Material Safety Data Sheet
NFPA HMIS PPE Transport Symbol
Issuing Date 27-Feb-2007 Revision Date Revision Number 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name Touch 'n Seal Gun Foam II Polyurethane Foam Sealant
Touch 鈥榥 Foam Professional All-Purpose Foam Sealant
Recommended Use Insulation
Supplier Address Convenience Products, division of Clayton Corp.
866 Horan Drive
Fenton, MO 63026-2416 USA
TEL: (636) 349-5855
Emergency Telephone Number Chemtrec 1-800-424-9300
(703) 527-3887 outside US
2. HAZARDS IDENTIFICATION
WARNING!
Emergency Overview
Contents under pressure.
Flammable gas.
Harmful by inhalation, in contact with skin and if swallowed.
May cause allergic respiratory reaction.
May cause sensitization by skin contact
Irritating to eyes, respiratory system and skin.
Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not
work with isocyanates.
May cause drowsiness and dizziness.
May cause adverse cardiovascular effects.
Appearance Pale Amber Physical State Liquid Aerosol Odor Faint hydrocarbon
Potential Health Effects
Principle Routes of Exposure Inhalation, Skin contact, Eye contact.
Acute Toxicity
Eyes Irritating to eyes. Risk of serious damage to eyes.
Skin Harmful in contact with skin. Will bond to skin. May cause sensitization by skin contact.
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons.
Inhalation Harmful by inhalation. Irritating to respiratory system. May cause allergic respiratory reaction.
Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal.
Inhalation of vapors in high concentration may cause shortness of breath (lung edema). May
cause allergy or asthma symptoms or breathing difficulties if inhaled.
Ingestion May be harmful if swallowed. May cause additional affects as listed under "Inhalation".
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Product may
cure in the gastrointestinal tract and form an obstruction. May cause adverse cardiac effects,
blood disturbances, and metabolic acidosis.
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Chronic Effects Repeated or prolonged exposure may cause central nervous system damage. Intentional
misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic
hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac
arrest. Repeated or prolonged contact causes sensitization, asthma and eczemas.
Aggravated Medical Conditions Allergies. Skin disorders. Respiratory disorders. Central nervous system. Preexisting eye
disorders. Kidney disorders. Liver disorders.
Interactions with Other Chemicals Irritants. Sensitizers. Epoxies. Use of alcoholic beverages may enhance toxic effects.
Environmental Hazard See Section 12 for additional Ecological information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight %
Flame Retardant Proprietary 5-10
Polymethylene polyphenylene isocyanate 9016-87-9 10-30
Methylene bisphenyl isocyanate (MDI) 101-68-8 10-30
Polyol blend Proprietary 10-30
Isobutane 75-28-5 5-10
Methylenediphenyl diisocyanate 26447-40-5 1-5
Propane 74-98-6 1-5
Dimethyl ether 115-10-6 5-10
4. FIRST AID MEASURES
General Advice Call 911 or emergency medical service. Remove and isolate contaminated clothing and shoes.
Eye Contact Call a physician immediately. Immediately flush with plenty of water. After initial flushing, remove any
contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing.
Skin Contact Wash skin with soap and water. If symptoms persist, call a physician. Remove and wash contaminated
clothing before re-use.
Inhalation Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing
is difficult.
Ingestion Call a physician or Poison Control Center immediately. May produce an allergic reaction. Do not induce
vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person.
Notes to Physician Keep victim warm and quiet.
Protection of First-aiders Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves.
5. FIRE-FIGHTING MEASURES
Flammable Properties Containers may explode when heated.
Flash Point -104掳C / -155掳F
Suitable Extinguishing Media Use extinguishing agent suitable for type of surrounding fire. Dry
chemical or CO2. Water spray, fog or regular foam. Move
containers from fire area if you can do it without risk. Damaged
cylinders should be handled only by specialists.
Explosion Data
Sensitivity to mechanical impact None
Sensitivity to static discharge Yes.
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Specific Hazards Arising from the Chemical
Some may burn but none ignite readily. Ruptured cylinders may rocket.
Protective Equipment and Precautions for Firefighters
Wear self-contained breathing apparatus and protective suit.
