Material Safety Data Sheet
Version: 1.3
09/04/2007
GE112A 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Compound
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Waterford Plant
260 Hudson River Rd
Waterford NY 12188
09/04/2007
Revised:
PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
Preparer:
1-800-424-9300
CHEMTREC
Sealant
Chemical Family/Use:
Mixture
Formula:
HMIS
Flammability: 1 Reactivity: 0 Health: 1
NFPA
Flammability: 1 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! May be harmful if swallowed, inhaled or absorbed through skin. Irritating to eyes, respiratory
system and skin. May cause central nervous system depression.
Form: Solid Color: White Odor: Acetic acid
POTENTIAL HEALTH EFFECTS
INGESTION
May be harmful if swallowed. May cause central nervous system effects. May cause gastrointestinal
irritation, nausea, vomiting, and diarrhea.
SKIN
Uncured product contact will irritate lips, gums and tongue. Skin irritation is possible after contact with
the uncured product. May be absorbed through skin and produce effects as listed under "Ingestion".
INHALATION
Causes mild respiratory tract irritation. Applies in uncured state. May be harmful if inhaled.
EYES
Eye irritation on contact with the uncured product.
MEDICAL CONDITIONS AGGRAVATED
Pre-existing skin or respiratory diseases.
SUBCHRONIC (TARGET ORGAN )
Skin; Central nervous system
Page 1/7
Material Safety Data Sheet
Version: 1.3
09/04/2007
GE112A 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Compound
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
suspected carcinogen by NTP, IARC, or OSHA.
ROUTES OF EXPOSURE
Dermal; Eyes; Inhalation
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS
DISTILLATES, 64742-47-8 5 - 10 %
PETROLEUM,HYDROTREATED
METHYLTRIACETOXYSILANE 4253-34-3 1-5%
B. NON-HAZARDOUS
Titanium Dioxide 13463-67-7 1-5%
Treated Filler 68611-44-9 5 - 10 %
dimethylpolysiloxane 70131-67-8 60 - 90 %
4. FIRST AID MEASURES
INGESTION
Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical
attention. Never give anything by mouth to an unconscious person.
SKIN
To clean from skin, remove completely with a dry cloth or paper towel, before washing with
detergent and water. Get medical attention if irritation persists.
INHALATION
If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If
breathing is difficult give oxygen. Get medical attention.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
NOTE TO PHYSICIAN
None known.
Page 2/7
Material Safety Data Sheet
Version: 1.3
09/04/2007
GE112A 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Compound
5. FIRE-FIGHTING MEASURES
> 93.3 掳C; 200 掳F
FLASH POINT:
estimated
METHOD:
Unknown
IGNITION TEMPERATURE:
Unknown
FLAMMABLE LIMITS IN AIR - LOWER (%):
Unknown
FLAMMABLE LIMITS IN AIR - UPPER (%):
No
SENSITIVITY TO MECHANICAL IMPACT:
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected.
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressureself-contained breathing
apparatus with full face mask and fullprotective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section. Increase area ventilation.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Use only in well-ventilated areas. Avoid contact with skin and eyes. Eye irritation on contact with the
uncured product. Skin irritation is possible after contact with the uncured product. CAUTION! Remove
contact lenses before using sealant. Do not handle lenses until all sealant has been cleaned from the
fingertips, nails and cuticles. Residual sealant may remain on fingers for several days and transfer to
lenses and cause severe eye irritation. Product releases acetic acid during application and curing. Use
mechanical ventilation to stay below TLV of 10 ppm acetic acid.
Page 3/7
Material Safety Data Sheet
Version: 1.3
09/04/2007
GE112A 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Compound
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Eyewash stations
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Cloth gloves.
EYE AND FACE PROTECTION
Safety glasses
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9. PHYSICAL AND CHEMICAL PROPERTIES
Not applicable
BOILING POINT - C & F:
Not applicable
VAPOR PRESSURE (20 C) (MM HG):
Not applicable
FREEZING POINT:
Not applicable
MELTING POINT:
Solid
PHYSICAL STATE:
Acetic acid
ODOR:
White
COLOR:
<1
EVAPORATION RATE (BUTYL ACETATE=1):
ca. 1.04
SPECIFIC GRAVITY (WATER=1):
ca. 1.04 g/cm3
DENSITY:
Not applicable
ACID / ALKALINITY (MEQ/G):
Not applicable
pH:
2.8 %(m)
VOLATILE ORGANIC CONTENT (VOL):
Insoluble
SOLUBILITY IN WATER (20 C):
Toluene
SOLUBILITY IN ORGANIC SOLVENT (STATE
SOLVENT):
Page 4/7
Material Safety Data Sheet
Version: 1.3
09/04/2007
GE112A 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Compound
36
VOC EXCL. H2O & EXEMPTS (G/L):
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur.
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Formaldehyde; Carbon monoxide; Acetic acid; Silicon dioxide.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
None known.
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: Not applicable.
ACUTE DERMAL
Remarks: Not applicable.
ACUTE INHALATION
Remarks: Not applicable.
OTHER
None.
SENSITIZATION
No data available
SKIN IRRITATION
No data available
EYE IRRITATION
No data available
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300
Page 5/7
Material Safety Data Sheet
Version: 1.3
09/04/2007
GE112A 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Compound
degrees Fahrenheit (150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a
skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. A
MSDS for formaldehyde is available from Momentive., Acetic acid released during curing.
12. ECOLOGICAL INFORMATION
ECOTOXICITY
No data available
DISTRIBUTION
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
This product is not regarded as dangerous goods according to the
Further Information:
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
Japan Inventory of Existing & y (Positive listing)
New Chemical Substances
(ENCS)
Korea Existing Chemicals y (Positive listing)
Inventory (KECI)
China Inventory of Existing y (Positive listing)
Chemical Substances
Australia Inventory of Chemical y (Positive listing)
Substances (AICS)
Philippines Inventory of y (Positive listing)
Chemicals and Chemical
Page 6/7
Material Safety Data Sheet
Version: 1.3
09/04/2007
GE112A 12C-Crtrg (0.730 Lbs-0.331 Kg)
Silicone Rubber Compound
Substances (PICCS)
EU list of existing chemical y (Positive listing)
substances
Canada DSL Inventory y (Positive listing)
Canada NDSL Inventory n (Negative listing)
TSCA list y (Positive listing) On TSCA Inventory
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information
SARA (311,312) HAZARD CLASS
Acute Health Hazard; Chronic Health Hazard
SARA (313) CHEMICALS
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2B TOXIC MATERIALS, D2A VERY TOXIC MATERIALS
Other
3214.10 Mastic Based on Rubber
SCHDLE B/HTSUS:
EAR99
ECCN:
CALIFORNIA PROPOSITION 65
This product does not contain any chemicals known to State of California to cause cancer, birth, or
any other reproductive defects.
16. OTHER INFORMATION
OTHER
C = ceiling limit NEGL = negligible EST = estimated NF = none found NA = not
applicable UNKN = unknown NE = none established REC = recommended ND = none
determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2)., These data are offered in good faith as typical values
and not as product specifications. No warranty, either expressed or implied, is made. The
recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the
intended use and determine whether they are appropriate.
Page 7/7
|