Material Safety Data Sheet
Version: 1.4
10/17/2007
GE24737 12C-Crtrg(0.695LBS-0.315KG)
CAULKING
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Daytona Plant
703 South Street
New Smyrna Beach FL 32168
10/17/2007
Revised:
PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
Preparer:
1-800-424-9300
CHEMTREC
Sealant
Chemical Family/Use:
Mixture
Formula:
HMIS
Flammability: 0 Reactivity: 0 Health: 1
NFPA
Flammability: 0 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! Irritating to eyes, respiratory system and skin. Harmful by inhalation, in contact with skin and if
swallowed. May cause allergic skin reaction. May cause central nervous system depression.
Form: Liquid Color: Clear Odor: acrylic
POTENTIAL HEALTH EFFECTS
INGESTION
May be harmful if swallowed. Irritation of the mouth, throat, and stomach. May cause kidney damage.
May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and central nervous
system depression.
SKIN
May be absorbed through skin and produce effects as listed under "Ingestion". Can cause irritation
and reddening of the skin.
INHALATION
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Can irritate
mucous membranes and respiratory tract with coughing and shortness of breath. Avoid inhalation of
vapour or mist.
EYES
Contact can cause severe irritation and conjunctivitis (redness and swelling).
MEDICAL CONDITIONS AGGRAVATED
Central nervous system disorders. Pre-existing skin or respiratory diseases. Kidney disorders
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Material Safety Data Sheet
Version: 1.4
10/17/2007
GE24737 12C-Crtrg(0.695LBS-0.315KG)
CAULKING
SUBCHRONIC (TARGET ORGAN )
Respiratory system; Kidney; Central nervous system; This product contains a component which
is considered a teratogen or embryotoxin under the Canadian WHMIS act.
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
suspected carcinogen by NTP, IARC, or OSHA.
ROUTES OF EXPOSURE
Inhalation; Dermal; Eyes
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS
ETHANEDIOLE 107-21-1 <1%
2-(2-Methoxyethoxy)ethanol, 111-77-3 1-5%
B. NON-HAZARDOUS
Vendor Trade secret-Acrylic - 30 - 60 %
Polymer
Water 7732-18-5 30 - 60 %
White Mineral Oil 8042-47-5 1-5%
Silica 112945-52-5 1-5%
4. FIRST AID MEASURES
INGESTION
Do NOT induce vomiting. If victim is conscious, give 2-4 glasses of water. If symptoms persist,
call a physician.
SKIN
Wash off with soap and water. Remove and wash contaminated clothing before re-use. Get
medical attention if irritation or symptoms from Section 3 develop. Flush skin with large amounts
of water for at least 15 minutes until no evidence of chemical remains.
INHALATION
Get medical attention if irritation or symptoms from Section 3 develop. If not breathing, begin
artificial respiration using a barrier device. Because of chemical properties, do not use mouth-to-
mouth contact. Remove to fresh air.
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Material Safety Data Sheet
Version: 1.4
10/17/2007
GE24737 12C-Crtrg(0.695LBS-0.315KG)
CAULKING
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention if irritation persists.
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
Aqueous system
FLASH POINT:
Not applicable
IGNITION TEMPERATURE:
Not applicable
FLAMMABLE LIMITS IN AIR - LOWER (%):
Not applicable
FLAMMABLE LIMITS IN AIR - UPPER (%):
No
SENSITIVITY TO MECHANICAL IMPACT:
SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected., Follow normal Industrial Hygiene practices when
handling
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking
surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as
specified in the protective equipment section. Keep out of water supplies and sewers.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Avoid contact with skin and eyes. Remove and wash contaminated clothing before re-use. Keep away
from children. Keep container tightly closed. Keep container dry. Do not inhale vapors. Avoid
accidental ingestion of this material. Wash hands and face before eating, drinking, smoking, using
toilet facilities, or applying cosmetics. Store between 40 F and 120 F. Product releases formaldehyde
during curing.
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Material Safety Data Sheet
Version: 1.4
10/17/2007
GE24737 12C-Crtrg(0.695LBS-0.315KG)
CAULKING
STORAGE
Keep tightly closed in a dry, cool and well-ventilated place.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Eyewash stations; Showers; Exhaust ventilation
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Impermeable or chemical resistant gloves.
