If spontaneous vomiting occurs, keep head below hips to avoid breathing the
product into the lungs. Never give anything by mouth to an unconscious person.
EYES: May cause irritation.
SKIN: May cause irritation. A single prolonged exposure is not likely to be absorbed through the skin
in harmful amounts.
NOTE TO
PHYSICIANS: Treat symptomatically and supportively. Treatment may vary with condition of victim and
specifics of incident. Call 1-800-537-7433 for additional information.
SECTION 5: FIRE FIGHTING MEASURES
FLASH POINT: 356潞F (180潞C) (minimum) (Cleveland Open Cup)
FLAMMABLE LIMITS IN AIR:
LOWER: Not available UPPER: Not available
AUTOIGNITION
TEMPERATURE: Not Available
Page 3 of 8
HAZARDOUS COMBUSTION
PRODUCTS: Decomposition and combustion materials may be toxic. Burning may produce hydrogen
sulfide, sulfur oxides, nitrogen oxides, phosphorus oxides, carbon monoxides, and unidentified
organic compound.
CONDITIONS OF
FLAMMABILITY: Sparks or flame. Product may burn, but does not ignite readily.
EXTINGUISHING
MEDIA: Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or foam may
cause frothing.
NFPA 704
HAZARD
IDENTIFICATION: This information is intended solely for the use by individuals trained in this system.
Health Hazard (Blue) 1 Fire Hazard (Red) 1
Specific Hazard (White) Reactivity (Yellow) 0
FIRE FIGHTING
INSTRUCTIONS: Keep storage containers cool with water spray. A positive pressure, self-contained breathing
apparatus (SCBA) and full body protective equipment are required for fire emergencies.
FIRE AND EXPLOSION
HAZARDS: Heated containers may rupture. "Empty" containers may retain residue and can be dangerous.
Product is not sensitive to mechanical impact or static discharge.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear
protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE CONTROLS/PERSONAL
PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid
breathing vapor or mist. Contain spill away from surface water and sewers. Contain spill as a liquid for possible recovery,
or absorb with compatible sorbent material and shovel with a clean, spark proof tool into a sealable container for disposal.
Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal.
SECTION 7: HANDLING AND STORAGE
HANDLING: Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe
for such locations should be used. Use clean tools and explosion-proof equipment. When
transferring large volumes of product, metal containers, including trucks and tank cars, should
be grounded and bonded. These products have a low vapor pressure and are not expected to
present an inhalation hazard under normal temperatures and pressures. However, when
aerosolizing, misting, or heating these products, do not breathe vapor or mist. Use in a well
ventilated area. Avoid contact with eyes, skin, clothing, and shoes.
SHIPPING AND
STORING: Keep container tightly closed when not in use and during transport. Store containers in a cool,
dry place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep
containers away from flame, sparks, static electricity, or other sources of ignition. Empty
product containers may retain product residue and can be dangerous.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING
CONTROLS: Provide general ventilation needed to maintain concentration of vapor or mist below applicable
exposure limits. Where adequate general ventilation is unavailable, use process enclosures,
local exhaust ventilation, or other engineering controls to control airborne levels below
applicable exposure limits.
Page 4 of 8
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY
PROTECTION: Use NIOSH-certified P- or R- series particulate filter and organic vapor cartridges when
concentration of vapor or mist exceeds applicable exposure limits. Protection provided by air
purifying respirators is limited. Do not use N-rated respirators. Selection and use of respiratory
protective equipment should be in accordance in the USA with OSHA General Industry
Standard 29 CFR 1910.134; or in Canada with CSA Standard Z94.4.
EYE
PROTECTION: Where eye contact is likely, wear safety glasses; contact lens use is not recommended.
SKIN
PROTECTION: Where skin contact is likely, wear neoprene, nitrile, or equivalent protective gloves; use of
natural rubber or equivalent gloves is not recommended. When product is heated and skin
contact is likely, wear heat-resistant gloves, boots, and other protective clothing. To avoid
prolonged or repeated contact where spills and splashes are likely, wear appropriate
chemical-resistant face shield, boots, apron, coveralls, long sleeve shirts, or other protective
clothing.