NFPA Health Hazard 2 Flammability 4 Stability 1 Physical and Chemical
Hazards -
HMIS Health Hazard 2* Flammability 4 Stability 1 Personal Precautions -
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Remove all sources of ignition. Evacuate personnel to safe areas. Ensure adequate
ventilation. Take precautionary measures against static discharges. Use personal protective
equipment. Keep people away from and upwind of spill/leak.
Methods for Containment If possible, turn leaking containers so that gas escapes rather than liquid. Allow substance to
evaporate. Dike to collect large liquid spills.
Methods for Cleaning Up Soak up with inert absorbent material. Sweep up and shovel into suitable containers for
disposal. Do not direct water at spill or source of leak.
Other Information Ventilate the area.
7. HANDLING AND STORAGE
Handling Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Take necessary action
to avoid static electricity discharge (which might cause ignition of organic vapors). Keep away
from open flames, hot surfaces and sources of ignition. Use only in an area containing flame
proof equipment. To avoid ignition of vapors by static electricity discharge, all metal parts of
the equipment must be grounded. Avoid breathing vapors or mists. Contents under pressure.
Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on
top of can.
Storage Keep containers tightly closed in a cool, well-ventilated place. Keep out of the reach of
children. Keep at temperatures below 48.8 掳C / 120 掳F.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
3
Methylene bisphenyl isocyanate TWA: 0.005 ppm Ceiling: 0.02 ppm 75 mg/m
3
(MDI) Ceiling: 0.2 mg/m
Isobutane TWA: 1000 ppm N/A N/A
Propane TWA: 1000 ppm TWA: 1000 ppm 2100 ppm
NIOSH IDLH: Immediately Dangerous to Life or Health
Engineering Measures Showers
Eyewash stations
Ventilation systems
Personal Protective Equipment
Eye/Face Protection Safety glasses with side-shields.
Skin and Body protection Impervious gloves. Lightweight protective clothing.
Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory
protection should be worn. Respiratory protection must be provided in accordance with
current local regulations.
Hygiene Measures When using, do not eat, drink or smoke.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor
Pale Amber Faint hydrocarbon
Odor Threshold Physical State
No information available Liquid Aerosol
pH No information available
Flash Point Autoignition Temperature
-104掳C / -155掳F Not applicable
Decomposition temperature Boiling Point/Range
No data available -42掳C / -44掳F
Melting Point/Range No data available
Flammability Limits in Air Explosion Limits
No data available No data available
Specific Gravity Water Solubility
1.05 Not Compatible
Solubility Evaporation Rate
Compatible. No data available
Vapor Pressure Vapor Density
No data available No data available
VOC Content EPA VOC (g/l)
Not applicable 155
Partition Coefficient (n- No data available
octanol/water)
10. STABILITY AND REACTIVITY
Stability Stable under recommended storage conditions
Conditions to Avoid Keep away from open flames, hot surfaces and sources of ignition.
Temperatures above 48.8 掳C / 120 掳F.
Incompatible Products Water. Alcohols. Strong bases. Strong oxidizing agents. Finely
powdered metals.
Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Nitrogen oxides
(NOx), Hydrogen cyanide.
Hazardous Polymerization Hazardous polymerization does not occur.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information Product does not present an acute toxicity hazard based on known or supplied information.
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Flame Retardant 1850 mg/kg ( Rat ) 2000 mg/kg ( Rat ) 5.22 mg/L ( Rat ) 4 h
23700 mg/kg ( Rabbit )
3
Polymethylene polyphenylene 49 g/kg ( Rat ) 9400 mg/kg ( Rabbit ) 490 mg/m ( Rat ) 4 h
isocyanate
Methylene bisphenyl isocyanate 9200 mg/kg ( Rat )
(MDI)
Polyol blend 64 mL/kg ( Rat ) 20 mL/kg ( Rabbit )
Isobutane 658 mg/L ( Rat ) 4 h
Methylenediphenyl diisocyanate 6200 mg/kg ( Rabbit ) 0.369 mg/L ( Rat ) 4 h
Propane 658 mg/kg ( Rat )
Dimethyl ether 308.5 mg/L ( Rat ) 4 h
Subchronic Toxicity (28 days)
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Chronic Toxicity Repeated or prolonged exposure may cause central nervous system damage. Intentional
misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic
hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac
arrest. Repeated or prolonged contact causes sensitization, asthma and eczemas.