EYE AND FACE PROTECTION
Safety glasses with side-shields
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found
PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9. PHYSICAL AND CHEMICAL PROPERTIES
100.00 掳C; 212 掳F
BOILING POINT - C & F:
Unknown
VAPOR PRESSURE (20 C) (MM HG):
No data available
VAPOR DENSITY (AIR=1):
Unknown
FREEZING POINT:
Unknown
MELTING POINT:
Liquid
PHYSICAL STATE:
acrylic
ODOR:
Clear
COLOR:
No data available
EVAPORATION RATE (BUTYL ACETATE=1):
1.05
SPECIFIC GRAVITY (WATER=1):
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Material Safety Data Sheet
Version: 1.4
10/17/2007
GE24737 12C-Crtrg(0.695LBS-0.315KG)
CAULKING
ca. 1.058 g/cm3
DENSITY:
Unknown
ACID / ALKALINITY (MEQ/G):
7.7 - 8.1
pH:
1.3 %(m)
VOLATILE ORGANIC CONTENT (VOL):
Unknown
SOLUBILITY IN WATER (20 C):
Unknown
SOLUBILITY IN ORGANIC SOLVENT (STATE
SOLVENT):
45
VOC EXCL. H2O & EXEMPTS (G/L):
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur.
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon dioxide (CO2); Formaldehyde; Carbon monoxide; Oxides of nitrogen.; Acrylic monomers
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
None known.
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: NONE FOUND
ACUTE DERMAL
Remarks: NONE FOUND
ACUTE INHALATION
Remarks: NONE FOUND
OTHER
Contains ethylene glycol which causes birth defects in laboratory animals., Repeated inhalation of
ethylene glycol mist may produce signs of central nervous system involvement, particularly dizziness
and nystagmus., Ethylene glycol has been shown to produce dose-related teratogenic effects in rats
and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect
doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis
has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a
preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at
concentrations of 150, 1000 and 2500 mg/m3 for 6 hours a day throughout the period of
organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The
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Material Safety Data Sheet
Version: 1.4
10/17/2007
GE24737 12C-Crtrg(0.695LBS-0.315KG)
CAULKING
conditions of these latter experiments did not allow a conclusion as to whether the developmental
toxicity was mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from
contaminated skin, or swallowing of ethylene glycol as a result of grooming the wetted coat. In a
further study, comparing effects from high aerosol concentration by whole-body or nose-only
exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 2500 mg/m3)
and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects
concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic
effects could be produced when ethylene glycol was applied to skin of pregnant mice over the period
of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal
teratogen. There is currently no available information to suggest that ethylene glycol has caused birth
defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental
toxicity. Exposure to high aerosol concentrations is only minimally effective in producing
developmental toxicity. The major route for producing developmental toxicity is perorally. Two chronic
feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes
dose-related increases in tumor incidence, or a different pattern of tumors compared with untreated
controls. The absence of a carcinogenic potential for ethylene glycol has been supported by numerous
in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects.
SENSITIZATION
No data available
SKIN IRRITATION
No data available
EYE IRRITATION
No data available
MUTAGENICITY
Unknown
12. ECOLOGICAL INFORMATION
ECOTOXICITY
No data available
DISTRIBUTION
No data available
CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
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Material Safety Data Sheet
Version: 1.4
10/17/2007
GE24737 12C-Crtrg(0.695LBS-0.315KG)
CAULKING
14. TRANSPORT INFORMATION
This product is not regarded as dangerous goods according to the
Further Information:
national and international regulations on the transport of dangerous
goods.
15. REGULATORY INFORMATION
Inventories
TSCA list y (Positive listing)
Canada DSL Inventory y (Positive listing)
Canada NDSL Inventory n (Negative listing)
Japan Inventory of Existing & n (Negative listing)
New Chemical Substances
(ENCS)
Australia Inventory of Chemical n (Negative listing)
Substances (AICS)
Philippines Inventory of n (Negative listing)
Chemicals and Chemical
Substances (PICCS)
Korea Existing Chemicals n (Negative listing)
Inventory (KECI)
China Inventory of Existing n (Negative listing)
Chemical Substances
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information
SARA (311,312) HAZARD CLASS
Acute Health Hazard
SARA (313) CHEMICALS
50-00-0, Formaldehyde
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2A VERY TOXIC MATERIALS, D2B TOXIC MATERIALS
Other
3214.10.00.10 Mastic based on rubber
SCHDLE B/HTSUS:
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Material Safety Data Sheet
Version: 1.4
10/17/2007
GE24737 12C-Crtrg(0.695LBS-0.315KG)
CAULKING
CALIFORNIA PROPOSITION 65
Warning! This product contains a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
50-00-0, Formaldehyde. 140-88-5, Ethyl Acrylate. 108-88-3, Toluene. 872-50-4, N-METHYL
PYRROLIDINONE.
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found
NA = not applicable UNKN = unknown NE = none established REC = recommended ND =
none determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm =
parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status
not required under 40 CFR part 720.30(h-2).
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