PERSONAL
HYGIENE: Use good personal hygiene. Wash thoroughly with soap and water after handling product and
before eating, drinking, or using tobacco products. Clean affected clothing, shoes, and
protective equipment before reuse. Discard leather articles, such as shoes, saturated with
these products
OTHER
PROTECTIVE
EQUIPMENT: Where spills and splashes are likely, facilities storing or using these products should be
equipped with an emergency eyewash and shower, both equipped with clean water, in the
immediate work area.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE,
APPEARANCE, AND ODOR: Amber, red, green, or blue; liquid; petroleum odor.
ODOR THRESHOLD: Not available
MOLECULAR WEIGHT: Not applicable
SPECIFIC GRAVITY: 0.88 (water = 1) (approximately)
DENSITY: 7.3 LB/US gal (880 g/L) (approximately)
VAPOR DENSITY: Not available
VAPOR PRESSURE: less than 0.1 mm Hg at 68潞F (20潞C)
BOILING POINT: 475潞F (246潞C) (minimum)
FREEZING/MELTING POINT: Not available [pour point 21潞F (-6潞C) (maximum)
pH: Not applicable
EVAPORATION RATE: Not available
SOLUBILITY IN WATER: Insoluble
FLASH POINT: 356潞F (180潞C) (minimum) (Cleveland Open Cup)
Page 5 of 8
FLAMMABLE LIMITS IN AIR: LOWER: Not available UPPER: Not available
AUTOIGNITION TEMPERATURE: Not available
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable under normal temperatures and pressures. Avoid sparks or flame when not in use.
INCOMPATIBILITY: Avoid oxidizing agents, reducing agents, and/or acids.
REACTIVITY: Polymerization is not known to occur under normal temperature and pressures. Not reactive
with water.
HAZARDOUS
DECOMPOSITION
PRODUCTS: None under normal temperatures and pressures. See also SECTION 5: HAZARDOUS
COMBUSTION PRODUCTS.
SECTION 11: TOXICOLOGICAL INFORMATION
SENSITIZATION: Based on best current information, there is no known human sensitization associated with
these products.
MUTAGENICITY: Experimental evidence suggests that these products do not cause mutagenesis.
CARCINOGENICITY: Based on best current information, there is no known carcinogenicity as regulated by OSHA;
as categorized by ACGIH A1 or A2 substances; as categorized by IARC Group 1, Group 2A,
or Group 2B agents; or as listed by NTP as either known carcinogens or substances for which
there is limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity
in experimental animals. Also see SECTION 15: CALIFORNIA.
REPRODUCTIVE
TOXICITY: Based on best current information, there is no known reproductive toxicity associated with
these products. Also see SECTION 15: CALIFORNIA.
TERATOGENICITY: Based on best current information, there is no known teratogenicity associated with these
Products.
TOXICOLOGICALLY
SYNERGISTIC
PRODUCT(S): Based on best current information, there are no known toxicologically synergistic products
associated with these products.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICITY: No information available for these products.
OCTANOL/WATER
PARTITION
COEFFICIENT: Not available
VOLATILE ORGANIC
COMPOUNDS: 100 WT%; 7.3 LB/US gal; 880 g/l (approximately) As per 40 CFR Part 51.1000(s).
SECTION 13: DISPOSAL CONSIDERATIONS
DISPOSAL: Dispose in accordance with federal, state, provincial, and local regulations. Regulations may
also apply to empty containers. The responsibility for proper waste disposal lies with the owner
of the waste. Contact Dixie Gas And Oil Corporation regarding proper recycling or disposal.
USEPA WASTE
CODE(S): These products, if discarded, are not expected to be a characteristic or listed hazardous
waste. If recycled in the USA, they must be managed in accordance with 40 CFR Part 279.