Carcinogenicity There are no known carcinogenic chemicals in this product.
Mutagenicity
Reproductive Toxicity This product does not contain any known or suspected reproductive hazards
Target Organ Effects Central nervous system (CNS), Eyes, Respiratory system, Immune system, Skin,
Cardiovascular system.
Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors
12. ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity effects.
Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea)
Flame Retardant EC50 > 10 mg/L 72 h EC50 3.9 - 5.5 mg/L 48 h
Methylenediphenyl EC50 = 3230 mg/L 96 h EC50 > 1000 mg/L 24 h
diisocyanate
Chemical Name Log Pow
Isobutane 2.88
Propane 2.3
Dimethyl ether -0.18
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261). Should not be released into the environment. Dispose of in accordance with local
regulations. Allow foam to cure before disposal.
Contaminated Packaging Dispose of in accordance with local regulations.
US EPA Waste Number D001
14. TRANSPORT INFORMATION
DOT
Proper Shipping Name Consumer commodity
Hazard Class ORM-D
Description Consumer commodity,ORM-D,
TDG
Proper Shipping Name Aerosols
Hazard Class 2.1
UN-No UN1950
Description AEROSOLS,2.1,UN1950
MEX
Proper Shipping Name Aerosols
Hazard Class 2.1
UN-No UN1950
Description UN1950 Aerosols,2.1
ICAO
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14. TRANSPORT INFORMATION
UN-No UN1950
Proper Shipping Name Aerosols
Hazard Class 2.1
Description Aerosols,UN1950
IATA
UN-No UN1950
Proper Shipping Name Aerosols, flammable
Hazard Class 2.1
ERG Code 10L
Description UN1950,Aerosols, flammable,2.1
IMDG/IMO
Proper Shipping Name Aerosols
Hazard Class 2
UN-No UN1950
EmS No. F-D, S-U
Description UN1950, Aerosols,2
RID
Proper Shipping Name Aerosols
Hazard Class 2
UN-No UN1950
Classification Code 5A
Description UN1950 Aerosols,2,,RID
ADR/RID-Labels 2
ADR
Proper Shipping Name Aerosols
Hazard Class 2
UN-No UN1950
Classification Code 5A
ADR/RID-Labels 2
ADN
Proper Shipping Name Aerosols
Hazard Class 2
Classification Code 5A
Special Provisions 63, 190, 191, 277, 913
Description UN1950 Aerosols,2,
Hazard Labels 2
Limited Quantity See SP277
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL Complies
EINECS/ELINCS Complies
ENCS Complies
CHINA Complies
KECL Complies
PICCS Complies
AICS Complies
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
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Chemical Name CAS-No Weight % SARA 313 - Threshold
Values
Polymethylene polyphenylene isocyanate 9016-87-9 10-30 1.0
Methylene bisphenyl isocyanate (MDI) 101-68-8 10-30 1.0
Methylenediphenyl diisocyanate 26447-40-5 1-5 1.0
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard Yes
Reactive Hazard No
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR
122.42).
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs
Methylene bisphenyl isocyanate (MDI) 5000 lb
U.S. State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island
Dimethyl ether X X X X
Propane X X X X
Isobutane X X X
Methylene bisphenyl X X X X X
isocyanate (MDI)
International Regulations
Mexico - Grade
The exposure limits values for 101-68-8 are listed under two synonyms:
3
Diphenylmethane diisocyanate - 0.02 ppm TWA; 0.2 mg/m TWA
Methylene bisphenyl isocyanate - 0.005 ppm TWA; 0.051 mg/m3 TWA
Chemical Name Carcinogen Status Exposure Limits
3
Methylene bisphenyl isocyanate (MDI) Mexico: TWA= 0.2 mg/m
Mexico: TWA= 0.02 ppm
Mexico: TWA= 0.005 ppm
3
Mexico: TWA= 0.051 mg/m
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.
WHMIS Hazard Class
A Compressed gases
B5 Flammable aerosol
D2A Very toxic materials
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Chemical Name NPRI
Methylene bisphenyl isocyanate (MDI) X
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Issuing Date 27-Feb-2007
Revision Date
Revision Note No information available
Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any other material or in any
process, unless specified in the text.
End of MSDS
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