Page 6 of 8
Processing, use, or contamination by the user may change the waste code(s) applicable to the
disposal of these products.
SECTION 14: TRANSPORT INFORMATION
DOT: Shipping Name: Not regulated.
TDG: Shipping Name: Not regulated.
EMERGENCY
RESPONSE
GUIDE NUMBER: Not applicable. Reference North American Emergency Response Guidebook
SECTION 15: REGULATORY INFORMATION
USA REGULATIONS
SARA SECTIONS
302 AND 304: Based on the ingredient(s) listed in SECTION 2, these products do not contain any "extremely
hazardous substances" listed pursuant to Title III of the Superfund Amendments and
Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified in 40 CFR Part
355, Appendix A and B.
SARA SECTIONS
311 AND 312: These products pose the following health hazard(s) as defined in 40 CFR Part 370 and is
subject to the requirements of sections 311 and 312 of Title III of the Superfund Amendments
and Reauthorization Act of 1986 (SARA): Immediate (Acute) Health Hazard Delayed (Chronic)
Health Hazard
SARA SECTION
313: These products do not contain "toxic" chemical(s) subject to the requirements of section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40
CFR Part 372.
CERCLA: Based on the ingredient(s) listed in SECTION 2, these products do not contain any hazardous
substances" listed pursuant to the Comprehensive Environmental Response, Compensation
and Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4.
TSCA: All the components of these products are listed on, or are automatically included as "naturally
occurring chemical substances" on, or are exempted from the requirement to be listed on, the
TSCA Inventory.
CALIFORNIA: These products may contain detectable amounts of aniline CAS 62-53-3, arsenic CAS 7440-
38-2, benzene CAS 71-43-2, cadmium CAS 7440-43-9, chromium CAS 7440-47-3, 1,4-
dioxane CAS 123-91-1, ethyl acrylate CAS 140-88-5, ethylene oxide CAS 75-21-8, lead CAS
7439-92-1, beta-naphthylamine CAS 91-59-8, propylene oxide CAS 75-56-9, and ortho-
toluidine CAS 95-53-4 from additives. Theseproducts may contain detectable amounts of
benzo(a)anthracene CAS 56-55-3, benzo(k)fluoranthene CAS 207-08-9, benzo(a)pyrene CAS
50-32-8, benzo(b)fluoranthene CAS 205-99-2, chrysene CAS 218-01-9, ibenz(a,h)anthracene
CAS 53-70-3, and indeno(1,2,3-cd)pyrene CAS 193-39-5. WARNING: These chemicals are
known to the State of California to cause cancer. Our testing of these products indicates that
these chemicals are not always detectable.These products may contain detectable amounts of
arsenicCAS 7440-38-2, benzene CAS 71-43-2, cadmium CAS 7440-43-9, ethylene oxide
CAS 75-21-8, lead CAS 7439-92-1, and toluene CAS 108-88-3 from additives. WARNING:
These chemicals are known to the State of California to cause birth defects or other
reproductive harm.
CANADIAN REGULATIONS
These products have been classified in accordance with the hazard criteria of the Controlled
Products Regulations (CPR) and the MSDS contains all information required by the CPR.
Page 7 of 8
WHMIS: Not regulated.
CANADIAN
ENVIRONMENTAL
PROTECTION
ACT (CEPA): All the components of these products are listed on, or are automatically included as
"substance occurring in nature" on, or are exempted from the requirements to be listed on, the
Canadian Domestic Substances List (DSL).
SECTION 16. OTHER INFORMATION
REVISION INFORMATION: Regulatory Update.
LABEL/OTHER INFORMATION: Not available.
User assumes all risks incident to the use of this (these) product(s). To the best of our knowledge, the information
contained herein is accurate. However, Dixie Gas And Oil Corporation assumes no liability whatsoever for the accuracy or
completeness of the information contained herein. No representations or warranties, either express or implied, or
merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or
the product to which information refers. The data contained on this sheet apply to the product(s) as supplied to the user.
漏2005 Printed in the USA.
Page 8 of 8
|